Skip to main content

Processing and Microstructure

  • Chapter
Nanocrystalline Ceramics

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 53))

  • 307 Accesses

Abstract

The microstructure is defined by the type, crystal structure, number, shape and topological arrangement of phases and defects such as point defects, dislocations, stacking faults or grain boundaries in a crystalline material (Gleiter 1996). Nanocrystalline materials are polycrystalline solids with grain sizes below 100 nm (Gleiter 1989). Grains as well as pores, interfaces and other defects are of similar dimensions (see Fig. 4.1). This nano-specific microstructure (nanostructure) leads to chemical and physical size effects. The coincidence of methods for the synthesis of large quantities of such materials, new methods of analysis (e.g. HRTEM or STM), and the original idea of Gleiter that with the compaction of nanoparticles, novel materials with interesting microstructure and properties can be expected, provided the basis for the broad research field ‘nano-materials’ which has increased enormously over the last decade.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Allen, A. J., Krueger, S., Skandan, G., Long, G. G., Hahn, H., Kerch, H. M., Parker, J. C., and Ali, M. N., J. Am. Ceram. Soc. 79 (1996), 1201

    Google Scholar 

  • Benker, A., diploma thesis, Darmstadt 1999

    Google Scholar 

  • Bennison, S. J., chapter “Grain Growth” in “Engineered Materials Handbook”, Volume 4 “Ceramics and Glasses”, Schneider, S. J., (chairman) ASM International, 1991, 304

    Google Scholar 

  • Betz, U. and Hahn, H., Nanostruct. Mater. 12 (1999), 911

    Article  Google Scholar 

  • Betz, U., Hahn, H. and Padmanabhan, K. A., Acta Met., 2000, submitted

    Google Scholar 

  • Chen, D. J. and Mayo, M. J., J. Am. Ceram. Soc., 79 (1996), 906

    Article  CAS  Google Scholar 

  • Chen, I.-W., Wang, X.-H., Nature 404 (2000), 168

    Article  CAS  Google Scholar 

  • Chiang, Y.-M., Birnie, D., and Kingery, W. D., “Physical Ceramics - Principles for Ceramic Science and Engineering”, Wiley New York 1997

    Google Scholar 

  • Coble, R. L., J. Appl. Phys. 32 (1961), 787

    Article  CAS  Google Scholar 

  • Duran, P., Villegas, M., Capel, F., Recio, P., and Moure, C., J. Euro. Ceram. Soc., 16 (1996), 945

    Article  CAS  Google Scholar 

  • Fotou G. P. and Toivo T. Kodas, T. T., Advanced Materials 9 (1997), 420

    Article  CAS  Google Scholar 

  • German, R. M., chapter “Fundamentals of Sintering” in “Engineered Materials Handbook”, Volume 4 “Ceramics and Glasses”, Schneider, S. J., (chairman) ASM International, 1991, 260

    Google Scholar 

  • Gleiter, H., Progress in Materials Science 33 (1989), 223

    Article  CAS  Google Scholar 

  • Gleiter, H., “Microstructure” chapter 9 in Cahn, R. W. and Haasen, P. (eds.), “Physical Metallurgy”, fourth edition, Elsevier Science, London 1996, 844

    Google Scholar 

  • Graaf, M. A. C. G. Van de and Burggraaf, A. J., in Advances in Ceramics, Vol. 2. Edited by Claussen, N., Rühle, M., and Heuer., A. H., American Ceramics Society, Columbus 1984, 744

    Google Scholar 

  • Groot Zevert., W. F. M., W.nnubst, A. J. A., Theunissen, G. S. A. M., and Burggraaf, A. J., J. Mater. Sci., 25 (1990), 3449

