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Sedimentary Geochemistry of the Carbonate and Sulphide Systems and their Potential Influence on Toxic Metal Bioavailability

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Book cover Chemistry of Marine Water and Sediments

Part of the book series: Environmental Science ((ENVSCIENCE))

Abstract

Two of the most biogeochemically dynamic and quantitatively important components of anoxic marine sediments are the carbonate and sulphide systems. They are in many ways remarkably similar (Fig. 7.1), as they are comprised of gases, are multiple species that are similarly dissolved, they form a variety of stable and metastable minerals, and they have widely used stable and radio isotopes. Both carbon and sulphur can occur in different redox states (Table 7.1), and because the dissolved systems include diprotic acids, they also exert a major influence on pH. Their dissolved concentrations can reach values of several millimoles. Carbonate and sulphide are thus generally regarded as the “master” components for controlling Eh-pH conditions in anoxic pore waters of marine sediments.

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Authors
  1. J. W. Morse
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Editors and Affiliations

  1. Dipartimento di Chimica Inorganica, Università di Palermo, Via delle Scienze, I-90128, Palermo, Italy

    Antonio Gianguzza

  2. Dipartimento di Chimica Analitica, Università di Torino, Via Pietro Giuria 5, I-10125, Torino, Italy

    Ezio Pelizzetti

  3. Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Salita Sperone 31, I-98166, Messina, Italy

    Silvio Sammartano

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© 2002 Springer-Verlag Berlin Heidelberg

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Morse, J.W. (2002). Sedimentary Geochemistry of the Carbonate and Sulphide Systems and their Potential Influence on Toxic Metal Bioavailability. In: Gianguzza, A., Pelizzetti, E., Sammartano, S. (eds) Chemistry of Marine Water and Sediments. Environmental Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04935-8_7

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  • DOI: https://doi.org/10.1007/978-3-662-04935-8_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-07559-9

  • Online ISBN: 978-3-662-04935-8

  • eBook Packages: Springer Book Archive

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