Skip to main content

Redox Fronts in Aquifer Systems and Parameters Controlling their Dimensions

  • Chapter
Redox

Abstract

Most hydrochemical systems are to a large extent characterised by redox-processes which may lead to secondary reactions as a result of changing geochemical equilibria. They depend on the abundance of oxidising and reducing agents. Driven by the oxidation of organic substance which may either be dissolved in the liquid phase or bound to solids, a typical sequence of events in the consumption of oxidising agents is determined by the decreasing energy budget along the reaction path from the oxic zone into the zone of methanogenesis.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Berner, R.A. (1981): Early diagenesis: A theoretical approach. Princeton University Press, 241 pp.

    Google Scholar 

  • Bradley, P.M.; Fernandez, JR., M. and Chapelle, F.H. (1992): Carbon limitation of denitrification rates in an anaerobic groundwater system. Environ. Sci. Technol. 26: 2377–2381.

    Google Scholar 

  • Calvert, S.E. & Pedersen, T.F. (1993): Geochemistry of recent oxic and anoxic marine sediments: Implications for the geological record. Mar. Geol. 113: 67–88.

    Google Scholar 

  • Christensen, B. (1997): Geochemische Charakterisierung eines Sedimentkernes aus dem Stausee Hengsen (Schwerte). unveröff. Diplomarbeit, Fachbereich Geowissenschaften, Universität Bremen, 85 pp.

    Google Scholar 

  • Cord-Ruwisch, R.; Seitz, H.-J. & Conrad, R. (1988): The capacity of hydrogentropohic anaerobic bacteria to compete for traces of hydrogen depends on the redox potential of the terminal electron acceptor. Arch. Microbiol. 149: 350–357.

    Google Scholar 

  • Francois, R. (1988): A study on the regulation of the concentration of some trace metals (Rb, Sr, Zn, Pb, Cu, V, Cr, Ni, Mn and Mo) in Saanich Inlet sediments, British Columbia, Canada. Mar. Geol. 83: 285–308.

    Google Scholar 

  • Hencke, J. (1998): Redoxreaktionen im Grundwasser: Etablierung und Verlagerung von Reaktionsfronten und ihre Bedeutung für die Spurenelement-Mobilität. Ber. Fachber. Geowissenschaften Univ. Bremen 128: 122 pp.

    Google Scholar 

  • Huettel, M.; Ziebis, W.; Forster, S.; Luther III, G.W. (1998): Advective transport affecting metal and nutrient distributions and interfacial fluxes in permeable sediments. Geochim. Cosmochim. Acta 62: 613–631.

    Google Scholar 

  • Kolle, W.; Werner, P.; Strebel, O. and Böttcher, J. (1983): Denitrifikation in einem reduzierenden Grundwasserleiter. Vom Wasser 61: 125–147.

    Google Scholar 

  • Landenberger, H. (1998): CoTReM, ein Multi-Komponenten Transport-und ReaktionsModell. Ber. Fachber. Geowissenschaften Univ. Bremen 110: 142 pp.

    Google Scholar 

  • Lensing, H.J. (1995): Numerische Modellierung mikrobieller Abbauprozesse im Grundwasser. Mitt. Inst. Hydrologie und Wasserwirtschaft Univ. Karlsruhe. 51: 185 pp.

    Google Scholar 

  • Lovley, D.R. & Goodwin, S. (1988): Hydrogen concentrations as an indicator of the predominant terminal electron-accepting reactions in aquatic sediments. Geochim. Cosmochim. Acta 52, 2993–3003.

    Google Scholar 

  • Lovley, D.R. & Phillips. E.J.P. (1987): Competitive mechanisms for the inhibition of sulfate reduction and methane production in the zone of ferric iron reduction in sediments. Appl. Environ. Microbiol. 53, 2636–2641.

    Google Scholar 

  • Postma, D.; Boesen, C.; Kristiansen, H. & Larsen, F. (1991): Nitrate reduction in an unconfined sandy aquifer: water chemistry, reduction processes and geochemical modeling. Water Resour. Res. 27, 2027–2045.

    Google Scholar 

  • Postma, D. & Jakobsen, R. (1996): Redox zonation: Equilibrium constraints on the Fe(III)/SO4-reduction interface. Geochim. Cosmochim. Acta 60, 3169–3175.

    Google Scholar 

  • Rowe, R.K. (1987): Pollutant transport through barriers. Proc. Geotech. Practice for Waste Disposal `87, 159–181.

    Google Scholar 

  • Schottler, U. & Sommer, H. (1987): Hydrogeologische Untersuchung des Ruhrtals im Bereich der Wassergewinnungsanlagen der Dortmunder Stadtwerke AG. Bericht der Dortmunder Stadtwerke AG 5.

    Google Scholar 

  • Schulte-Ebbert, U.; Hollerung, R.; Willme, U.; Kaczmarczyk, B.; Bahrig, B. & Schöttler, U. (1991): Verhalten von anorganischen Spurenstoffen bei wechselnden Redoxverhältnissen im Grundwasser. Dortmunder Beiträge zur Wasserforschung 43: 358 pp.

    Google Scholar 

  • Schulte-Ebbert, U. & Schottler, U. (1995): Systemanalyse des Untersuchungsgebietes „Insel Hengsen“. In: Schöttler, U. and Schulte-Ebbert, U. (Eds.): Schadstoffe im Grundwasser — Bd. 3: Verhalten von Schadstoffen im Untergrund bei der Infiltration von Oberflächenwasser am Beispiel des Untersuchungsgebietes „Insel Hengsen” im Ruhrtal bei Schwerte. VCH Weinheim, 475–513.

    Google Scholar 

  • Selenka, F. & Hack, A. (1992): Quantifizierung und Charakterisierung der organischen Substanz am Korngerüst des Bodens und der Sedimente im Versuchsfeld Hengsen. unpubl. report of the working group „Gewinnung von Festmaterial für Analysen und Laborversuche“ of DFG-Priority Program „Schadstoffe im Grundwasser”, DFG Bonn, 231 pp.

    Google Scholar 

  • Van Beek, C.G.E.M.; Boukes, H.; Van Rijsbergen, D. & Straatman, R. (1988): The threat to the Netherlands waterworks by nitrate in the abstracted groundwater, as demonstrated on the well field Vierlingsbeek. Wat. Supply 6, 313–318.

    Google Scholar 

  • Van Beek, C.G.E.M. & VAN Der Kooij, D. (1982): Sulfate-reducing bacteria in groundwater from clogging and nonclogging shallow wells in the Netherlands river region. Ground Water 20, 298–302.

    Article  Google Scholar 

  • Wendland, F.; Albert, H.; Bach, M. & Schmidt, R. (1994): Potential nitrate pollution of groundwater in Germany: A supraregional differentiated model. Envir. Geol. 24, 1–6.

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2000 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Schüring, J., Schlieker, M., Hencke, J. (2000). Redox Fronts in Aquifer Systems and Parameters Controlling their Dimensions. In: Schüring, J., Schulz, H.D., Fischer, W.R., Böttcher, J., Duijnisveld, W.H.M. (eds) Redox. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04080-5_11

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-04080-5_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-08581-9

  • Online ISBN: 978-3-662-04080-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics