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Raman Scattering in Materials Science pp 369–445Cite as

Raman Spectroscopic Studies of Polymer Structure

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Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 42))

Abstract

For polymer systems, Raman spectroscopy provides information concerning chemical composition, segmental orientation, conformational distribution, and phase identification. The technique is extremely versatile in that information can be obtained for liquid or solid (film, bulk or fiber) samples, ordered or disordered. The Raman intensity from vibrations associated with polymer backbone bonds is especially intense, and most structural information is contained in bands arising from these modes. Because of the availability of laser sources that produce highly polarized radiation capable of being focused to a volume of order 1 µm, sample anisotropy can be determined with accuracy, speed and high spatial resolution. Low lying vibrations (< 200 cm−1) that originate from skeletal deformation modes or interchain interactions are easily accessible in Raman spectroscopy and yield much information regarding the microscopic structure of the 3-dimensional state. Increases in computation power and analysis capability have also greatly enhanced the utility of this technique.

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  1. Shaw Ling Hsu
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  1. Physics Department MD3028/SRL, Ford Motor Company, 48121-2053, Dearborn, MI, USA

    Willes H. Weber (Principal Research Scientist) (Principal Research Scientist)

  2. Department of Physics, 500 East University, University of Michigan, 48109-1120, Ann Arbor, MI, USA

    Roberto Merlin

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Hsu, S.L. (2000). Raman Spectroscopic Studies of Polymer Structure. In: Weber, W.H., Merlin, R. (eds) Raman Scattering in Materials Science. Springer Series in Materials Science, vol 42. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04221-2_11

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