Abstract
The chemical structure of a complex polymer is characterized by its chemical composition, the sequence of the monomer units in the polymer chain, the functionality, and the molar mass. Typically, polymer analysis has to deal with the overlaying effects of different types of molecular heterogeneity in one macromolecular system. As for functional homopolymers (telechelics, macromonomers) the molar mass distribution is superimposed by a functionality type distribution. Random or segmented copolymers consist of a multitude of molecules with different chain lengths and different chemical compositions. In the ideal case, such complex systems should be separated into individual oligomers, which then may be analyzed with respect to chain lengths, functional groups, and chemical composition.
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Pasch, H., Schrepp, W. (2003). Analysis of Complex Polymers. In: MALDI-TOF Mass Spectrometry of Synthetic Polymers. Springer Laboratory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05046-0_6
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DOI: https://doi.org/10.1007/978-3-662-05046-0_6
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