    Google Scholar 

  • Hahn, H. and Averback, R. S., J. Am. Ceram. Soc. 74 (1991), 2918

    Google Scholar 

  • Hahn H., and R. S. Averback, Nanostruct. Mater., 1 (1992), 95

    Article  CAS  Google Scholar 

  • Hahn, H., Nanostruct. Mater., 2 (1993), 251

    Google Scholar 

  • Hahn, H., Logas, J., and Averback, R. S., J. Mater. Res. 5 (1990), 609

    Google Scholar 

  • Hahn, H., Nanostruct. Mater. 2, (1993), 251

    Google Scholar 

  • Herring, C., J. Appl. Phys., 2 (1950), 301

    Google Scholar 

  • Hu, M. Z. C., Harris, M. T., and Byers, C. H., J. Coll. Int. Sci. 198 (1998), 87

    Google Scholar 

  • Hu, M. Z. C., Hunt, R. D., Andrew, E. A., and Hubburd, C. R., J. Amer. Ceram. Soc. 82 (1999), 2313

    Google Scholar 

  • Hu, M. Z. C., Zielke, J. T., Lin, J. S., and Byers, C. H., J. Mat. Res. 14 (1999), 103

    Google Scholar 

  • Inamura, S., Miyamoto, H., Imaida, Y., Takagawa, M., Hirota, K., and Yamaguchi, O., J. Mater. Sci. 29 (1994), 4913

    Article  CAS  Google Scholar 

  • Kanters, J., Eisele, U., and Rödel, J., Acta Mater. 48 (2000), 1239

    Article  CAS  Google Scholar 

  • Kimoto, S., Hirota, K., Yamaguchi, O., Kume, H., Inamura, S., and Miyamoto, H., J. Am. Ceram. Soc. 77 (1994), 1694

    Google Scholar 

  • Kingery, W. D., Bowen, H. K., and Uhlmann, D. R. R., “Introduction to Ceramics”, 2nd edition, Wiley New York 1976

    Google Scholar 

  • Kumar, K. P., Kelzer, K., Burggraaf, A. J., Okuba, T., Nagamoto, H. and Morooka, S., Nature, 358 (1992), 48

    Google Scholar 

  • Lange, F. F. and Hirlinger, M.M., J. Am. Ceram. Soc., 70 (1987), 827

    Article  CAS  Google Scholar 

  • Liao, S.C., Chen, Y. J., Kear, B. H., and Mayo, W. E., Nanostruct. Mater. 10 (1998), 1063

    Google Scholar 

  • Liao, S. C., Mayo, W. E., and Pae, K. D., Acta Mater. 45 (1997), 4027

    Article  CAS  Google Scholar 

  • Mayo, M. J., Mater. Design, 14 (1993), 323

    Google Scholar 

  • Mayo, M. J., in “Superplasticity in Advanced Materials”, Hori, S., Tokizane, M., and Furushiro. N., (eds.) The Japan Society for Research on Superplasticity, Japan, 1991,541

    Google Scholar 

  • Mayo, M. J., and Chen, D. J., in “Synthesis and Processing of Nanocrystalline Powder”, Bourell, D. L., (ed.), The Minerals, Metals and Materials Soc., Warrendale, Pennsylvania, 1996,210

    Google Scholar 

  • Mayo, M. J., Hague, D. C. and Chen, D. J., Mater. Sci. Engin., A166 (1993), 145

    Article  Google Scholar 

  • Mayo, M. J., Seidensticker, J. R., Hague, D. C., and Carim, A. H., Nanostruct. Mater. 11 (1999), 271

    Article  CAS  Google Scholar 

  • Nitsche, R., Rodewald, M., Skandan, G., Fuess, H., and Hahn, H., Nanostruct. Mater., 7 (1996), 535

    Article  CAS  Google Scholar 

  • Powell, Q. H., Kodas, T. T., and Anderson, B. M., Chem. Vap. Deposition 2 (1996), 179

    Article  CAS  Google Scholar 

  • Rajendran, J., Drennan, J., and Badwal, S. P. S., J. Mat. Sci. Lett. 6 (1987), 1431

