Abstract
The characterisation of redox conditions in natural aquatic systems is both of scientific and of practical significance. The biogeochemical processes in anoxic systems have been studied in many instances in lakes, sediments and groundwater (e.g. Heron et al., 1994; Urban et al., 1997). To which extent the redox reactions occur in a certain system and which reduced species are present, such as reduced iron, manganese(II) and sulfide, is significant with regard to many practical problems, like use of groundwater for drinking water or remediation of contaminated sites. With regard to groundwater, the redox conditions downstream of landfills, which release large amounts of degradable compounds, need to be understood and characterised (Amirbahman et al., 1998; Heron & Christensen, 1995).
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References
Amirbahman, A.; Schönenberger, R.; Johnson, C.A. & Sigg, L. (1998): Aqueous phase biogeochemistry of a calcareous aquifer system downgradient from a municipal solid waste landfill ( Winterthur, Switzerland). Environ. Sci. Technol. 32: 1933–1940.
Bard, A.J. & Faulkner, L.R. (1980): Electrochemical methods; fundamentals and applications. John Wiley & Sons, New York.
Bockris, J.O.M. & Reddy, A.K.N. (1973): Modern electrochemistry. Plenum/Rosetta, New York.
Boller, M.; Gujer, W. & Tschui, M. (1994): Parameters affecting nitrifying biofilm reactors. Wat. Sci. Tech. 29: 1–11.
Diem, D. & Stumm, W. (1984): Is dissolved Mn2+ being oxidized by 02 in absence of Mn-bacteria or surface catalysts? Geochim. Cosmochim. Acta 48: 1571–1573
Grenthe, I.; Stumm, W.; Laaksuharju, M.; Nilsson, A.-C. & WIKBERG, P. (1992): Redox potentials and redox reactions in deep groundwater systems. Chem. Geol. 98: 131–150.
Hamilton-Taylor, J. & Davison, W. (1995): Redox-driven cycling of trace elements in lakes. In: LERMAN, A.; IMBODEN, D.M. & GAT, J.R. (Eds.): Physics and chemistry of lakes. Springer-Verlag, Berlin. pp 217–263.
Heron, G. & Christensen, T.H. (1995): Impact of sediment-bound iron on redox buffering in a landfill leachate polluted aquifer ( Vejen, Denmark). Environ. Sci. Technol. 29: 187–192.
Heron, G.; Christensen, T.H. & Tjell, J.C. (1994): Oxidation capacity of aquifer sediments. Environ. Sci. Technol. 28: 153–158.
Kempton, J.H.; Lindberg, R.D. & Runnells, D.D. (1990): Numerical modeling of platinum Eh measurements by using heterogeneous electron-transfer kinetics. In: MELCHIOR, D.C. & BASSETT, R.L. (Eds.): Chemical modeling of aqueous systems II. ACS, Washington DC. pp 339–349.
Kuhn, A. & SIGG, L. (1993): Arsenic cycling in eutrophic Lake Greifen, Switzerland: Influence of seasonal redox processes. Limnol. Oceanogr. 38: 1052–1059.
Lindberg, R.D. & Runnells, D.D. (1984): Ground water redox reactions: an analysis of equi- librium state applied to Eh measurements and geochemical modeling. Science 225: 925–927.
Macalady, D.L.; Langmuir, D.; Grundl, T. & Elzerman, A. (1990): Use of model-generated Fe3+ ion activities to compute Eh and ferric oxyhydroxide solubilities in anaerobic systems. In: Melchior, D.C. & Bassett, R.L. (Eds.): Chemical modeling of aqueous systems II. ACS, Washington DC. pp 350–367.
Peiffer, S.; Klemm, O.; Pecher, K. & Hollerung, R. (1992): Redox measurements in aqueous solutions - a theoretical approach to data interpretation, based on electrode kinetics. J. Cont. Hydrol. 10: 1–18.
Schwarzenbach, R.P.; Angst, W.; Holliger, C.; HUG, S.J. & Klausen, J. (1997): Reductive transformations of anthropogenic chemicals in natural and technical systems. Chimia 51: 908–914.
Sigg, L.; Johnson, C.A. & Kuhn, A. (1991): Redox conditions and alkalinity generation in a seasonally anoxic lake (Lake Greifen). Mar. Chem. 36: 9–26.
Stumm, W. & Morgan, J.J. (1970): Aquatic chemistry. Wiley-Interscience, New York. STUMM, W. & MORGAN, J.J. (1996): Aquatic chemistry. Wiley-Interscience, New York. Sulzberger, B.; Canonica, S.; EGLI, T.; GIGER, W.; KLAUSEN, J. & VON GUNTEN, U. (1997): Oxidative transformations of contaminants in natural and technical systems. Chimia 51: 900–907.
Urban, N.R.; Dinkel, C. & Wehrli, B. (1997): Solute transfer across the sediment surface of a eutrophic lake: I. Porewater profiles from dialysis samplers. Aquat. Sci. 59: 1–25.
Von Langen, P.J.; Johnson, K.S.; Coale, K.H. & Elrod, V.A. (1997): Oxidation kinetics of manganese (II) in seawater at nanomolar concentrations. Geochim. Cosmochim. Acta 61: 4945–4954.
Whitfield, M. (1974): Thermodynamic limitations on the use of the platinum electrode EH measurements. Limnol. Oceanogr. 19: 857–865.
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Sigg, L. (2000). Redox Potential Measurements in Natural Waters: Significance, Concepts and Problems. In: Schüring, J., Schulz, H.D., Fischer, W.R., Böttcher, J., Duijnisveld, W.H.M. (eds) Redox. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-04080-5_1
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DOI: https://doi.org/10.1007/978-3-662-04080-5_1
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