Skip to main content

Atomic Resolution of Porphyrins: Single-Molecule Observations of Porphyrinoid Compounds by Scanning Tunneling Microscopy

  • Chapter
Chemistry of Nanomolecular Systems

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 70))

  • 237 Accesses

Summary

This chapter reviews single-molecule observations of porphyrinoid molecules. These are versatile materials that have excellent physical properties associated with their expanded π-electron systems, which are likely to find applications in future nanoscience. The resolution of the observed images is strongly dependent on the substrate used.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. G. Binning, H. Rohrer, C. Gerber, E. Weibel: Phys. Rev. Lett. 49, 57 (1982)

    Article  CAS  Google Scholar 

  2. T.J. Marks: Angew. Chem., Int. Ed. Engl. 29, 857 (1990)

    Google Scholar 

  3. D.K. Rittenberg, K.-i. Sugiura, Y. Sakata, S. Mikami, A. J. Epstein, J.S. Miller: Adv. Mater. 12, 126 (2000)

    CAS  Google Scholar 

  4. M.A. Baldo, D.F. O’Brien, Y. You, A. Shoustikov, S. Sibley, M.E. Thompson, S.R. Forrest: Nature 395, 151 (1998)

    Article  CAS  Google Scholar 

  5. B.M.L. Chen, A. Tulinsky: J. Am. Chem. Soc. 94, 4144 (1972)

    Article  CAS  Google Scholar 

  6. T. Ohmori, H. Masuda, M. Simura, J. Kuroda, T. Okumura: Thin Solid Films 315, 1 (1998)

    Article  CAS  Google Scholar 

  7. P. Miao, A.W. Robinson, R.E. Palmer, B.M. Kariuki, K.D.M. Harris: J. Phys. Chem. B 104, 1285 (2000)

    Article  CAS  Google Scholar 

  8. K.W. Hipps, D.E. Barlow, U. Mazur: J. Phys. Chem. B 104, 2444 (2000)

    Article  CAS  Google Scholar 

  9. D.E. Barlow, K.W. Hipps: J. Phys. Chem. B 104, 5993 (2000)

    Article  CAS  Google Scholar 

  10. X. Lu, K.W. Hipps: J. Phys. Chem. B 101, 5391 (1997)

    Article  CAS  Google Scholar 

  11. X. Lu, K.W. Hipps, X.D. Wang, U. Mazur: J. Am. Chem. Soc. 118, 7197 (1996)

    Article  CAS  Google Scholar 

  12. K.W. Hipps, X. Lu, X.D. Wang, U. Mazur: J. Phys. Chem. 100, 11207 (1996)

    Article  CAS  Google Scholar 

  13. G. Dufour, C. Poncey, F. Rochet, H. Roulet, S. Iacobucci, M. Sacchi, F. Yubero, N. Motta, M.N. Piancastelli, A. Sgariata, M. De Crescenzi: J. Electron Spectrosc. Relat. Phenom. 76, 219 (1995)

    Article  CAS  Google Scholar 

  14. L. Ottaviano, S. Santucci, S. Di Nardo, L. Lozzi, M. Passacantando, P. Picozzi: J. Vac. Sci. Technol. A 15, 1014 (1997)

    Google Scholar 

  15. P. Sautet, C. Joachim: Surf. Sci. 271, 387 (1992)

    Article  CAS  Google Scholar 

  16. P.H. Lippel, R.J. Wilson, M.D. Miller, C. Wöul, S. Chiang: Phys. Rev. Lett. 62, 171 (1989)

    Article  CAS  Google Scholar 

  17. J.K. Gimzewski, E. Stoll, R.R. Schlittler: Surf. Sci. 181, 267 (1987)

    Article  CAS  Google Scholar 

  18. J.Y. Grand, T. Kunstmann, D. Hoffmann, A. Haas, M. Dietsche, J. Seifritz, R. Möller: Surf. Sci. 366, 403 (1996)

    Article  CAS  Google Scholar 

  19. I.I. Smolyaninov: Surf. Sci. 364, 79 (1996)

    Article  CAS  Google Scholar 

  20. M. Kanai, T. Kawai, K. Motai, X.D. Wang, T. Hashizume, T. Sakura: Surf. Sci. 329, L619 (1995)

    Article  CAS  Google Scholar 

  21. Y. Maeda, T. Matsumoto, M. Kasaya, T. Kawai: Jpn. J. Appl. Phys. Pt. 2 35, L405 (1996)

    Google Scholar 

  22. F. Rochet, G. Dufour, H. Roulet, N. Motta, A. Sgariata, M.N. Piancastelli, M. De Crescenzi: Surf. Sci. 319, 10 (1994)