    Google Scholar 

  • Rhodes, W. H., J. Am. Ceram. Soc., 64 (1981), 19

    Article  CAS  Google Scholar 

  • Sagel-Ransijn, C. D., Winnubst, A. J. A., Burggraaf, A. J., and Verweij, H., J. Euro. Ceram. Soc. 16 (1996), 759

    Article  CAS  Google Scholar 

  • Shi, J. L., Gao, J.H., Li, B. S., and Yen, T. S., J. Euro. Ceram. Soc., 15 (1995), 967

    Article  CAS  Google Scholar 

  • Skandan, G., “Processing of Nanostructured Zirconia Ceramics,” Nanostruct. Mater. 5 (1995), 111

    CAS  Google Scholar 

  • Skandan, G., Hahn, H., Kear, B. H., Roddy, M., and Cannon, W. R., Mater. Lett., 20 (1994), 305

    Article  CAS  Google Scholar 

  • Skandan, G., Hahn, H., Roddy, M., and Cannon, W. R., J. Am. Ceram. Soc., 77 (1994), 1706

    Google Scholar 

  • Srdic, V. V., Winterer, M., and Hahn, H., J. Am. Ceram. Soc. 83 (2000), 729

    Article  CAS  Google Scholar 

  • Srdic, V. V., Winterer, M., and Hahn, H., J. Am. Ceram. Soc., 83 (2000), 1853

    Google Scholar 

  • Srdic, V. V., Winterer, M., A. MöIler, G. Miehe and Hahn, H., J. Am. Ceram. Soc. 84 (2001), 2771

    Google Scholar 

  • Swinkels F. B. and Ashby, M. F., Acta Meta11. 29 (1981), 259

    Google Scholar 

  • Vollath, D. and Szabo, D.V., Nanostruct. Mater. 4 (1994), 927–938

    Article  CAS  Google Scholar 

  • Vollath, D., Szabo, D. V., and HauBelt, J., J. Eur. Ceram. Soc. 17 (1997), 1317

    Google Scholar 

  • Wakai, F., Sakaguchi, S., and Matsuno, Y., Adv. Ceram. Mater. 1 (1986), 259

    CAS  Google Scholar 

  • Wang, J. and Gao, K., Nanostruct. Mater. 11 (1999), 451

    Article  CAS  Google Scholar 

  • Wang, J., Ong, C. L., Gan L. M., and Ng, S. C., Mater. Letters, 27 (1996), 239

    Article  Google Scholar 

  • Winnubst, A. J. A., Theunissen, G. S. A. M., and Burggraaf, A. J., in “Euro Ceramics”, Vol 1., With, G. de, R. A. Terpstra, R. A., and R. Metselaar, R. (eds.), Elsevier, London 1989,393

    Google Scholar 

  • Yamaguchi, O., Hirota, K., Inamura, S., and Miyamoto, H., in “Advanced Synthesis and Proc-essing of Composites and Advanced Ceramics”, Ceramic Transactions Vol. 56. The Ameri-can Ceramic Society 1995,353

    Google Scholar 

  • Yan, M. F., chapter “Solid State Sintering” in “Engineered Materials Handbook”, Volume 4 “Ceramics and Glasses”, Schneider, S. J., (chairman) ASM International, 1991,304

    Google Scholar 

  • Chu, B. (ed.), “Laser Light Scattering”, 2“d edition, Academic Press 1991

    Google Scholar 

  • O’Brien, R. W. and White, L. W., J. Chem. Soc. Faraday II 74 (1978), 1607

    Google Scholar 

  • Barrett, E. P., Joyner, L. G., and Halenda, P. P., J. Am. Ceram. Soc. 73 (1951), 373 Anantharaman, T. R. and Christian, J. W., Acta Cryst., 9 (1956), 479

    Google Scholar 

  • Cullity, A. D., “Elements of X-Ray Diffraction”, Addison-Wesley, Reading, Massachusetts, 1978

