Mississippi Valley-Type Deposits in Continental Margin Basins: Lessons from the Appalachian-Caledonian Orogen

  • S. E. Kesler
Part of the Special Publication of the Society for Geology Applied to Mineral Deposits book series (MINERAL DEPOS., volume 10)


One of the major questions concerning Mississippi Valley-type (MVT) deposits at continental margins is the mechanism by which mineralizing brines were expelled from their source basins. Possible mechanisms, listed in order of the intensity of regional deformation with which they are associated, include basinal overpressuring, regional tilting, hinterland recharge of foreland basins, and destruction of source basins by regional thrusting. MVT mineralization in the Caledonian-Appalachian orogen provides an excellent opportunity to compare the effectiveness of these four brine expulsion processes. In general, the largest MVT deposits are found in areas of most intense regional thrusting, suggesting that hinterland recharge or basin deformation is the important brine expulsion mechanism. The fact that widespread MVT mineralization in the East Tennessee area of the southern Appalachians is adjacent to overlapping Taconic and Acadian foreland basins and metamorphic maxima suggests that basin deformation is the dominant process for brine expulsion.


Fluid Inclusion Foreland Basin Thrust Sheet Fluid Inclusion Study Econ Geol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. Akande SO, Zentilli M (1984) Geologic, fluid inclusion, and stable isotope studies of the Gays River lead-zinc deposit, Nova Scotia, Canada. Econ Geol 79: 1187–1211Google Scholar
  2. Anderson GM, Macqueen RW (1982) Ore deposit models — 6. Mississippi Valley-type lead-zinc deposits. Geosci Can 9: 108–117Google Scholar
  3. Andrew CJ, Ashton JH (1985) The regional setting, geology and metal distribution of the Navan orebody, Ireland. Trans Inst Min Metall Sect B 94: 66–93Google Scholar
  4. Bachtadse V, Van der Voo R, Haynes FM, Kesler SE (1987) Late Paleozoic magnetization of mineralized and unmineralized Ordovician carbonates from East Tennessee: evidence for a post-ore chemical event. J Geophys Res 92: 14165–14176CrossRefGoogle Scholar
  5. Bassett MG (1985) Silurian stratigraphy and facies development in Scandinavia. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 283–292Google Scholar
  6. Bergstrom J, Gee DG (1985) The Cambrian in Scandinavia. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 247–272Google Scholar
  7. Bethke CM (1986) Hydrologic constraints on the genesis of the Upper Mississippi Valley district from Illinois Basin brines. Econ Geol 81: 233–249CrossRefGoogle Scholar
  8. Bethke C, Marshak S (1990) Brine migration across North America — the plate tectonics of groundwater. Annu Rev Earth Planet Sci 18: 287–315CrossRefGoogle Scholar
  9. Bjorlykke A (1978) The eastern marginal zone of the Caledonide orogen in Norway. In: Caledonian-Appalachian orogen of the North Atlantic region. Geol Sury Can Pap 78–13: 49–56Google Scholar
  10. Bjorlykke A, Sangster DF (1981) An overview of sandstone lead deposits and their relation to red-bed copper and carbonate-hosted lead-zinc deposits: Econ Geol 75th Anniversary Vol: 179–213Google Scholar
  11. Bovan JA, Read JF (1987) Incipiently drowned facies within a cyclic peritidal ramp sequence, Early Ordovician Chepultepec interval, Virginia Appalachians. Geol Soc Am Bull 98: 714–727Google Scholar
  12. Boyle RW, Wanless RK, Stevens RD (1976) Sulfur isotope investigation of the barite, manganese and lead-zinc-copper-silver deposits of the Walton-Cheverie area, Nova Scotia, Canada. Econ Geol 71: 749–762Google Scholar
  13. Bradley DW, Kusky TM (1986) Geologic evidence for rate of plate convergence during the Taconic arc-continent collision. J Geol 94: 667–681CrossRefGoogle Scholar
  14. Brown WH, Weinberg EL (1968) Geology of the Austinville-Ivanhoe district, Virginia. In: Ridge JD (ed) Ore deposits of the United States, 1933–1967, vol 1. AIME, New York, pp 169–186Google Scholar
  15. Bruton OL, Lindstrom M, Owen AW (1985) The Ordovician of Scandinavia. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 273–282Google Scholar
  16. Bryhni I, Andresson P-G (1985) Metamorphism in the Scandinavian Caledonides. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 763–781Google Scholar
  17. Callahan WH (1968) Geology of the Friedensville zinc mine, Lehigh County, Pennsylvania. In: Ridge JD (ed) Ore deposits of the United States 1933–1967 ( Graton-Sales Volume). AIME, New York, pp 95–107Google Scholar
  18. Cathles LM, Smith AT Jr (1983) Thermal constraints on the formation of Mississippi Valley-type lead-zinc deposits and their implications for episodic basin dewatering and deposit genesis. Econ Geol 78: 983–1002CrossRefGoogle Scholar
  19. Chapman TJ, Gayer RA, Williams GD (1985) Structural cross-sections through the Finnmark Caledonides and timing of the Finnmarkian event. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 593–610Google Scholar
  20. Clark SHB (1989) Metallogenic map of zinc, lead, and barium deposits and occurrences in Paleozoic sedimentary rocks, east-central United States. US Geol Sury Map I - 1773Google Scholar
  21. Collins JA, Smith L (1975) Zinc deposits related to diagenesis and intrakarstic sedimentation in the Lower Ordovician St. George Formation, western Newfoundland. Bull Can Petrol Geol 23: 393–427Google Scholar
  22. Colton GW (1971) The Appalachian basin — its depositional sequences and their geologic relationships. In: Fisher GW, Pettijohn FJ, Reed JC Jr (eds) Studies of Appalachian geology: central and southern. Wiley, New York, pp 4–47Google Scholar
  23. Duane MJ, de Wit MJ (1988) Pb-Zn ore deposits of the northern Caledonides: products of continental-scale fluid mixing and tectonic expulsion during continental collision. Geol 16: 999–002CrossRefGoogle Scholar
  24. Dunham K, Beer KE, Ellis RA, Ballagher MJ, Nutt MJC, Webb BC (1978) United Kingdom. In: Bowie SHU, Kvalheim A, Haslam HW (eds) Mineral deposits of Europe, vol 1. Northwest Europe. Institution of Mining and Metallurgy, London, pp 263–346Google Scholar
  25. Elliot I, Aronson JL (1987) Alleghanian episode of K-bentonite illitization in southern Appalachian basin. Geol 15: 735–739CrossRefGoogle Scholar
  26. Evans AM (1976) Genesis of Irish base-metal deposits. In: Wolf KH (ed) Handbook of stratbound and stratiform ore deposits, vol 5. Elsevier, Amsterdam, pp 231–255Google Scholar
  27. Foley NK, Sinha AK, Craig JR (1981) Isotopic composition of lead in the Austinville-Ivanhoe Pb-Zn district, Virginia. Econ Geol 76: 2012–2017Google Scholar
  28. Foyn S (1985) The Late Precambrian in northern Scandinavia. In: Gee DG, Sturt BA (eds) The Caledonides Orogen — Scandinavia and related areas. Wiley, New York, pp 233–246Google Scholar
  29. Garven G (1985) The role of regional fluid flow in the genesis of the Pine Point deposit, western Canada sedimentary basin. Econ Geol 80: 307–324CrossRefGoogle Scholar
  30. Gee DG, Sturt BA (eds) (1985) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, 1514 ppGoogle Scholar
  31. Hall CM, York D, Saunders CM, Strong DF (1989) Laser 40Ar/39Ar dating of Mississippi Valleytype mineralization western Newfoundland. Int Geological Congr Abstr Vol, pp 2–10Google Scholar
  32. Halliday AN, Shepherd TJ, Nakai S, Chesley J, Dickin AP (1989) Sm-Nd and Rb-Sr dating of MVT deposits. GSA Abstr Prog 7: 175Google Scholar
  33. Hanor JS (1987) Origin and migration of subsurface sedimentary brines. Soc Econ Paleontol Mineral Lect Notes Short Course 21, 247 ppGoogle Scholar
  34. Harris LD (1971) A Lower Paleozoic paleoaquifer— the Kingsport Formation and Mascot Dolomite of Tennessee and southwest Virginia. Econ Geol 66: 735–743CrossRefGoogle Scholar
  35. Hatcher RD (1987) Tectonics of the southern and central Appalachian internides. Annu Rev Earth Planet Sci 15: 337–362CrossRefGoogle Scholar
  36. Haynes FM, Kesler SE (1989) Pre-Alleghanian ( Pennsylvanian-Permian) hydrocarbon emplacement along Ordovician Knox unconformity, eastern Tennessee. Am Assoc Petrol Geol Bull 73: 289–297Google Scholar
  37. Hearn PP Jr, Sutter JF, Belkin HE (1987) Evidence for Late-Paleozoic brine migration in Cambrian carbonate rocks of the central and southern Appalachian: implications for Mississippi Valley-type sulfide mineralization. Geochim Cosmochim Acta 51: 1323–1334CrossRefGoogle Scholar
  38. Henriksen N (1985) The Caledonides of central East Greenland 70°-76°N. In: Gee DG, Sturt BA(eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 1095–1114Google Scholar
  39. Hoagland AD (1976) Appalachian zinc-lead deposits. In: Wolfe KH (ed) Handbook of stratabound and stratiform ore deposits, vol 6. Elsevier, Amsterdam, pp 495–534Google Scholar
  40. Howe SS (1981) Mineralogy, fluid inclusions, and stable isotopes of lead-zinc occurrences in central Pennsylvania. MSc Thesis, State College, Pennsylvania State University, 155 ppGoogle Scholar
  41. Hurst JM, Jepsen HF, Kalsbeek F, McKerrow WS, Peel JS (1985) The geology of the northern extremity of the East Greenland Caledonides. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 1047–1064Google Scholar
  42. Jackson M, McCabe C, Ballard MM, Van der Voo R (1988) Magnetite authigenesis and diagenetic paleotemperatures across the northern Appalachia basin. Geology 16: 592–595CrossRefGoogle Scholar
  43. Jamieson RA, Beaumont C (1988) Orogeny and metamorphism: a model for deformation and pressure-temperature-time paths with application to the central and southern Appalachians. Tectonics 7: 417–445CrossRefGoogle Scholar
  44. Jowett C (1977) Nature of the ore forming fluids of the Polaris lead-zinc deposit, Little Cornwallis Island, NWT, from fluid inclusion studies. Can Min Metall Bull (March): 23–31Google Scholar
  45. Kesler SE, van der Pluijm BA (1990) Relation of Lower Ordovician-hosted MVT mineralization to Appalachian orogenic events. Geology 18: 1115–1118CrossRefGoogle Scholar
  46. Kesler SE, Jones LM, Ruiz J (1988) Strontium isotopic geochemistry of Mississippi Valley-type deposits, East Tenessee: implications for age and source of mineralizing brines. Geol Soc Am Bull 100: 1300–1307 (reply to discussion in 102:1600–1602)Google Scholar
  47. Kesler SE, Gesink JA, Haynes FM (1989) Evolution of mineralizing brines in the east Tennessee Mississippi Valley-type ore field. Geology 17: 466–469CrossRefGoogle Scholar
  48. Kesler TL (1950) Geology and mineral deposits of the Cartersville district, Georgia. US Geol Sury Prof Pap 224, 97 ppGoogle Scholar
  49. Lane T (1989) Sphalerite/dolomite stratigraphy and the tectonic origin of an MVT deposit, Daniel’s Harbour, Newfoundland, Canada. Geol Soc Am Abstr Prog 21: A8Google Scholar
  50. Lindblom S (1986) Textural and fluid inclusion evidence for ore deposition in the Pb-Zn deposit at Laisvall, Sweden. Econ Geol 81: 46–64CrossRefGoogle Scholar
  51. McNaughton K, Smith TE (1986) A fluid inclusion study of sphalerite and dolomite from the Nanisivik lead-zinc deposit, Baffin Island, Northwest Territories, Canada. Econ Geol 81: 713720Google Scholar
  52. Miller JD, Kent DV (1988) Regional trends in the timing of Alleghanian remagnetization in the Appalachians. Geology 16: 588–591CrossRefGoogle Scholar
  53. Nakai S, Halliday AN, Kesler SE, Jones HD (1990) Rb-Sr dating of sphalerite and genesis of MVT deposits. Nature 346: 354–357CrossRefGoogle Scholar
  54. Oliver J (1986) Fluids expelled tectonically from orogenic belts: their role in hydrocarbon migration and other geologic phenomena. Geology 14: 99–102CrossRefGoogle Scholar
  55. Quinn L (1991) Ordovician foredeep sandstones of the Goose Tickle Group, western Newfoundland. Geol Assoc Can Prog Abstr 16: A103Google Scholar
  56. Ramsay DM, Sturt BA, Jansen O, Andersen TB, Sinhan-Roy S (1985) The tectonostratigraphy of western Porsangerhalvoya, Finnmark, north Norway. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 611–622Google Scholar
  57. Rast N (1989) The evolution of the Appalachian chain. In: Bally AW, Palmer AR (eds) The geology of North America, vol A. The geology of North America — an overview. Geological Society of America, Boulder, CO, pp 323–348Google Scholar
  58. Ravenhurst CE, Reynolds PH, Zentilli M, Krueger HW, Blenkinsop J (1989) Formation of Carboniferous Pb-Zn and barite mineralization from basin-derived fluids, Nova Scotia, Canada. Econ Geol 84: 1471–1488Google Scholar
  59. Rickard DT, Willden MY, Narinder N-E, Donnely TH (1979) Studies on the genesis of the Laisvall sandstone lead-zinc deposit, Sweden. Econ Geol 74: 1255–1285Google Scholar
  60. Roberts D, Gee DG (1985) An introduction to the structure of the Scandinavian Caledonides. In: Gee DG, Strut BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 56–68Google Scholar
  61. Sangster DF (1983) Mississippi Valley-type deposits: a geological melange. In: Kisvarsanyi G, Grant SK, Pratt WP, Koenig JW (eds) International Conference on Mississippi Valley-type Lead-Zinc Deposits, Proc Vol. University of Missouri, Rolla, MO, pp 7–19Google Scholar
  62. Sangster DF, Vaillancourt PD (1990) Geology of the Yava sandstone-lead deposit, Cape Breton Island, Nova Scotia. In: Sangster AL (ed) Mineral deposit studies in Nova Scotia, vol 1. Geol Sury Can Pap 90–8: 203–244Google Scholar
  63. Sawkins FJ (1966) Ore genesis in the North Pennine orefield, in the light of fluid inclusion studies. Econ Geol 61: 385–401CrossRefGoogle Scholar
  64. Sharp JJ Jr (1978) Energy and momentum transport model of the Ouachita basin and its possible impact on the formation of economic mineral deposits. Econ Geol 73: 1057–1068CrossRefGoogle Scholar
  65. Sharp JM, Kyle JR (1988) The role of groundwater processes in the formation of ore deposits. In: Back W, Rosensheim JS, Seaber PR (eds) The geology of North America, hydrogeology, vol O-2. Geological Society of America, Boulder, CO, pp 461–483Google Scholar
  66. Shepherd TJ, Darbyshire DPF, Moore GR, Greenwood DA (1982) Age of Pennine mineralization. Bull Bur Mech Gites Min 11: 371–377Google Scholar
  67. Smith RC II (1977) Zinc and lead occurrences in Pennsylvania. Pa Geol Sury Mineral Resour Rep 72, 318 ppGoogle Scholar
  68. Sorenson H, Nielsen BL, Jacobsen FL (1978) Denmark and Greenland. In: Bowie SHU, Kvalheim A, Haslam HW (eds) Mineral deposits of Europe, vol 1. Northwest Europe. Institution of Mining and Metallurgy, London, pp 251–261Google Scholar
  69. Stam JC (1960) Some ore occurrences of the Mississippi Valley-type in equatorial Africa. Econ Geol 55: 1708–1715CrossRefGoogle Scholar
  70. Steel R, Siedlecka A, Roberts D (1985) The Old Red Sandstone basins of Norway and their deformation. In: Gee DG, Sturt BA (eds) The Caledonide orogen — Scandinavia and related areas. Wiley, New York, pp 293–316Google Scholar
  71. Stendal H, Ghisler M (1984) Strata-bound copper sulfide and non strata-bound arsenopyrite and base metal mineralization in the Caledonides of east Greenland — a review. Econ Geol 79: 1574–1585CrossRefGoogle Scholar
  72. Sturt BA (1978) The Norwegian Caledonides. Geol Sury Can Pap 78–13: 13–16Google Scholar
  73. Sverjensky DA (1986) Genesis of Mississippi Valley-type lead-zinc deposits. Annu Rev Earth Planet Sci 14: 177–199CrossRefGoogle Scholar
  74. Symons DTA, Sangster DF (1991) Paleomagnetism of the Mississippi Valley-type Polaris Zn-Pb deposit: genetic consequences of a Late Devonian age. Geol Assoc Can Prog Abstr 16:Al21Google Scholar
  75. Taylor M, Kesler SE, Cloke PL, Kelly WC (1983) Fluid inclusion evidence for fluid mixingGoogle Scholar
  76. Mascot-Jefferson City zinc district, Tennessee. Econ Geol 78: 1425–1439Google Scholar
  77. Torsvik TH, Ryan PD, Trench A, Harper DAT (1991) Cambrian-Ordovician paleogeography of Baltica. Geology 19: 7–10CrossRefGoogle Scholar
  78. Tull JF, Groszos M (1990) Nested Paleozoic “successor” basins in the southern Appalachian Blue Ridge. Geology 18: 1046–1049CrossRefGoogle Scholar
  79. Unrug R, Unrug S (1990) Paleontological evidence of Paleozoic age for the Walden Creek Group, Ocoee Supergroup, Tennessee. Geology 18: 1041–1045Google Scholar
  80. Wilbur JS, Mutschler FE, Friedman JD, Zartman RE (1990) New chemical, isotopic and fluid inclusion data from zinc-lead-copper veins, Shawangunk Mountains, New York: Econ Geol 85: 182–196Google Scholar
  81. Williams CE, McArdle P (1978) Ireland. In: Bowie SHU, Kvalheim A, Haslam HW (eds) Mineral deposits of Europe, vol 1. Northwest Europe. Institution of Mining and Metallurgy, London, pp 319–346Google Scholar
  82. Williams H (1984) Miogeoclines and suspect terranes of the Caledonian-Appalachian orogen: tectonic patterns in the North Atlantic region. Can J Earth Sci 21: 887–901CrossRefGoogle Scholar
  83. Willdén MU (1980) Paleoenvironment of the autochthonous sedimentary rock sequence at Laisvall,Swedish Caledonides. Acta Univ Stockholm, Stockholm Contrib Geol 33, 100 ppGoogle Scholar
  84. Zimmerman RK, Kesler SE (1981) Fluid inclusion evidence for solution mixing, Sweetwater(Mississippi Valley-type) district, Tennessee. Econ Geol 76: 134–142Google Scholar

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© Springer-Verlag Berlin Heidelberg 1994

Authors and Affiliations

  • S. E. Kesler
    • 1
  1. 1.Department of Geological SciencesUniversity of MichiganAnn ArborUSA

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