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Exclusion Principle and Quantum Mechanics

  • Wolfgang Pauli
Chapter

Abstract

The history of the discovery of the exclusion principle, for which I have received the honor of the Nobel Prize award in the year 1945, goes back to my student days in Munich. While, in school in Vienna, I had already obtained some knowledge of classical physics and the then new Einstein relativity theory, it was at the University of Munich that I was introduced by Sommerfeld to the structure of the atom — somewhat strange from the point of view of classical physics. I was not spared the shock which every physicist, accustomed to the classical way of thinking, experienced when he came to know of Bohr’s ‘Basic postulate of quantum theory’ for the first time. At that time there were two approaches to the difficult problems connected with the quantum of action. One was an effort to bring abstract order to the new ideas by looking for a key to translate classical mechanics and electrodynamics into quantum language which would form a logical generalization of these. This was the direction which was taken by Bohr’s Correspondence Principle. Sommerfeld, however, preferred, in view of the difficulties which blocked the use of the concepts of kinematical models, a direct interpretation as independent of models as possible, of the laws of spectra in terms of integral numbers, following, as Kepler once did in his investigation of the planetary system, an inner feeling for harmony. Both methods, which did not appear to me irreconcilable, influenced me.

Keywords

Configuration Space Exclusion Principle Wave Mechanic Symmetrical State Symmetry Class 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. Landé, Zeitschrift für Physik 5, 231 (1921)CrossRefADSGoogle Scholar
  2. 1a.
    A. Landé, Zeitschrift für Physik 7, 398 (1921)CrossRefADSGoogle Scholar
  3. 1b.
    A. Landé, Physikalische Zeitschrift 22, 417 (1921).Google Scholar
  4. 2.
    W. Pauli, Zeitschrift f’ür Physik 16, 155 (1923).CrossRefADSGoogle Scholar
  5. 3.
    W. Pauli, Zeitschrift f’ür Physik 31, 373 (1925).zbMATHCrossRefADSGoogle Scholar
  6. 4.
    E. C. Stoner, Philosophical Magazine 48, 719 (1924).CrossRefGoogle Scholar
  7. 5.
    W. Pauli, Zeitschrift für Physik 31, 765 (1925).zbMATHCrossRefADSGoogle Scholar
  8. 6.
    S. Goudsmit and G. Uhlenbeck, Die Naturwissenschaften 13, 953 (1925).zbMATHCrossRefADSGoogle Scholar
  9. 6a.
    S. Goudsmit and G. Uhlenbeck, Nature 117, 264 (1926).CrossRefADSGoogle Scholar
  10. 7.
    L. H. Thomas, Nature 117, 514 (1926)CrossRefADSGoogle Scholar
  11. 7a.
    L. H. Thomas, Philosophical Magazine 3, 1 (1927).zbMATHGoogle Scholar
  12. 7b.
    Compare also J. Frenkel, Zeitschrift f’ür Physik 37, 243 (1926).zbMATHCrossRefADSGoogle Scholar
  13. 8.
    Compare Rapport du Sixième Conseil Solvey de Physique, Paris 1932, pp. 217–225.Google Scholar
  14. 9.
    For this earlier stage of the history of the exclusion principle compare also the author’s note in Science 103, 213 (1946), which partly coincides with the first part of the present lecture.Google Scholar
  15. 10.
    The Nobel-lectures of W. Heisenberg, E. Schrödinger and P. A. M. Dirac are collected in Die moderne Atomtheorie, Leipzig 1934.Google Scholar
  16. 11.
    The articles of N. Bohr are collected in Atomic theory and the description of nature (Cambridge University Press, 1934). See also his article “Light and Life”, Nature 131, 421 and 457 (1933).zbMATHGoogle Scholar
  17. 12.
    W. Heisenberg, Zeitschrift f’ür Physik 38, 411 (1926)zbMATHCrossRefADSGoogle Scholar
  18. 12a.
    W. Heisenberg, Zeitschrift f’ür Physik 39, 499 (1926).zbMATHCrossRefADSGoogle Scholar
  19. 13.
    E. Fermi, Zeitschrift für Physik 36, 902 (1926).zbMATHCrossRefADSGoogle Scholar
  20. 13a.
    P. A. M. Dirac, Proceedings of the Royal Society A 112, 661 (1926).zbMATHCrossRefGoogle Scholar
  21. 14.
    S. N. Bose, Zeitschrift für Physik 26, 178 (1924)zbMATHCrossRefADSGoogle Scholar
  22. 14a.
    S. N. Bose, Zeitschrift für Physik 27, 384 (1924)zbMATHCrossRefADSGoogle Scholar
  23. 14b.
    A. Einstein, Sitzungsberichte der Berliner Akademie der Wissenschaften, 1924, p. 261Google Scholar
  24. 14c.
    A. Einstein, Sitzungsberichte der Berliner Akademie der Wissenschaften, 1925, p. 1 and 18.Google Scholar
  25. 15.
    W. Pauli, Die Naturwissenschaften 12, 741 (1924).CrossRefADSGoogle Scholar
  26. 16.
    W. Heisenberg, Zeitschrift f’ür Physik 41, 239 (1927).zbMATHCrossRefADSGoogle Scholar
  27. 16a.
    F. Hund, Zeitschrift fur Physik 42, 39 (1927).CrossRefGoogle Scholar
  28. 17.
    D. M. Dennison, Proceedings of the Royal Society A, 115, 483 (1927).CrossRefGoogle Scholar
  29. 18.
    R. de Laer Kronig, Die Naturwissenschaften 16 , 335 (1928).CrossRefGoogle Scholar
  30. 18a.
    W. Heitler und G. Herzberg, Die Naturwissenschaften 17, 673 (1929).zbMATHCrossRefADSGoogle Scholar
  31. 19.
    G. N. Lewis and M. F. Ashley, Physical Review 43, 837 (1933).Google Scholar
  32. 19a.
    G. M. Murphy and H. Johnston, Physical Review 45 , 550 (1934)CrossRefADSGoogle Scholar
  33. 19b.
    G. M. Murphy and H. Johnston, Physical Review 46, 95 (1934).CrossRefADSGoogle Scholar
  34. 20.
    Compare for the following the author’s report in Reviews of Modern Physics 13 , 203 (1941), where older literature is given. See also W. Pauli and V. Weisskopf, Helvetica Physica Acta 7, 709 (1934).Google Scholar
  35. 21.
    N. Bohr and L. Rosenfeld, Kongelige Danske Videnskabernes Selskabs, matematiskfysiske Meddelelser XII, No. 8 (1933).Google Scholar
  36. 22.
    P. Jordan and E. Wigner, Zeitschrift für Physik 47, 631 (1928).zbMATHCrossRefADSGoogle Scholar
  37. 22a.
    Compare also v. Focx, Zeitschrift für Physik 75, 622 (1932).CrossRefADSGoogle Scholar
  38. 23.
    W. Pauli, Annales de l’Institut Henri Poincaré 6, 137 (1936) andMathSciNetGoogle Scholar
  39. 23a.
    W. Pauli, Physical Review 58, 716 (1940).CrossRefADSGoogle Scholar
  40. 24.
    See Ref. 20.Google Scholar
  41. 25.
    L. Landau and R. Peierls, Zeitschriftf’ür Physik 69, 56 (1931). Compare also the author’s article in Handbuch der Physik 24, Part 1, 1933, Chapter A, §2.CrossRefADSGoogle Scholar
  42. 26.
    P. A. M. Dirac, Proceedings of the Royal Society A, 117, 610 (1928).zbMATHCrossRefGoogle Scholar
  43. 27.
    See footnote 10.Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1994

Authors and Affiliations

  • Wolfgang Pauli

There are no affiliations available

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