    Google Scholar 

  • Toraya, H., Yoshimura, M., and Somiya, S., J. Am. Ceram. Soc. 67 (1984) C119

    CAS  Google Scholar 

  • Howard, C. J., Hill, R. J., and Reichert, B. E., Acta Cryst. B44 (1988), 116

    Article  Google Scholar 

  • Levin, I., and D. Brandon, D., J. Am. Ceram. Soc. 81 (1998), 195

    Google Scholar 

  • Schmid, H. K., J. Am. Ceram. Soc. 70 (1987), 367

    Article  CAS  Google Scholar 

  • Allen, A. J., Krueger, S., Skandan, G., Long, G. G., Hahn, H., Kerch, H. M., Parker, J. C. and Ali, M. N., J. Am. Ceram. Soc. 79 (1996), 1201

    Google Scholar 

  • Ayyub, P., Palkar, V. R., Chattopadhyay,S., and Multani, M., Phys. Rev., B51 (1995), 6135 Bennison, S. J., chapter “Grain Growth” in “Engineered Materials Handbook”, Volume 4 “Ceramics and Glasses”, Schneider, S. J., (chairman) ASM International, 1991, 304

    Google Scholar 

  • Bondars, B., Heidemane, G., Grabis, J., Laschke, K., Boysen, H., Scheider, J., Frey, F., J. Mater. Sci. 30 (1995), 1621

    Google Scholar 

  • Brook, R. J., J. Am. Ceram. Soc. 52 (1969), 56

    Article  CAS  Google Scholar 

  • Chen, D. J. and Mayo, M. J., Nanostruct. Mater. 2 (1993), 469

    Article  CAS  Google Scholar 

  • Chen, I. W., Mater. Sci. Engin., A166 (1993), 51

    Article  Google Scholar 

  • Chen, P. L. and Chen, I. W., J. Am. Ceram. Soc. 79 (1996), 1793

    Google Scholar 

  • Chen, P. L. and Chen, I. W., J. Am. Ceram. Soc. 79 (1996), 1801

    Google Scholar 

  • Chen, P. L. and Chen, I. W., J. Am. Ceram. Soc. 79 (1996), 3129

    Article  CAS  Google Scholar 

  • Chen, P. L. and Chen, I. W., J. Am. Ceram. Soc. 80 (1997), 637

    Article  CAS  Google Scholar 

  • Chiang, Y: M., Birnie, D., and Kingery, W. D., “Physical Ceramics - Principles for Ceramic Science and Engineering”, Wiley New York 1997

    Google Scholar 

  • Duran, P., Villegas, M., Capel, F., Recio, P., and Moure, C., J. Euro. Ceram. Soc., 16 (1996), 945

    Google Scholar 

  • Flagan, R. C. and Lunden, M. M., Mater. Sci. Eng. A204 (1995), 113

    Article  Google Scholar 

  • Frey, F., Boysen, H., Vogt, T., Acta Cryst., B46 (1990), 724

    Article  Google Scholar 

  • Garvie, R. C., J. Phys. Chem., 82 (1978), 218

    Google Scholar 

  • Graaf, M. A. C. G. Van de, Ter Maat, J. H. H., and Burggraaf, A. J., J. Mater. Sci., 20 (1985), 1407

    Google Scholar 

  • Gregg, S. J. and Sing, K. S. W., “Adsorption, Surface Area and Porosity”, Academic Press 1982

    Google Scholar 

  • Hahn, H., Logas, J., and Averback, R. S., J. Mater. Res. 5 (1990), 609

    Article  CAS  Google Scholar 

  • Hahn, H., Nanostruct. Mater. 2 (1993), 251

    Google Scholar 

  • John, W., “The Characteristics of Environmetal and Laboratory Generated Aerosols”, chapter 5, in “Aerosol Measurement - Principles, Techniquies and Applications”, K. Willeke and P. A. Baron (eds.), Van Nostrand Reinhold, New York, 1993, 59