    Article  CAS  Google Scholar 

  23. R. Hiesgen, M. Räbisch, H. Böttcher, D. Meissner: Sol. Energy Mater. Sol. Cells 61, 73 (2000)

    Article  CAS  Google Scholar 

  24. M. Nakamura, Y. Morita, H. Tokumoto: Appl. Surf. Sci. 113/114, 316 (1997)

    Google Scholar 

  25. H. Tanaka, T. Kawai: Jpn. J. Appl. Phys. Pt. 1 35, 3759 (1996)

    Google Scholar 

  26. C. Dekker, S.J. Tans, B. Oberndorf, R. Meyer, L.C. Venema: Synth. Met. 84, 853 (1997)

    Article  CAS  Google Scholar 

  27. W. Mizutani, Y. Sakakibara, M. Ono, S. Tanishima, K. Ohno, N. Toshima: Jpn. J. Appl. Phys. Pt. 2 28, L1460 (1989)

    Google Scholar 

  28. W. Mizutani, M. Shigeno, Y. Sakakibara, K. Kajimura, M. Ono, S. Tanishima, K. Ohno, N. Toshima: J. Vac. Sci. Technol. A 8, 675 (1990)

    Google Scholar 

  29. M. Pomerantz, A. Aviram, R.A. McCorkle, L. Li, A.G. Schrott: Science 255, 1115 (1992)

    Article  CAS  Google Scholar 

  30. Rudiono, F. Kaneko, M. Takeuchi: Appl. Surf. Sci. 142, 598 (1999)

    Article  CAS  Google Scholar 

  31. Y. Maeda, T. Matsumoto, T. Kawai: Surf. Sci. 384, L896 (1997)

    Article  CAS  Google Scholar 

  32. C. Hamann, R. Laiho, A. Mrwa: Phys. Status Solidi A 116, 729 (1989)

    Article  CAS  Google Scholar 

  33. O. Pester, A. Mrwa, M. Hietschold: Phys. Status Solidi A 131, 19 (1992)

    Article  CAS  Google Scholar 

  34. L. Ottaviano, L. Lozzi, S. Santucci, S. Di Nardo, M. Passacantando: Surf. Sci. 392, 52 (1997)

    Article  CAS  Google Scholar 

  35. X. Qiu, C. Wang, S. Yin, Q. Zeng, B. Xu, C. Bai: J. Phys. Chem. B 104, 3570 (2000)

    Article  CAS  Google Scholar 

  36. P. Smolenyak, R. Peterson, K. Nebesny, M. Toerker, D.F. O’Brien, N.R. Armstrong: J. Am. Chem. Soc. 121, 8628 (1999)

    Article  CAS  Google Scholar 

  37. A. Manivannan, L.A. Nagahara, H. Yanagi, A. Fujishima: J. Vac. Sci. Technol. B 12, 2000 (1994)

    Google Scholar 

  38. L.A. Nagahara, A. Manivannan, H. Yanagi, M. Toriida, M. Ashida, Y. Maruyama, K. Hashimoto, A. Fujishima: J. Vac. Sci. Technol. A 11, 781 (1993)

    Google Scholar 

  39. L. Scudiero, D.E. Barlow, K.W. Hipps: J. Phys. Chem. B 104, 11899 (2000)

    Article  CAS  Google Scholar 

  40. L. Scudiero, D.E. Barlow, U. Mazur, K.W. Hipps: J. Am. Chem. Soc. 123, 4073 (2001)

    Article  CAS  Google Scholar 

  41. J.K. Gimzewski, T.A. Jung, M.T. Cuberes, R.R. Schlittler: Surf. Sci. 386, 101 (1997)

    Article  CAS  Google Scholar 

  42. M.S. Boeckl, A.L. Bramblett, K.D. Hauch, T. Sasaki, B.D. Ratner, J.W. Rogers, Jr.: Langmuir 16, 5644 (2000)

    Article  CAS  Google Scholar 

  43. T. Yokoyama, S. Yokoyama, T. Kamikado, S. Mashiko: J. Chem. Phys. 115, 3814 (2001)

    Article  CAS  Google Scholar 

  44. T.A. Jung, R.R. Schlittler, J.K. Gimzewski, H. Tang, C. Joachim: Science 271, 181 (1996)

    Article  CAS  Google Scholar 

  45. T.A. Jung, R.R. Schlittler, J.K. Gimzewski: Nature 386, 696 (1997)

    Article  CAS  Google Scholar 

  46. D. Fujita, T. Ohgi, W.L. Deng, H. Nejo, T. Okamoto, S. Yokoyama, K. Kamikado, S. Mashiko: Surf. Sci. 454–456, 1021 (2000)

    Google Scholar 

  47. J.K. Gimzewski, C. Joachim: Science 283, 1683 (1999)

    Article  CAS  Google Scholar 

  48. F. Moresco, G. Meyer, K.-H. Rieder, H. Tang, A. Gourdon, C. Joachim: Appl. Phys. Lett. 78, 306 (2001)

    Article  CAS  Google Scholar 

  49. F. Moresco, G. Meyer, K.-H. Rieder, H. Tang, A. Gourdon, C. Joachim: Phys. Rev. Lett. 86, 672 (2001)

    Article  CAS  Google Scholar 

  50. T. Yokoyama, S. Yokoyama, T. Kamikado, Y. Okuno, S. Mashiko: Nature 413, 619 (2001)

    CAS  Google Scholar 

  51. W. Han, S. Li, S.M. Lindsay, D. Gust, T.A. Moore, A.L. Moore: Langmuir 12, 5742 (1996)

    Article  CAS  Google Scholar 

  52. M. Kunitake, N. Batina, K. Itaya: Langmuir 11, 2337 (1995)

    Article  CAS  Google Scholar 

  53. N. Batina, M. Kunitake, K. Itaya: J. Electroanal. Chem. 405, 245 (1996)

    Article  Google Scholar 

  54. M. Kunitake, U. Akiba, N. Batina, K. Itaya: Langmuir 13, 1607 (1997)

    Article  CAS  Google Scholar 

  55. K. Ogaki, N. Batina, M. Kunitake, K. Itaya: J. Phys. Chem. 100, ‘7185 (1996)

    Google Scholar 

  56. K. Sashikata, T. Sugata, M. Sugimasa, K. Itaya: Langmuir 14, 2896 (1998)

    Article  CAS  Google Scholar 

  57. L.-J. Wan, S. Shundo, J. Inukai, K. Itaya: Langmuir 16, 2164 (2000)

    Article  CAS  Google Scholar 

  58. M. Furukawa, H. Tanaka, K.-i. Sugiura, Y. Sakata, T. K.wai: Surf. Sci. 445, L58 (2000)

    Article  CAS  Google Scholar 

  59. N.J. Tao, G. Cardenas, F. Cunha, Z. Shi: Langmuir 11, 4445 (1995)

    Article  CAS  Google Scholar 

  60. B. Duong, R. Arechabaleta, N.J. Tao: J. Electroanal. Chem. 447, 63 (1998)

    Article  CAS  Google Scholar 

  61. N. Bampos, C.N. Woodburn, M.E. Welland, J.K.M. Sanders: Angew. Chem., Int. Ed. Engl. 38, 2780 (1999)

    Google Scholar 

  62. P.J. Thomas, N. Berovic, P. Laitenberger, R.E. Palmer, N. Bampos, J.K.M. Sanders: Chem. Phys. Lett. 294, 229 (1998)

    Article  CAS  Google Scholar 

  63. K.-i. Sugiura, T. Matsumoto, S. Ohkouchi, Y. Naitoh, T. Kawai, Y. Takai, K. Ushiroda, Y. Sakata: Chem. Commun. 1957 (1999)

    Google Scholar 

  64. K.-i. Sugiura, H. Tanaka, T. Matsumoto, T. Kawai, Y. Sakata: Chem. Lett. 1193 (1999)

    Google Scholar 

  65. C.C. Leznoff, A.B.P. Lever (eds.): Phthalocyanines, Vol. 1 ( VCH, New York 1989 )

    Google Scholar 

  66. C.C. Leznoff, A.B.P. Lever (eds.): Phthalocyanines, Vol. 2 ( VCH, New York 1992 )

    Google Scholar 

  67. C.C. Leznoff, A.B.P. Lever (eds.): Phthalocyanines, Vol. 3 ( VCH, New York 1993 )

    Google Scholar 

  68. C.C. Leznoff, A.B.P. Lever (eds.): Phthalocyanines, Vol. 4 ( VCH, New York 1996 )

    Google Scholar 

  69. G. Ashkenasy, D. Cahen, R. Chohen, A. Shanzer, A. Vilan: Acc. Chem. Res. 35, 121 (2002)

    Article  CAS  Google Scholar 

  70. T. Takami, J.K. Gimzewski, R.R. Schlittler, T. Jung, Ch. Gerber, K. Sugiura, Y. Sakata: 50th National Meeting of the Japanese Physical Society, Kanagawa, March 1995, Abstr., 28p-PSB-29.

    Google Scholar 

  71. T.K. Miyamoto, S. Tsuzuki, T. Hasegawa, Y. Sasaki: Chem. Lett., 1587 (1983)

    Google Scholar 

  72. T.K. Miyamoto, N. Sugita, Y. Matsumoto, Y. Sasaki, M. Kovno: Chem. Lett., 1695 (1983)

    Google Scholar 

  73. H.L. Anderson: Chem. Commun., 2323 (1999)

    Google Scholar 

  74. G.Y. Tseng, J.C. Ellenbogen: Science 294, 1293 (2001)

    Article  CAS  Google Scholar 

  75. A.K. Burrell, D.L. Officer, P.G. Plieger, D.C.W. Reid: Chem. Rev. 101 2751(2001)

    Google Scholar 

  76. T. Pullerits, V. Sundström: Acc. Chem. 29, 381 (1996)

    Google Scholar 

  77. H. Tanaka, T. Kawai: J. Vac. Sci. Technol., B15, 602 (1997)

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Sugiura, Ki., Miyasaka, H., Ishii, T., Yamashita, M. (2003). Atomic Resolution of Porphyrins: Single-Molecule Observations of Porphyrinoid Compounds by Scanning Tunneling Microscopy. In: Nakamura, T., Matsumoto, T., Tada, H., Sugiura, Ki. (eds) Chemistry of Nanomolecular Systems. Springer Series in Chemical Physics, vol 70. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05250-1_4

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-05250-1_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-07910-8

  • Online ISBN: 978-3-662-05250-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics