Skip to main content

Redox Potential Measurements in Natural Waters: Significance, Concepts and Problems

  • Chapter
Redox

Abstract

The characterisation of redox conditions in natural aquatic systems is both of scientific and of practical significance. The biogeochemical processes in anoxic systems have been studied in many instances in lakes, sediments and groundwater (e.g. Heron et al., 1994; Urban et al., 1997). To which extent the redox reactions occur in a certain system and which reduced species are present, such as reduced iron, manganese(II) and sulfide, is significant with regard to many practical problems, like use of groundwater for drinking water or remediation of contaminated sites. With regard to groundwater, the redox conditions downstream of landfills, which release large amounts of degradable compounds, need to be understood and characterised (Amirbahman et al., 1998; Heron & Christensen, 1995).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Amirbahman, A.; Schönenberger, R.; Johnson, C.A. & Sigg, L. (1998): Aqueous phase biogeochemistry of a calcareous aquifer system downgradient from a municipal solid waste landfill ( Winterthur, Switzerland). Environ. Sci. Technol. 32: 1933–1940.

    Article  Google Scholar 

  • Bard, A.J. & Faulkner, L.R. (1980): Electrochemical methods; fundamentals and applications. John Wiley & Sons, New York.

    Google Scholar 

  • Bockris, J.O.M. & Reddy, A.K.N. (1973): Modern electrochemistry. Plenum/Rosetta, New York.

    Book  Google Scholar 

  • Boller, M.; Gujer, W. & Tschui, M. (1994): Parameters affecting nitrifying biofilm reactors. Wat. Sci. Tech. 29: 1–11.

    Google Scholar 

  • Diem, D. & Stumm, W. (1984): Is dissolved Mn2+ being oxidized by 02 in absence of Mn-bacteria or surface catalysts? Geochim. Cosmochim. Acta 48: 1571–1573

    Article  Google Scholar 

  • Grenthe, I.; Stumm, W.; Laaksuharju, M.; Nilsson, A.-C. & WIKBERG, P. (1992): Redox potentials and redox reactions in deep groundwater systems. Chem. Geol. 98: 131–150.

    Article  Google Scholar 

  • Hamilton-Taylor, J. & Davison, W. (1995): Redox-driven cycling of trace elements in lakes. In: LERMAN, A.; IMBODEN, D.M. & GAT, J.R. (Eds.): Physics and chemistry of lakes. Springer-Verlag, Berlin. pp 217–263.

    Chapter  Google Scholar 

  • Heron, G. & Christensen, T.H. (1995): Impact of sediment-bound iron on redox buffering in a landfill leachate polluted aquifer ( Vejen, Denmark). Environ. Sci. Technol. 29: 187–192.

    Article  Google Scholar 

  • Heron, G.; Christensen, T.H. & Tjell, J.C. (1994): Oxidation capacity of aquifer sediments. Environ. Sci. Technol. 28: 153–158.

    Article  Google Scholar 

  • Kempton, J.H.; Lindberg, R.D. & Runnells, D.D. (1990): Numerical modeling of platinum Eh measurements by using heterogeneous electron-transfer kinetics. In: MELCHIOR, D.C. & BASSETT, R.L. (Eds.): Chemical modeling of aqueous systems II. ACS, Washington DC. pp 339–349.

    Chapter  Google Scholar 

  • Kuhn, A. & SIGG, L. (1993): Arsenic cycling in eutrophic Lake Greifen, Switzerland: Influence of seasonal redox processes. Limnol. Oceanogr. 38: 1052–1059.

    Article  Google Scholar 

  • Lindberg, R.D. & Runnells, D.D. (1984): Ground water redox reactions: an analysis of equi- librium state applied to Eh measurements and geochemical modeling. Science 225: 925–927.

    Article  Google Scholar 

  • Macalady, D.L.; Langmuir, D.; Grundl, T. & Elzerman, A. (1990): Use of model-generated Fe3+ ion activities to compute Eh and ferric oxyhydroxide solubilities in anaerobic systems. In: Melchior, D.C. & Bassett, R.L. (Eds.): Chemical modeling of aqueous systems II. ACS, Washington DC. pp 350–367.

    Chapter  Google Scholar 

  • Peiffer, S.; Klemm, O.; Pecher, K. & Hollerung, R. (1992): Redox measurements in aqueous solutions - a theoretical approach to data interpretation, based on electrode kinetics. J. Cont. Hydrol. 10: 1–18.

    Article  Google Scholar 

  • Schwarzenbach, R.P.; Angst, W.; Holliger, C.; HUG, S.J. & Klausen, J. (1997): Reductive transformations of anthropogenic chemicals in natural and technical systems. Chimia 51: 908–914.

    Google Scholar 

  • Sigg, L.; Johnson, C.A. & Kuhn, A. (1991): Redox conditions and alkalinity generation in a seasonally anoxic lake (Lake Greifen). Mar. Chem. 36: 9–26.

    Article  Google Scholar 

  • Stumm, W. & Morgan, J.J. (1970): Aquatic chemistry. Wiley-Interscience, New York. STUMM, W. & MORGAN, J.J. (1996): Aquatic chemistry. Wiley-Interscience, New York. Sulzberger, B.; Canonica, S.; EGLI, T.; GIGER, W.; KLAUSEN, J. & VON GUNTEN, U. (1997): Oxidative transformations of contaminants in natural and technical systems. Chimia 51: 900–907.

    Google Scholar 

  • Urban, N.R.; Dinkel, C. & Wehrli, B. (1997): Solute transfer across the sediment surface of a eutrophic lake: I. Porewater profiles from dialysis samplers. Aquat. Sci. 59: 1–25.

    Article  Google Scholar 

  • Von Langen, P.J.; Johnson, K.S.; Coale, K.H. & Elrod, V.A. (1997): Oxidation kinetics of manganese (II) in seawater at nanomolar concentrations. Geochim. Cosmochim. Acta 61: 4945–4954.

    Article  Google Scholar 

  • Whitfield, M. (1974): Thermodynamic limitations on the use of the platinum electrode EH measurements. Limnol. Oceanogr. 19: 857–865.

    Article  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2000 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Sigg, L. (2000). Redox Potential Measurements in Natural Waters: Significance, Concepts and Problems. In: Schüring, J., Schulz, H.D., Fischer, W.R., Böttcher, J., Duijnisveld, W.H.M. (eds) Redox. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04080-5_1

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-04080-5_1

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-08581-9

  • Online ISBN: 978-3-662-04080-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics