Abstract
The decomposition of raw materials during glass melting yields large quantities of gases [6.1]. Most of these gases, especially water vapour, sulphur dioxide, carbon dioxide, and air, are released into the furnace atmosphere, while a smaller portion either remains dissolved within the glass melt or forms bubbles. But this not the only bubble-forming mechanism.
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References
F. Krämer: “Gasprofilmessungen zur Bestimmung der Gasabgabe beim Glasschmelzprozeß”, Glastechn. Ber. 53, 177–188 (1980)
H.O. Mulfinger, F. Krämer: “Analyse von Blasen und Gasen im Glas”, in Glastechnische Fabrikationsfehler, ed. by H. Jebsen-Marwedel, R. Brückner (Springer, Berlin, Heidelberg 1980) pp. 162–179
E.K. Ware, P.P. Pirooz: “Gas adsorption on freshly broken glass surfaces -a source of error in analysis of bubbles in glass”, Glass Technol. 8, 86–87 (1967)
H.O. Mulfinger: “Analyse des Inhalts von Gasblasen im Glas”, Glastechn. Ber. 44, 467–473 (1971)
V.O. Altemose: “Mass spectrometry for the analysis of bubbles in glass”, in Gas Bubbles in Glass, TC14 Report Int. Comm. Glass (Institut National du Verre, Charleroi, Belgium 1985) pp. 64–73
R.L. Schick, E.L. Swarts: “Mass spectrometric analysis of bubbles in glass”, J. Am. Ceram. Soc. 65, 594–597 (1982)
H. Knödler, J.P. Bock, W. Knatz: “Mass spectrometer analysis of the contents of bubbles in glasses in the picoliter range”, Glastechn. Ber. 52, 31–42 (1979)
J.E. Fenstermacher: “Analysis of gases entrapped in glass using a mass spectrometer-ultra high vacuum system”, J. Vac. Sci. Technol. 8, 380–384 (1971)
A. Götz, InProcess Instruments, Otto-Lilienthal-Str. 21, 28199 Bremen
J. J. Barrett, N.I. Adams, III: “Laser-excited rotation-vibration Raman scattering in ultra-small gas samples”, J. Opt. Soc. Am. 58, 311–319 (1968)
R.K. Jannsen, D.M. Krol: “Micro-Raman spectroscopy: a technique for analyzing bubbles in glass”, Appl. Opt. 24, 275–279 (1985)
S.W. Lee, K.S. Hong, R.A. Condrate, Sr., R.P. Hapanowicz, R. F. Speyer: “Characterization of gas components and deposits in bubbles in silicate glasses prepared with sodium sulfate”, J. Mat. Sci. 27, 4961–4966 (1992)
W.R. Fenner, H.A. Hyatt, J.M. Kellam, S.P.S. Porto: “Raman cross section of some simple gases”, J. Opt. Soc. Am. 63, 73–77 (1973)
J. Schulze: Quantitative Glasblasenanalyse mittels Raman-Spektroskopie, Diploma Thesis (Mainz 1994);
J. Schulze, R. Feile, D. Köpsel, F. Krämer: “Quantitative analysis of small gas bubbles with diameters down to 60 micron with Micro-Raman spectroscopy”, in Proc. 69. Glastechnische Tagung (Deutsche Glastechnische Gesellschaft, Frankfurt/Main 1995) pp. 90–93
H.O. Mulfinger: “Zum Verhalten von Blasen in Glasschmelzen”, Glastechn. Ber. 45, 238–243 (1972)
H.O. Mulfinger: “Gasanalytische Verfolgung des Lautervorgangs im Tiegel und in der Schmelzwanne”, Glastechn. Ber. 49, 232–245 (1976)
L. Nemec: “The refining of glass melts”, Glass Technol. 15, 153–156 (1974)
M. Mühlbauer, L. Nemec: “Einfluß der Gase einer Glasschmelze auf das Verhalten der Gasblasen unter isothermen Bedingungen”, Glastechn. Ber. 54, 389–399 (1981)
R.G.C. Beerkens: “Chemical equilibrium reactions as driving forces for growth of gas bubbles during refining”, Glastechn. Ber. 63 K, 222–243 (1990)
R.G.C. Beerkens, M. van Kersbergen: “Redox reactions and properties of gases in glass melts”, Final Report NCNG-Novem, TNO Report HAM-RPT-9577, July 1996
F.G.K. Baucke, G. Röth: “Electrochemical mechanism of the oxygen bubble formation at the interface between oxidic melts and zirconium silicate refractories”, Glastechn. Ber. 61, 109–118 (1988)
F.W. Krämer: “Analysis of gases evolved by AZS refractories and by refractory/glass melt reactions. Techniques and results. Contribution to the bubble-forming mechanism of AZS material”, Glastechn. Ber. 65, 93–98 (1992)
F.A.G. van Dijk: Glass Defects Originating from Glass Melt/Fused Cast AZS Refractory Interaction, PhD Thesis (Eindhoven 1994)
F.W. Krämer: “Nitrogen bubbles from AZS refractories”, in Proc. Int. Symp. on Glass Problems, Vol. 1 (Şişecam, Istanbul 1996) pp. 292–297
H.O. Mulfinger: “Gase (Blasen) in der Glasschmelze”, in Glastechnische Fabrikationsfehler, ed. by H. Jebsen-Marwedel, R. Brückner (Springer, Berlin, Heidelberg 1980) pp. 193–268
F.W. Krämer: “Bubble defect diagnosis by means of a mathematical model”, in Coll. Papers XIV. Int. Congress on Glass, Vol. 2 (Indian Ceramic Soc., Calcutta 1986) pp. 288–295
F. Simmonis, H. de Waal, R.C.G. Beerkens: “Influence of furnace design and operation parameters on the residence time distribution of glass tanks, predicted by 3-D computer simulation”, in Coll. Papers XIV Int. Congress on Glass, Vol. II (Indian Ceramic Soc, Calcutta 1986) pp. 118–127
J. Chmelar, P. Schill, A. Franek: “Mathematical models of glass melting furnaces”, Glastechn. Ber. Glass Sci. Technol. 68 C2, 63–66 (1995)
M.K. Choudhary, N.T. Huff: “Mathematical modeling in the glass industry: an overview of status and needs”, Glastechn. Ber. Glass Sci. Technol. 70, 363–370 (1997)
F.W. Krämer: “Mathematical model of bubble growth and dissolution in glass melts”, in Gas Bubbles in Glass, TC14 Report Int. Com. Glass (Institut National du Verre, Charleroi, Belgium 1985) pp. 92–126
J.I. Ramos: “Multicomponent gas bubbles, Part 1+2”, J. Non-Equilib. Thermodyn. 13, 1–25, 107–131 (1988)
B. Balkanli, A. Ungan: “Numerical simulation of bubble behavior in glass melting tanks, Part 1–4”, Glass Technol. 37 (29–3-4), 101–105, 137–142, 164–168 (1996)
E. Itoh, H. Yoshikawa, Y. Kawase: “Modeling of bubble removal from glass melts at fining temperatures”, Glastechn. Ber. Sci. Technol. 70, 8–16 (1997)
J. Ullrich, J. Klouzek, L. Nemec, M. Rakova: “The significant features of bubble behaviour in the bubble source identification system”, in Fundamentals of Glass Science and Technology, ed. by S. Person (Glafo, Växjö 1997) pp. 630–636
S. Kawachi, Y. Kawase: “Evaluation of bubble removing performance in a TV glass furnace, Part 1+2”, Glastechn. Ber. Glass Sci. Technol. 71, 83–91, 111–119 (1998)
L. Nemec, J. Ullrich: “Calculations of interactions of gas bubbles with glass liquids containing sulphates”, J. Non-Cryst. Solids 238, 98–114 (1998)
E. Zschimmer: Die Glasindustrie in Jena (Dietrichs, Jena 1912)
W. Vogel: Chemistry of Glass (Am. Ceram. Soc, Columbus OH 1985);
W. Vogel: Glass Chemistry (Springer, Berlin, Heidelberg 1992);
W. Vogel: Glaschemie (VEB Deutscher Verlag für Grundstoffindustrie, 1979 and 1983);
W. Vogel: Glaschemie (Springer, Berlin, Heidelberg 1992)
E.A. Porai-Koshits, V.I. Averjanov: “Primary and secondary phase separation of sodium silicate glasses”, J. Non-Cryst. Solids 1, 29–38 (1968)
D.W. Johnson, F.A. Hummel: “Phasentrennungserscheinungen in Gläsern”, Compt. Rend. Symp. Leningrad, Akad. Wiss. UdSSR (1968)
D.W. Johnson, F.A. Hummel: Phasentrennungserscheinungen in Gläsern (Verlag Akad. Wiss. UdSSR, Leningrad 1974)
W. Vogel, D. Ehrt: “25 Jahre Glaschemie in Jena”, Z. Chem. 14, 396–404 (1974)
T.P. Seward, D.R. Uhlmann: “Phase separation in the system BaO-SiO2”, J. Am. Ceram. Soc. 51, 278–285 (1968)
W. Skatulla, W. Vogel, H. Wessel: “Über Phasentrennung und Borsäureanomalie in einfachen Natriumborat- und technischen Borosilikatgläsern”, Silicattechnik 9, 51–62 (1958)
W. Vogel: “Struktur der Gläser vom Vycor-Typ im Glassystem Na2O-B2O3-SiO2”, Silicattechnik 9, 323 (1958)
W. Vogel: “Über Phasentrennung im Glas”, in Compt. Rend. Symp. Sur la Fusion du Verre (Union Scientifique Continentale du Verre, Bruxelles 1958) pp. 741–770
K. Kühne: “Eigenschaften und Struktur ultra-mikroporöser Gläser”, Z. Phys. Chem. 204, 20–42 (1955)
W. Vogel: “Sekundäre Entmischungserscheinungen in phosphatgetrübten Borosilikatgläsern”, Silicattechnik 15, 383–387 (1964)
W. Vogel, H.G. Byhan: “Zur Struktur binärer Lithiumsilikatgläser”, Silicattechnik 15, 239–244 (1964)
H. Schönborn: “Aufbau und Eigenschaften der Phosphattrübgläser”, Silicattechnik 10, 390–400 (1959)
W. Vogel, W. Schmidt, L. Horn: “Die mehrphasige Struktur von Barium-borosilikatgläsern als Folge einer stufenförmig ablaufenden Phasentrennung”, Z. Chem. 9, 401–440 (1969)
K. Gerth, A. Rehfeld: “Untersuchungen am System BaO-B2O3-SiO2”, Silicattechnik 20, 227–228 (1969)
W. Vogel, W. Höland, L. Horn, G. Völksch: “Phase separation behaviour of special base glasses — a contribution to the development of bioactive glass ceramics”, J. Phys. 46, C8, 415–420 (1985)
E. Kashieva, J. Dimitriev: private communication
W. Vogel: Struktur und Kristallisation der Gläser (VEB Deutscher Verlag für Grundstoffindustrie, Leipzig 1965, 1971)
W. Vogel:. “The microstructure of glass”, Zeiss Information with Jena Review 2, 36–38 (1992)
W. Vogel: Glasfehler (Springer, Berlin, Heidelberg 1993)
W. Vogel, A. Rehfeld, H. Ritschel: “Über die Verteilung farbloser und farbiger Zusatzkomponenten in einfachen Gläsern sowie über Einfluss auf Struktur und Kristallisation”, Silic. Ind. 5, 1–11 (1967)
N.J. Kreidl, M.S. Maklad: “Effect of water content on phase separation”, J. Am. Ceram. Soc. 52, 508–509 (1969)
M.S. Maklad, N.J. Kreidl: “Some effects of OH groups on sodium silicate glasses”, in Proc. 9th Int. Congr. Glass (Institut du Verre, Paris 1971) pp. 75–100
E.N. Boulos, N.J. Kreidl: “Water in glass: a review”, J. Canad. Ceram. Soc. 41, 83–90 (1972)
G.E. Rindone, R.J. Ryder: “Phase separation induced by platinum in sodium phosphate melts”, Glass Ind. 38, 29–31 (1957)
M.K. Murthy: “Influence of platinum nucleation on constitution of and phase separation in sodium phosphate glasses”, J. Am. Ceram. Soc. 44, 412–417 (1961)
J.S. Hayden, D.L. Sapak, A.J. Marker III: “Elimination of metallic platinum in phosphate laser glass”, Proc. SPIE 895, 176–181 (1988)
J.H. Campbell, E.P. Wallerstein, J.S. Hayden, D.L. Sapak, D.E. Warrington, A.J. Marker III, H. Toratani, H. Meissner, S. Nakajima, T. Izumitani: “Elimination of platinum inclusions in phosphate laser glasses”, Lawrence Livermore National Laboratory, UCRL-53932, 1–62 (1989)
J.H. Campbell, E.P. Wallerstein, J.S. Hayden, D.L. Sapak, D.E. Warrington, A.J. Marker III: “Effects of melting conditions on Pt-inclusion content in phosphate laser glasses”, Glastechn. Ber. 68, 11–21 (1995)
J.H. Campbell, E.P. Wallerstein, H. Toratani. H.E. Meissner, S. Nakajima, T.S. Izumitani: “Effects of process gas environment on platinum-inclusion density and dissolution rate in phosphate laser glasses”, Glastechn. Ber. 68, 59–69 (1995)
C.L. Weinzapfel, G.J. Greiner, C.D. Walmer, J.F. Kimmons, E.P. Wallerstein, F.T. Marchi, J.H. Campbell, J.S. Hayden, K. Komiya,T. Kitayama: “Large scale damage testing in a production environment”, NIST Special Publ. 756, 112–122 (1987)
J.S. Hayden, H.J. Hoffmann: “Elimination of particles”, Schott Information 55, 6–8 (1991)
J.S. Hayden, A.J. Marker III: “Engineering of glass for optimized optical and physical properties”, XVI Congreso Internacional Del Vidrio (16th Int. Congr. on Glass), Madrid, Spain, October 4–9 (1992)
A.J. Marker III, J.S. Hayden, J.H. Campbell: “Engineering of glass for specific intracavity and extracavity applications”, Proc. SPIE 1969, 96–103 (1993)
J.S. Hayden, N. Neuroth: “Laser glasses”, in The Properties of Optical Glass, Schott Series on Glass and Glass Ceramics, ed. by H. Bach, N. Neuroth (Springer, Berlin, Heidelberg 1998) pp. 308–321
T. Izumitani, M. Matsukawai, H. Miyode: “Solubility of Pt in Nd-phosphate laser glass”, NIST Special Publ. 756, 29–34 (1987)
C.G. Young: “Glass lasers”, Proc. IEEE 57, 1267–1289 (1969)
National Materials Advisory Board, Division of Engineering, National Research Council: “Fundamentals of damage in laser glass”, Report No. NMAB-271 (Washington, DC 1970)
E.S. Bliss: Damage in Laser Glass, Special Technical Publication No. 469 (Am. Soc. for Testing and Materials, Philadelphia, PA 1970)
J.H. Campbell, E.P. Wallerstein, J.S. Hayden, D.L. Sapak, D. Warrington, A.J. Marker, H. Toratani, H. Meissner, S. Nakajima, T. Izumitani: “Elimination of platinum inclusions in phosphate laser glasses”, LLNL Report UCRL-53932 (Livermore, CA 1989)
J.H. Campbell: “Modeling platinum-inclusion dissolution in phosphate laser glasses”, Glastechn. Ber. 68 (3), 91–101 (1995)
R.W. Hopper, D.R. Uhlmann: “Mechanism of inclusion damage in laser glasses”, J. Appl. Phys. 41 (10), 4023–4037 (1970)
R.W. Hopper, D.R. Uhlmann: “Vaporization of inclusions during laser operation”, J. Appl. Phys. 41 (4), 5356–5357 (1970)
R.W. Hopper, C. Lee, D.R. Uhlmann: “The inclusion problem in glass”, in Damage in Laser Materials: 1970, ed. by A.J. Glass, A.H. Guenther, Special Publ. 341 (Nat. Bureau of Standards, Boulder, CO 1970) pp. 55–66
M. Sparks, C.J. Duth Ler: “Theory of infrared absorption and material failure in crystals containing inclusions”, J. Appl. Phys. 44 (7), 3038–3045 (1973)
Yu.K. Danileiko, A.A. Manenkov, V.S. Nechotailo, A.M. Prokhorov, V.Ya. Khaimo-Mal’kov: “The role of absorbing impurities in laser-induced damage of transparent dielectrics”, Sov. Phys. JETP 36(3), 541–543 (1973)
N.E. Alekseev, V.P. Gapontsev, M.E. Zhabotinskii, V.B. Kravchenko, Yu.P. Rudnitskii: Laser Phosphate Glasses, English translation, UCRL-Trans-11817 (LLNL, Livermore, CA 1983)
P.V. Avizonis, T. Farrington: “Internal self-damage of ruby and Nd-glass lasers”, Appl. Phys. Lett. 7, 205–206 (1965)
C. Yamanaka, T. Saski, M. Hongyo, Y. Nagao: “Investigations of damage in laser glass”, in Damage in Laser Materials: 1971, ed. by A.J. Glass, A.H. Guenther (Special Publ. 356, Nat. Bureau of Standards, Boulder, CO 1971) pp. 104–112
S. Stokowski, D. Milam, M. Weber: “Laser induced damage in fluoride glasses: a status report”, in Laser Induced Damage in Optical Materials: 1918, ed. by A.J. Glass, A.H. Guenther, Special Publ. 541 (Nat. Bureau of Standards, Boulder, CO 1978) pp. 99–108
R.P. Gonzales, D. Milam: “Evolution during multiple-shot irradiation of damage surrounding isolated platinum inclusions in phosphate laser glass”, in Laser Induced Damage in Optical Materials: 1978, ed. by H.E. Bennett, A.H. Guenther, D. Milam, B.E. Newman (Special Publ. 746, Nat. Bureau of Standards, Boulder, CO 1985) pp. 128–137
J.H. Pitts: “Modeling laser damage caused by platinum inclusions in laser glass”, in Laser Induced Damage in Optical Materials: 1985, ed. by H.E. Bennett, A.H. Guenther, D. Milam, B.E. Newman, Special Publ. 746 (Nat. Bureau of Standards, Boulder, CO, 1985) pp. 537–546
C.W. Hatcher: “Assessment of laser glass damage on the Nova system”, in 1985 Laser Program Annual Report, UCRL-50021–85 (LLNL, Livermore, CA 1986) Chap. 6, pp. 4–6
T. Izumitani, K. Hosaka, C. Yamanaka: “Laser damage of Hoya laser glass, LCG-11”, in Laser Induced Damage in Optical Materials: 1972, ed. by A.J. Glass, A.H. Guenther (Special Publ. 372, Nat. Bureau of Standards, Boulder, CO 1972) pp. 3–10
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Feile, R. et al. (1999). Analysis and Diagnosis of Local Defects. In: Bach, H., Krause, D. (eds) Analysis of the Composition and Structure of Glass and Glass Ceramics. Schott Series on Glass and Glass Ceramics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03746-1_6
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