Abstract
This chapter describes analytical methods that are applicable for the characterization of the chemical composition of fibers as such, without a previous separation of the components or component groups from each other. Although the details of the structure and composition generally can be obtained only to a limited extent, these direct methods possess definite advantages. For example, a minimum of preparation is required. Often samples can be analyzed more or less directly and, in some cases, the lateral and vertical distribution of different chemical structures in the fibers can be determined. The methods can be roughly divided into the following groups:
-
1.
“Dry” methods for the characterization of structural features of fiber constituents. These methods include different spectroscopies: nuclear magnetic resonance (NMR), infrared (IR), Raman and ultraviolet/visible (UV/Vis) as well as pyrolysis gas chromatography (Py-GC).
-
2.
“Dry” methods for the surface analysis of fibers. By far the most important of these methods are electron spectroscopy for chemical analysis (ESCA), also known as X-ray photoelectron spectroscopy (XPS), and secondary ion mass spectroscopy (SIMS).
-
3.
“Wet” methods for the determination of the amounts of different components and functional groups in the fibers as a whole or on the fiber surfaces by using both chemical and enzymatic treatments.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Agarwal UP, Atalla RH 1995 Raman spectroscopy. In: Conners TE, Banerjee S (eds) Surface analysis of paper. CRC Press, New York 152–181
Alén R, Kuoppala E, Oesch P 1996 Formation of the main degradation compound groups from wood and its components during pyrolysis. J Anal Appl Pyrolysis 36: 137–148
Arisz PW, Lomax JA, Boon JJ 1990 High-performance liquid chromatography/chemical ionization mass spectrometric analysis of pyrolysates of amlylose and cellulose. Anal Chem 62: 1519–1522
Atalla RH, Agarwal UP 1986 Recording Raman spectra from plant cell walls. J Raman Spectrosc 17: 229–231
Briggs D, Beamson G 1992 High resolution XPS of organic polymers. Wiley, New York, 306 pp Briggs D, Brown A, Vickerman JC 1989 Handbook of static secondary ion mass spectrometry SIMS. Wiley, New York, 164 pp
Briggs D, Seah MP (eds) 1990 Practical surface analysis vol 1. Auger and X-ray photoelectron spectroscopy, 2nd edn. Wiley, New York, 674 pp
Briggs D, Seah MP (eds) 1992 Practical surface analysis vol 2. Ion and neutral spectroscopy, 2nd edn. Wiley, New York, 738 pp
Brinen JS, Greenhouse S, Dunlop-Jones N 1991 SIMS imaging: a new approach for studying paper surfaces. Nord Pulp Pap Res J 1: 30–36
Brinen JS, Proverb RJ 1993 SIMS imaging of paper surfaces. Part 2. Distribution of organic surfactants. Nord Pulp Pap Res J 4: 177–183
Buchert J, Siika-Aho M, Bailey M, Puls J, Valkeajärvi A, Pere J, Viikari L 1993 Quantitative determination of wood-derived soluble oligosaccharides by HPLC. Biotechnol Tech 7: 785790
Buchert J, Teleman A, Harjunpää V, Tenkanen M, Viikari L, Vuorinen T 1995 Effect of cooking and bleaching on the structure of xylan in conventional pine kraft pulp. Tappi 78 (11): 125–130
Conners TE, Banerjee S (ed) 1995 Surface analysis of paper. CRC Press, Boca Raton, 346 pp
Detter-Hoskin LD, Busch KL 1995 SIMS: secondary ion mass spectrometry. In: Conners TE, Banerjee S (ed) Surface analysis of Paper. CRC Press, Boca Raton, 207–234
Dorris GM, Gray DG 1978a The surface analysis of paper and wood fibers by ESCA I. Application to cellulose and lignin. Cellul Chem Technol 12: 9–23
Dorris GM, Gray DG 1978b The surface analysis of paper and wood fibers by ESCA. II. Surface composition of mechanical pulps. Cellul Chem Technol 12: 721–734
Engstrand P, Sjögren B, Olander K, Htun M 1991 The significance of carboxylic groups for the physical properties of mechanical pulp fibers. Proc 6th Int Symp Wood and Pulping Chem, Melbourne, Australia 1: 75–79
