Summary
It is possible to describe quasiperiodic structures in terms of a skeleton of a hierarchical self-similar packing of overlapping atomic clusters. The related inflation rules constrain both composition and atomic valences to have strictly defined values. Stability of the skeleton requires that bonding electrons are recurrently localized at site-forming self-similar isomorphic subsets of the structure and are distributed into “magic cluster” states. Properties can be understood in the framework of such a cluster description of quasicrystals.
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Janot, C., Dubois, JM. (2002). Quasicrystals as Hierarchical Packing of Overlapping Clusters. In: Suck, JB., Schreiber, M., Häussler, P. (eds) Quasicrystals. Springer Series in Materials Science, vol 55. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05028-6_8
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DOI: https://doi.org/10.1007/978-3-662-05028-6_8
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