Abstract
A reactive plume model has been developed in order to calculate NO-N02 transformation in the vicinity of the source. The model has been tailored to explicitly allow for the interaction of chemical reactions and the physical mixing process. The mixing process depends in both the macro-scale and micro-scale properties of the plume. Both effect have been taken into account and will be discussed. The model is based on the resolution of nine ordinary differential equations for the reactive species NO-N02-03 and their cross products integrated over the width of the plume. The results are compared to experimental data and those obtained by the resolution of the complete Eulerian transport equations. It is shown the reactive plume model gives accurate results.
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References
Bange P, Janssen LHJM, Nieuwstadt FTM, Visser H, and Erbrink JJ (1991) Improvement of the modelling of daytime nitrogen oxidation in plumes by using instantaneous plume dispersion parameters. Atmospheric Environment, vol 25A,N° 10, pp 2321–2328
Builjes P.J.H., (1981) Chemically reacting plume experiment for the wind tunnel, Netherlands Organisation for Applied Scientific Research, Division of technology for Society, Ref N° 81–0123563, file N° 8710–20330
Delamare L., Gonzalez M. and Coppalle A. (1998) Numerical simulation of a turbulent reactive plume using a new analytical model for the influence of micromixing, Air pollution Modelling and its application XII, Plenum Press, New York, pp 441–449
Delamare L, Coppalle A, and Gonzalez M (2000) A simple and practical model for reactive plume, Int. J. Environment and pollution, Vol 14, N°1–6, 382–390
Fraigneau Y, Gonzalez M, and Coppalle A (1995) Dispersion and chemical reaction of a pollutant near a motorway. Science of the total environment, 169, pp 83–91
Fraigneau Y, Gonzalez M, and Coppalle A (1996-a) Turbulence effects upon the N02/NO conversion in the vicinity of an urban area. Science of the total environment, 189/190, pp 293–300
Fraigneau Y, Gonzalez M, and Coppalle A (1996-b) The influence of turbulence upon the chemical reaction of nitric oxide release from a ground source into ambient ozone, Atm. Env., 30, 1467–1480
Galmarini S, Vila-Guerau de Arellano J, and Duynkerke PG (1995) The effect of micro-scale turbulence on the reaction rate in a chemically reactive plume. Atmospheric environment, vol 29, N° 1, pp 87–95
Georgopoulos P.G. and Seinfeld J.H., (1986) Mathematical modeling of turbulent reacting plume, I Theory and model formulation, II application to the NO-NO2–03 system, Atm. Env., vol 20, 1791–1807/1809–1818
Gonzalez M. (1997) Analysis of the effect of microscale turbulence on atmospheric chemical reaction by means of the P.D.F. approach, Atm. Env., 31,pp575–586.
Janssen LHJM (1986) Mixing of ambiant air in a plume and its effects on the oxidation of NO. Atmospheric Environment, vol 20, N° 12, pp 2347–2357
Janssen L.H. et al (1990) Time scales of physical and chemical processes in chemically reactive plumes, Atm. Env., vol 24A, pp 2861–2874.
Janssen LHJM, Van Haren F, Bange P, and Van Duuren H (1991) Measuremants and modelling of reactions of nitrogen oxides in power-plant plumes at night. Atmospheric Environment, vol 25A, N° 5–6, pp 289–840
Karamchandani P. and Peters L. (1987) Three-dimensional behavior of mixinglimited chemistry in the atmosphere, Atm. Env., Vol 21, pp511–522
Meeder JP, Bouwmans I, and Nieuwstadt FTM (1994) The Large Eddy Simulation of Dispersion of Passive and Chemically Reactive Polluants in a Convective Atmospheric Boundary Layer. Direct and Large Eddy Simulation, vol I, pp 179–188
Sykes RI et al (1992) Large-eddy simulation of turbulent reacting plume. Atm. Env., 26, pp 2565–2574.
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© 2002 Springer-Verlag Berlin Heidelberg
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Philippe, C., Coppalle, A., Plion, P. (2002). A Reactive Plume Model for the NO-N02 Transformation Close to the Stack Emission. In: Sportisse, B. (eds) Air Pollution Modelling and Simulation. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04956-3_19
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DOI: https://doi.org/10.1007/978-3-662-04956-3_19
Publisher Name: Springer, Berlin, Heidelberg
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