    Google Scholar 

  • Kingery, W. D. and Francois, B., in “Sintering and Related Phenomena”, Kuczynski, G. C., Hooton, N. A., and Gibbon, C. F., Gordon and Breach, New York 1967,23

    Google Scholar 

  • Kingery, W. D., Bowen, H. K., and D. R. Uhlmann, “Introduction to Ceramics”, John Wiley and Sons, New York 1976

    Google Scholar 

  • Klein, S., Winterer, M., and Hahn, H., Adv. Mater. (Chem. Vapor Depos.), 4 (1998), 143

    Google Scholar 

  • Mayo, M. J. and Chen, D. J., in “Synthesis and Processing of Nanocrystalline Powder”, Bourell, D. L. (ed.), Warrendale, Pensylvania: The Minerals, Metals and Materials Society 1996, 210

    Google Scholar 

  • Mayo, M. J., and Hague, D. C., Nanostruct. Mater. 3 (1993), 43

    Article  CAS  Google Scholar 

  • Mayo, M. J., Hague, D. C., and Chen, D. J., Mater. Sci. Engin. A166 (1993), 145

    Article  Google Scholar 

  • Mayoral, R., Requena, J., Moya, J. S., Lopez, C., Cintas, A., Miguez, H., Meseguer, F., Vazquez, L., Holgado, M., and Blanco, A., Adv. Mater. 9 (1997), 257

    Article  CAS  Google Scholar 

  • Nitsche, R., Rodewald, M., Skandan, G., Fuess, H., and Hahn, H. Nanostruct. Mater. 7 (1996), 535

    Google Scholar 

  • Sagel-Ransijn, C. D., Winnubst, A. J. A., Burggraaf, A. J., and Verweij, H., J. Euro. Ceram. Soc., 16 (1996), 759

    Article  CAS  Google Scholar 

  • Skandan, G. and Hahn, H., unpublished results 1993

    Google Scholar 

  • Skandan, G., Hahn, H., Roddy, M. and Cannon, W. R., J. Am. Ceram. Soc., 77 (1994), 1706

    Google Scholar 

  • Skandan, G., Nanostruct. Mater. 5 (1995), 111

    Article  CAS  Google Scholar 

  • Stebens, R., “Engineering Properties of Zirconia”, in Schneider, S. J. (ed.), Engineered Materials Handbook volume 4, “Ceramics and Glasses”, ASM 1991, pp 775.

    Google Scholar 

  • Alexander, K. B., Becher, P. F., Waters, S. B., and Bleier, A., J. Am. Ceram. Soc. 77 (1994), 939

    Article  CAS  Google Scholar 

  • Balmer, M. L., Lange, F. F., and Levi, C. G., J. Am. Ceram. Soc. 77 (1994), 2069

    Google Scholar 

  • Balmer, M. L., Eckert, H., Das, N., and Lange, F. F., J. Am. Ceram. Soc. 79 (1996), 321

    Article  CAS  Google Scholar 

  • Bennison, S. J., “Grain Growth”, in “Engineering Materials Handbook”, volume 4: “Ceramics and Glasses”, ASM International 1991,304

    Google Scholar 

  • Garvie, R. C., J. Phys. Chem. 82 (1978), 218

    Article  CAS  Google Scholar 

  • Hillert, M., Acta Metal. 36 (1988), 3177

    Article  CAS  Google Scholar 

  • Inamura, S., Miyamoto, H., Imaida, Y., Takagawa, M., Hirota, K., and Yamaguchi, O., J. Mater. Sci. 29 (1994), 4913

    Article  CAS  Google Scholar 

  • Kingery, W. D., and Francois, B., in “Sintering and Related Phenomena”, Kuczynski, G.C., Hooton, N. A., and Gibbon, C. F., (eds.), Gordon and Breach, New York, 1967,23

    Google Scholar 

  • Kingery, W. D., Bowen, H., and Uhlmann, D. R., “Introduction to Ceramics”, Wiley, New York, 1976