Eriksson E, Sjöström E 1968 The influence of acidic groups on the physical properties of high yield pulps. Tappi J 51 (1): 56–59
Faix O 1992 Fourier transform infrared spectroscopy. In: Lin SY, Dence CW (eds) Methods in lignin chemistry. Springer, Berlin Heidelberg New York, 83–109
Friese MA, Banerjee S 1995 FTIR spectroscopy. In: Conners TE, Banerjee S (ed) Surface analysis of paper. CRC Press, Boca Raton, 119–141
Gellerstedt G, Lindfors E 1984 Structural changes in lignins during kraft cooking. Part 4. Phenolic hydroxyl groups in wood and kraft pulps. Sven Papperstidn 87: R115 - R118
Gran G 1950 Determination of the equivalent point in potentiometric titrations. Acta Chem Scand 4: 559–577
Gray DG 1978 The surface analysis of paper and wood fibers by ESCA. III. Interpretation of carbon is peak shape. Cellul Chem Technol 12: 735–743
Hatfield GR, Sardashti M, Maciel GE 1987 Analysis of molecular orientational order in solid samples by nuclear magnetic resonance: application to lignin and cellulose in wood. Anal Chem 59: 1659–1664
Heitner C, Min T 1987 The effect of sulphite treatment on the brightness and bleachability of chemithermomechanical pulp. Cellul Chem Technol 21: 289–296
Helleur RJ 1987 Characterization of the saccharide composition of heteropolysaccharides by pyrolysis-capillary gas chromatography-mass spectrometry. J Anal Appl Pyrolysis 11: 297–311
Horii F, Hirai A, Kitamaru R 1983 Relationship between carbon-13 chemical shifts and conformation of oligosaccharides and cellulose in the solid state. Bull Magn Reson 5: 190–195
Istone WK 1995 X-Ray photoelectron spectroscopy XPS. In: Conners TE, Banerjee S (eds) Surface analysis of paper. CRC Press, Boca Raton, 235–268
Katz S, Beatson RP, Scallan AM 1984 The determination of strong and weak acidic groups in sulphite pulps. Sevensk Papperstidn 87 (6): R48–53
Kleen M 1993 Characterization of wood and pulp using analytical pyrolysis and multivariate data analysis. Dissertation, Royal Institute of Technology, Stockholm
Kulick RJ, Brinen JS 1996 Probing paper surfaces with TOF SIMS–a new tool for problem solving. Proc Tappi Papermakers Conf 325–334
Kushelevsky AP, Slifkin MA 1987 Photoacoustic spectroscopy of printing inks. J Oil Colour Chem Assoc 70: 99–101
Lai Y-Z, Guo X, Situ W 1990 Estimation of phenolic hydroxyl groups in wood by a peroiodate oxidation method. J Wood Chem Technol 10: 365–377
Laine J, Buchert J, Viikari L, Stenius P 1996 Characterization of unbleached kraft pulps by enzymatic treatment, potentiometric titration and polyelectrolyte adsorption. Holzforschung 50: 208–214
Laine J, Lövgren L, Stenius P, Sjöberg S 1994 Potentiometric titration of unbleached kraft cellulose fibre surfaces. Coll Surf A 88: 277–287
Laine J, Stenius P 1997 The effect of charge on the fibre and paper properties of bleached industrial kraft pulps. Pap Puu 79 (4): 257–266
Laine J, Stenius P, Carlsson G, Ström G 1994 Surface characterization of unbleached kraft pulps by means of ESCA. Cellulose 1: 145–160
Larsson N, Stenius P, Eriksson JC, Maripuu R, Lindberg B 1982 ESCA studies of sulphated polyethylene surfaces modified by adsorption of polyethyleneimine and colloidal silica particles. J Colloid Interface Sci 90: 127–136
Larsson PT, Wickholm K, Iversen T 1997 A CP/MAS 13C NMR investigation of molecular ordering in celluloses. Carbohydr Res 302: 19–25
Leary GJ, Lloyd JA, Morgan KR 1988 A CP/MAS 13C NMR study of residual lignin in kraft pulps. Holzforschung 42: 199–202
Lindström T, Carlsson G 1982a The effect of chemical environment on fibre swelling. Svensk Papperstidn 85 (1): R14 - R20
Lindström T, Carlsson G 1982b The effect of carboxyl groups and their ionic form during drying on the hornification of cellulose fibers. Svensk Papperstidn 85 (3): R146 - R151
Meier D, Faix O 1992 Pyrolysis-gas chromatography-mass spectrometry. In: Lin SY, Dence CW (eds) Methods in lignin chemistry. Springer, Berlin Heidelberg New York, 177–199
Mitikka M, Teeäär R, Tenkanen M, Laine J, Vuorinen T 1995 Sorption of xylans on cellulose fibers. Proc 8th Int Symp Wood and Pulping Chem, Helsinki, 111: 231–236
Newman RH 1994 Crystalline forms of cellulose in softwoods and hardwoods. J Wood Chem Technol 14: 451–466
Newman RH, Hemmington JA 1990 Determination of the degree of cellulose crystallinity in wood by carbon-13 nuclear magnetic resonance spectroscopy. Holzforschung 44: 351–355
Saastamoinen S, Likonen J, Neimo L, Paulapuro H, Stenius P 1994 SIMS study of the adsorption of calcium and aluminum ions on unbleached and hydrogen peroxide bleached pressurized groundwood. Pap Puu 76 (1–2): 74–80
Scallan AM, Katz S, Argyropoulos DS 1988 Conductometric titration of cellulosic fibers. In: Schuerch C (ed) Cellulose and wood–chemistry and technology. Wiley, New York, 1457–1471
Schrader B 1995 General survey of vibrational spectroscopy. In: Schrader B (ed) Infrared and Raman spectroscopy. VCH, Weinheim, 7–61
Scott JAN, Procter AR, Fergus BJ, Goring DAI 1969 The application of UV microscopy to the distribution of lignin in wood. Description and validity of the technique. Wood Sci Technol 3: 73–92
Shafizadeh F, Fu YL 1973 Pyrolysis of cellulose. Carbohydr Res 29: 113–122
Sillén LG 1956 Some graphical methods for determining equilibrium constants. II. On “curve-fitting” methods for two-variable data. Acta Chem Scand 10: 186–202.
Sjöström E 1989 The origin of charge on cellulosic fibers. Nord Pulp Pap Res J 4: 90–93
Sjöström E 1993 Wood chemistry. Fundamentals and applications, 2nd edn. Academic Press, San Diego, 293 pp
Sjöström E, Enström B 1966 A method for the separate determination of sulpho and carboxyl groups in sulphite pulps. Svensk Papperstidn 69 (3): 55–59
Sjöström E, Eriksson E 1968 The influence of carboxyl and carbonyl groups on the brightness stability of bleached pulps. Tappi J 51 (1): 16–19
Sjöström E, Haglund P 1961 Studies on factors affecting the determination of carboxyl groups in cellulose. Svensk Papperstidn 64 (11): 438–446
Tan Z, Reeve DW 1992 Spatial distribution of organochlorine in fully bleached kraft pulp fibers. Nord Pulp Pap Res J 7: 30–36
Tenkanen M, Hausalo T, Siika-Aho M, Buchert J, Viikari L 1995 Use of enzymes in combination with anionic chromatography in the analysis of carbohydrate composition of kraft pulps. Proc 8th Int Symp Wood Pulping Chem, Helsinki, Finland 2: 189–194
Tipson RS, Parker FS 1980 Infrared spectroscopy. In: Pigman W, Horton D, Wander JD (eds) The carbohydrates, chemistry and biochemistry, 2nd edn. Academic Press, New York, 1394–1436
VanderHart DL, Atalla RH 1984 Studies of microstructure in native celluloses using solid-state 13C NMR. Macromolecules 17: 1465–1472
Vuorinen T, Buchert J, Teleman A, Tenkanen M, Fagerström P 1996 Selective hydrolysis of hexenuronic acid groups and its application in ECF and TCF bleaching of kraft pulps. Proc Int Pulp Bleaching Conf, Washington DC, 43–51
Westall J 1982 FITEQL: a computer program for determination of chemical equilibrium constants from experimental data, version 2.0. Report 82–02, Department of Chemistry, Oregon State University, Corvallis
Wâgberg L, Winter L, Lindström T 1985 Determination of ion-exchange capacity of carboxymethylated cellulose fibers using colloid and conductometric titrations. In: Punton V (ed) Papermaking raw materials. Mechanical Engineering Ltd, London 2: 917–923
Westermark U, Samuelson B 1993 A spectrophotometric method for the determination of sulfonic acids in wood material. Nord Pulp Pap Res J 8: 358–359, 398
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Stenius, P., Vuorinen, T. (1999). Direct Characterization of Chemical Properties of Fibers. In: Sjöström, E., Alén, R. (eds) Analytical Methods in Wood Chemistry, Pulping, and Papermaking. Springer Series in Wood Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03898-7_6
Download citation
DOI: https://doi.org/10.1007/978-3-662-03898-7_6
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-08317-4
Online ISBN: 978-3-662-03898-7
eBook Packages: Springer Book Archive