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Introduction — Environmental Analytical Chemistry as a Tool for Studying Chemical Processes in Marine Environments

  • A. Gianguzza
  • E. Pelizzetti
  • S. Sammartano
Part of the Environmental Science book series (ESE)

Abstract

The marine analytical chemist must be aware that the constituents — dissolved and suspended — of sea water have a three-dimensional distribution pattern. In contrast to distribution patterns in a mineral resource or in a batch of ore, distribution patterns in the marine environment are influenced by chemical, biological and physical processes, resulting in pronounced variability of individual patterns. Very often, only the general features of such a distribution pattern are known before seawater analysis is carried out. The optimal approach, therefore, presupposes an understanding of the marine environment and of the wide variety of chemical processes influencing the distribution of the compounds under examination. This means the marine analytical chemist is forced to have a reasonable knowledge of chemical oceanography.

Keywords

Organometallic Compound Global Biogeochemical Cycle Hyphenated Technique Technology Library Chemical Oceanography 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. Agrell C, Okla L, Larsson P, Blacke C, Wania F (1999) Evidence of latitudinal fractionation of polychlorinated byphenil congeners along the Baltic Sea region. Environ Sci Technol 33: 1149–1156CrossRefGoogle Scholar
  2. Alves LC, Allen LA, Houk RS (1993) Measurements of vanadium, nickel and arsenic in seawater and urine reference materials by inductively-coupled plasma mass spectrometry with cryogenic desolvation. Anal Chem 65: 2468CrossRefGoogle Scholar
  3. Baes CF, Mesmer RE (1976) The hydrolysis of cations. Interscientia, New YorkGoogle Scholar
  4. Baker JI, Hites RA (1999) Polychlorinated dibenzo-p-dioxins and dibenzofurans in the remote North Atlantic marine atmosphere. Environ Sci Technol 33: 14–20CrossRefGoogle Scholar
  5. Bloom NS, Gill GA, Cappellino S, Dobbs C, Mcshea L, Driscoll C, Mason R, Rudd J (1999) Speciation and cycling of mercury in Lavaca Bay, Texas, sediments. Environ Sci Technol 33: 7–13Google Scholar
  6. Bruland KW (1983) Trace elements in sea water. In: Riley JP, Chester R (eds) Chemical oceanography, znd ed, vol VIII. Academic Press, London, pp 157–220Google Scholar
  7. Champ MA, Seligman, PF (eds.) (1996). Organotin. Environmental fate and effects. Chapman and Hall, LondonGoogle Scholar
  8. Craig PJ (ed) (1986) Organometallic compounds in the environment. Principles and reactions. Longman, Harlow EssexGoogle Scholar
  9. Craig PJ, Miller D (1997) Metal ions and organometallic compounds in sea water and in sediments: Biogeochemical cycles. In: Gianguzza A, Pelizzetti E, Sammartano S (eds) Marine chemistry–an environmental analytical chemistry approach. Kluwer Academic, Dordrecht (Water Science and Technology Library, vol XXV, pp 85–98 )Google Scholar
  10. Farago ME (1997) Arsenic in the marine environment. In: Gianguzza A, Pelizzetti E, Sammartano S (eds) Marine chemistry–an environmental analytical chemistry approach. Kluwer Academic, Dordrecht (Water Science and Technology Library, vol XXV, pp 275–292 )Google Scholar
  11. Harner T, Kylin H, Bidleman TF, Strachan WMJ (1999) Removal of alpha-and gamma-hexachlorocycloexane and enantiomers of alpha-hexachlorocycloexane in the Eastern Artic Ocean. Environ Sci Technol 33x157–1164Google Scholar
  12. Hedges J (1992) Global biogeochemical cycles: progress and problems. Mar Chem 39: 67–93CrossRefGoogle Scholar
  13. Martin JH, Fitzwater SE (1992) Dissolved organic carbon in the Atlantic, Southern and Pacific Oceans. Nature 356: 699–700CrossRefGoogle Scholar
  14. Morel FMM (1983) Principles of aquatic chemistry. John Wiley andSons, New YorkGoogle Scholar
  15. Millero FJ (1996) Chemical oceanography, znd edn. CRC Press, Boca RatonGoogle Scholar
  16. Millero FJ (1999) Physical chemistry of natural waters. CRC Press, Boca RatonGoogle Scholar
  17. Quay PD, ilbrook B, Wong CS (1992) Oceanic uptake of fossil fuel CO2: carbon-13 evidence. Science 256: 74CrossRefGoogle Scholar
  18. Sadiq M (1992) Toxic metal chemistry in marine environments. Marcel Dekker Inc., New YorkGoogle Scholar
  19. Solomons W, Forstner U (1984) Metals in the hydrocycle. Springer Verlag, MünchenCrossRefGoogle Scholar
  20. Stumm W, Brauner PA (1975) Chemical speciation. In: Riley JP, Skirrow G (eds) Chemical oceanography, 2nd edn, vol I. Academic Press, London, pp 173–240Google Scholar
  21. Stumm W, Morgan JJ (1996) Aquatic chemistry, 3rd edn. John Wiley and Sons, New YorkGoogle Scholar
  22. Sugimura Y, Suzuki Y (1988) High temperature catalytic oxidation method for the determination of non volatile dissolved organic carbon in seawater by direct injection of a liquid sample. Mar Chem 24: 105–112CrossRefGoogle Scholar
  23. Tessier A, Turner DR (1995) Metal speciation and bioavailability in aquatic systems. John Wiley and Sons, Chichester (IUPAC Series on Analytical and Physical Chemistry of Environmental Systems, vol I II )Google Scholar
  24. Tittlemeier SA, Simon M, Jarman WM, Elliott JE, Norstrom RJ (1999) Identification of a novel C10H6N2Br4C12 heterocyclic compound in seabird eggs. A bioaccumulation marine natural products? Environ Sci Technol 33: 26–33CrossRefGoogle Scholar
  25. Van Den Berg CMG (1989) Electroanalytical chemistry of sea water. In: Riley JP (ed) Chemical oceanography, vol IX. Academic Press, London, pp 197–245Google Scholar
  26. Vincenti M (1997) Application of mass spectrometric techniques to the detection of natural and anthropogenic substances in the sea. In: Gianguzza A, Pelizzetti E, Sammartano S (eds) Marine chemistry–an environmental analytical chemistry approach. Kluwer Academic, Dordrecht (Water Science and Technology Library, vol XXV, pp 189–210 )Google Scholar
  27. Yang XH, Lee C, Seranton MI (1993) Determination of nanomolar concentrations of individual dissolved low molecular weight amines and organic acids in seawater. Anal Chem65: 572Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2000

Authors and Affiliations

  • A. Gianguzza
  • E. Pelizzetti
  • S. Sammartano

There are no affiliations available

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