    Google Scholar 

  • Mayo, M. J., Hague, D. C., and Chen, D. J., Mater. Sci. Engin. A166 (1993), 145

    Article  Google Scholar 

  • Mayo, M. J., Mater. Design 14 (1993), 323

    Article  CAS  Google Scholar 

  • Mayoral, R., Requena, J., Moya, J. S., Lopez, C., Cintas, A., Miguez, H., Meseguer, F., Vazquez, L., Holgado, M., and Blanco, A., Adv. Mater., 9 (1997), 257

    Article  CAS  Google Scholar 

  • Scott, H. G., J. Mater. Sci. 10 (1975), 1527

    Google Scholar 

  • Srdic, V. V., and Savic, D. I., J. Mater. Sci. 33 (1998), 2391

    Google Scholar 

  • Srdic, V. V., Winterer, M. and Hahn, H., J. Am. Ceram. Soc. 83 (2000), 729

    Article  CAS  Google Scholar 

  • Srdic, V. V., Winterer, M. and Hahn, H., J. Am. Ceram. Soc. 83 (2000), 1853

    Google Scholar 

  • Garvie, R. C., J. Phys. Chem. 82 (1978), 218

    Google Scholar 

  • Kingery, W. D., and Francois, B., in “Sintering and Related Phenomena”, Kuczynski, G.C., Hooton, N. A., and Gibbon, C. F., (eds.), Gordon and Breach, New York, 1967,23

    Google Scholar 

  • Kingery, W. D., Bowen, H., and Uhlmann, D. R., “Introduction to Ceramics”, Wiley, New York, 1976

    Google Scholar 

  • Kung, H. H., J.Solid State Chemistry 52 (1984), 191

    Google Scholar 

  • Kung, H. H., “Transition Metal Oxides: Surface Chemistry and Catalysis”, Elsevier, Amsterdam 1989

    Google Scholar 

  • Mayo, M. J., Hague, D. C., and Chen, D. J., Mater. Sci. Engin. A166 (1993), 145

    Article  Google Scholar 

  • Möller, A., 2000 to be published

    Google Scholar 

  • Parks, G. A., deBruyn, P. L., J. Phys. Chem. 66 (1962), 967

    Article  CAS  Google Scholar 

  • Srdic, V. V., Winterer, M., A. Möller, G. Miehe and Hahn, H., J. Am. Ceram. Soc. 84 (2001), 2771

    Google Scholar 

  • Wang, J. and Gao, L., Nanostr. Mater. 11 (1999), 451

    Article  CAS  Google Scholar 

  • Bhattacharya, S. S., private communication, Darmstadt 1999

    Google Scholar 

  • Chen, D.-J., and Mayo, M. J., Nanostruct. Mater. 2 (1993), 469

    Article  CAS  Google Scholar 

  • Duran, P., Villegas, M., Capel, F., Recio, P., and Moure, C., J. Eur. Ceram. Soc. 16 (1996), 945

    Article  CAS  Google Scholar 

  • Hughes, A. E., in Science of Ceramic Interfaces II, Nowotny, J. (ed.), Elsevier, Amsterdam 1994, 183

    Google Scholar 

  • Lange, F. F., J. Am. Ceram. Soc. 69 (1986), 240

    Article  CAS  Google Scholar 

  • Mondai, P., “Elektrische Eigenschaften nanokristalliner Y2O,-stabilisierter ZrO2 Keramiken”, Dissertation, Darmstadt 1998

    Google Scholar 

  • Rhodes, J. Am. Ceram. Soc. 64 (1981), 19

    Google Scholar 

  • Theunissen, G. S. A. M., Winnubst, A. J. A., and Burggraaf, A. J., J. Eur. Ceram. Soc. 11 (1993), 315

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2002 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Winterer, M. (2002). Processing and Microstructure. In: Nanocrystalline Ceramics. Springer Series in Materials Science, vol 53. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04976-1_4

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-04976-1_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-07784-5

  • Online ISBN: 978-3-662-04976-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics