Summary
The formation processes of free clusters and their structures are discussed using molecular dynamics simulations. The evaporation process plays an important role in generating magic number clusters of weakly bound molecules and atoms. Structures depend on the potential functions between atoms or molecules. Overall shapes of clusters generally change from linear or prolate at high temperature to spherical at low temperature, when the monomer gas is cooled to produce their aggregates. For chemically bound clusters like fullerene, the annealing process is important for making chemically stable clusters. Quantum effects of atoms are discussed using a path-integral molecular dynamics simulation.
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References
D.J. Wales, M.A. Miller, T.R. Walsh: Nature 394, 758 (1998)
T. Ikeshoji: Sci. Rept. Research Institutes Tohoku University A39, 59 (1994)
T. Ikeshoji, B. Hafskjold, Y. Hashi, Y. Kawazoe: Phys. Rev. Lett. 76, 1792 (1996)
T. Ikeshoji, B. Hafskjold, Y. Hashi, Y. Kawazoe: J. Chem. Phys. 105, 5126 (1996)
T. Ikeshoji: Surface Rev. Lett. 3, 247 (1996)
T. Ikeshoji: Sci. Rept. Research Institutes Tohoku University A43, 43 (1997)
T. Ikeshoji: In Similarities and Differences between Atomic Nuclei and Clus- ters ed. by Abe/Arai/Lee/Yabana (Amer. Inst. Phys. 1998 ) p. 427
R.A. Buckinghum: Proc. Roy. Soc. (London) A168 (1938)
J.E. Jones: Proc. Roy. Soc. (London) A106, 463 (1924)
B. Hafskjold: private communication J. Chem. Phys. 84, 3491 (1986)
W. Miehle, O. Kandler, T. Leisner, O. Echt: J. Chem. Phys. 91, 5940 (1989)
J. Farges, M.F. de Feraudy, B. Raoult, G. Torchet: J. Chem. Phys. 78, 5067 (1983)
J. Farges, M.F. de Feraudy, B. Raoult, G. Torchet: Adv. Phys. Chem. part II 70, 45 (1988)
J. Tersof: Phys. Rev. Lett. 61, 2879 (1988)
S. Maruyama, Y. Yamaguchi: Chem. Phys. Lett. 286, 343 (1998)
Y. Yamaguchi, S. Maruyama: Chem. Phys. Lett. 286, 336 (1998)
D.W. Brenner: Phys. Rev. B 42, 9458 (1990)
A.J. Stone, D.J. Wales: Chem. Phys. Lett. 128, 501 (1986)
H.C. Andersen: J. Chem. Phys. 72, 2384 (1980)
S.M. Foiles, M.I. Baskes, M.S. Daw: Phys. Rev. B 33, 7986 (1986)
W.L. Jorgensen, J. Chanfrasekhar, J.D. Madura: J. Chem. Phys. 79, 926 (1983)
G.H. Townes, A.L. Schawlow: Microwave Spectroscopy (Dover 1982 )
S. Wei, Z. Shi., A.W. Castleman: J. Chem. Phys. 94, 3268 (1991)
K. Laasonen, M.L. Klein: J. Phys. Chem. 98, 10079 (1994)
R.P. Feynman, A.R. Hibbs: Quantum Mechanics and Path Integrals (McGraw—Hill 1965 )
J. Cao, G.A. Voth: J. Chem. Phys. 99
S. Miura, S. Okazake, K. Kinugawa: J. Chem. Phys. 110, 4253 (1999) and references therein
M.P. Allen, D.J. Tildsley: Computer Simulation of Liquids (Oxford 1987 ) p. 272
P. Bopp, G. Jancso, K. Heinzenger: Chem. Phys. Lett. 98, 129 (1983)
C. Desfrancois, H. Abdoul-Carime, N. Khelifa, J.P. Schermann: J. Chem. Phys. 92, 409 (1995)
T. Ikeshoji: Prog. Theor. Phys. Supp. 138, 161 (2000)
S. Lee, J. Kim, S.J. Lee, K.S. Kim: Phys. Rev. Lett. 79 2038 (1997); K.S. Kim, S. Lee, J. Kim, J.Y. Lee: J. Amer. Chem. Soc. 119, 9329 (1997) and references therein
T. Ikeshoji, T. Nakanaga: J. Mol. Struct. (TehoChem) 138, 259 (1999)
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Ikeshoji, T. (2002). Formation of Free Clusters and Their Structures: Molecular Dynamics Simulations. In: Kawazoe, Y., Kondow, T., Ohno, K. (eds) Clusters and Nanomaterials. Springer Series in CLUSTER PHYSICS. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04812-2_11
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DOI: https://doi.org/10.1007/978-3-662-04812-2_11
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