Abstract
The application of Raman spectroscopy to the characterization and study of the physical properties of fullerenes and related carbon-based materials is reviewed. Carbon can exhibit different arrangements in the solid state, such as the well known graphite and diamond structures, as well as the more recently discovered structures based on fullerenes and carbon nanotubes. Each one of these structural arrangements exhibits a characteristic Raman spectrum. The classification of the vibrational modes and their characteristic Raman spectra are presented for these different forms of carbon. The effect on the characteristic Raman spectra of various perturbations, such as disorder, doping, and variation of temperature and pressure, is reviewed. Since some of these structures exhibit electronic interband separations close to the energy of the exciting photons, the resonant behavior of the various Raman spectra is also discussed.
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Dresselhaus, M.S., Pimenta, M.A., Eklund, P.C., Dresselhaus, G. (2000). Raman Scattering in Fullerenes and Related Carbon-Based Materials. In: Weber, W.H., Merlin, R. (eds) Raman Scattering in Materials Science. Springer Series in Materials Science, vol 42. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04221-2_10
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