Abstract
La1−x Ca x MnO3 is among the most-studied compounds of the manganite family. Among the reasons for its popularity are its robust magnetoresistance effect, larger than in other much-studied materials such as La1−x Sr x MnO3, and the possibility of analyzing the phase diagram at all values of the Ca concentration (most manganites can only be studied in a more restrictive hole-density range). La1−x Ca x MnO3 is usually labeled as a “low” bandwidth manganite, but it may be better to consider it as a representative of “intermediate” bandwidth compounds. The reason is that this material still has a ferromagnetic metallic phase in a robust density range, unlike truly low-bandwidth compounds such as Pr1−x Ca x MnO3 (discussed later) where the metallic phase is only induced by external magnetic fields.
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Dagotto, E. (2003). Phase Diagrams and Basic Properties of Manganites. In: Nanoscale Phase Separation and Colossal Magnetoresistance. Springer Series in Solid-State Sciences, vol 136. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05244-0_3
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