Influence of Physicochemical Properties on Uptake and Loss of Pesticides and Adjuvants from the Leaf Surface

  • G. G. Briggs
  • R. H. Bromilow
Part of the Ernst Schering Research Foundation Workshop book series (SCHERING FOUND, volume 12)

Abstract

The literature on the effects of adjuvants on the uptake of chemicals by plants, insects, isolated cells, micro-organisms and skin is very complex. The physical properties of both the active ingredient and the adjuvant clearly play a part, although its exact nature is generally far from clear.

Keywords

Surfactant Alkane Oleate Volatility Uracil 

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References

  1. Anderson NH, Girling J (1983) The uptake of surfactants into wheat. Pestic Sci 14: 399–404CrossRefGoogle Scholar
  2. Arnold KA, Wildman AS, White RJ, Buss MW, Cline MN (1993) Improved early symptom development with a ready-to-use glyphosate formulation by addition of fatty acid. Pestic Sci 38: 270–271Google Scholar
  3. Baker EA (1982) Chemistry and morphology of plant epicuticular waxes. In: Cutler DF, Alvin KL, Price CE (eds) The plant cuticle. Academic, London, pp 139–165 (Linnean Society symposium series, no 10 )Google Scholar
  4. Barak E, Dinoor A, Jacoby B (1981) Adsorption of systemic fungicides and a herbicide by some components of plant tissue in relation to some physicochemical properties of the pesticide. Pestic Sci 14: 213–219CrossRefGoogle Scholar
  5. Baker EA, Hayes AL, Butler RC (1992) Physicochemical properties of agrochemicals: their effects on foliar penetration. Pestic Sci 34: 167–182CrossRefGoogle Scholar
  6. Briggs GG, Bromilow RH, Evans AA (1982) Relationships between lipophilicity and root uptake and translocation on non-ionised chemicals by barley. Pestic Sci 13: 495–504CrossRefGoogle Scholar
  7. Briggs GG, Bromilow RH, Evans AA, Williams M (1983) Relationships between lipophilicity and the distribution of non-ionised chemicals in barley shoots following uptake by the roots. Pestic Sci 14: 492–500CrossRefGoogle Scholar
  8. Briggs GG, Rigitano RLO, Bromilow RH (1987) Physicochemical factors affecting the uptake by roots and translocation to shoots of weak acids in barley. Pestic Sci 19: 101–112CrossRefGoogle Scholar
  9. Bromilow RH, Chamberlain K (1991) Pathways and mechanisms of transport of herbicides in plants. In: Kirkwood RC (ed) Target sites for herbicide action. Plenum, New York, pp 245–284Google Scholar
  10. Bromilow RH, Chamberlain K, Evans AA (1990) Physicochemical aspects of phloem translocation of herbicides. Weed Sci 38: 305–314Google Scholar
  11. Chamberlain K, Briggs GG, Bromilow RH, Evans AA, Chen QF (1987) The influence of physicochemical properties of pesticides on uptake and translocation following foliar application. Aspects Appl Biol 14: 293–304Google Scholar
  12. Gaskin RE, Stevens PJG (1993) Antagonism of foliar uptake of glyphosate into grasses by organosilicone surfactants. I. Effects of plant species, formulation, concentrations and timing of application. Pestic Sci 38: 185–192Google Scholar
  13. Hartley GS, Graham-Bryce IJ (1980) Physical principles of pesticide behaviour. Academic, LondonGoogle Scholar
  14. Higuchi T (1977) Prodrug, molecular structure and percutaneous delivery. In: Roche EB (ed) Design of biopharmaceutical properties through prodrugs and analogs. American Pharmaceutical Association, Washington, pp 409421Google Scholar
  15. Köcher H, Kocur J (1993) Influence of wetting agents on the foliar uptake and herbicidal activity of glufosinate. Pestic Sci 37: 155–158CrossRefGoogle Scholar
  16. Krenek MR, Reed KG, King DN (1987) Factors affecting the phytotoxicity of solvents used in pesticide formulations. In: Greenhalgh R, Roberts TR (eds) Proceedings 6th international congress of pesticide chemistry. Blackwell, Oxford, pp 287–290Google Scholar
  17. Leahy DE, Morris JJ, Taylor Pi, Wait AR (1992) Model solvents for QSAR. II. Fragment values (f-values) for the “critical quartet”. J Chem Soc Perkin Transact 2: 723–731Google Scholar
  18. McCall Pi (1988) Quantitative modelling of the effects of physical and chemical parameters on the foliar penetration of pesticides and its potential for predicting field behaviour. Aspects Appl Biol 21: 185–201Google Scholar
  19. Nalewaja JD, Matysiak R (1993) Influence of diammonium sulphate and other salts on glyphosate phytotoxicity. Pestic Sci 38: 77–84CrossRefGoogle Scholar
  20. Schönherr J, Riederer M, Schreiber L, Bauer H (1990) Foliar uptake of pesticides and its activation by adjuvants: theories and methods for optimisation. In: Frehse H (ed) Proceedings 7th international congress of pesticide che. mistry. VCH, Weinheim, pp 237–253Google Scholar
  21. Silcox D, Holloway Pi (1986) Techniques suitable for the determination of fo-liar uptake, movement and metabolism of nonionic surfactants. Aspects Appl Biol 11: 1–11Google Scholar
  22. Stevens PJG, Bukovac MJ (1987) Studies on octylphenol surfactants. I. Effects of oxyethylene content on properties of potential relevance to foliar absorption. Pestic Sci 20: 19–35Google Scholar
  23. Stock D, Holloway PJ (1993) Possible mechanisms for surfactant-induced foliar uptake of agrochemicals. Pestic Sci 38: 165–177CrossRefGoogle Scholar
  24. Stock D, Holloway Pi, Grayson BT, Whitehouse P (1993) Development of a predictive uptake model to rationalise selection of polyoxyethylene surfactant adjuvants for foliage-applied agrochemicals. Pestic Sci 37: 233–245CrossRefGoogle Scholar
  25. Tayar NE, Ruey-Shivan T, Testa B, Carrupt P-A, Hansch C, Leo A (1991) Percutaneous penetration of drugs: a quantitative structure-permeability relationship study. J Pharm Sci 80: 744–749CrossRefGoogle Scholar
  26. Thornber CW (1979) Isosterism and molecular modification in drug design. Chem Soc Rev 8: 563–580CrossRefGoogle Scholar
  27. Uchida M (1980) Affinity and mobility of fungicidal dialkyl dithiolanylidenemalonates in rice plants. Pestic Biochem Physiol 14: 249–255CrossRefGoogle Scholar
  28. Urvoy C, Pollacsek M, Gauvrit C (1992) Seed oils as additives: penetration of triolein, methyl oleate and diclofop-methyl in maize leaves. Weed Res 32: 375–383CrossRefGoogle Scholar
  29. Worthing CR, Hance RH (1991) The pesticide manual, 9th edn. British Crop Protection Council, FarnhamGoogle Scholar
  30. Young RC, Mitchell RC, Brown TH, Ganellin CR, Griffiths G, Jones M, Rana KK, Saunders D, Smith IR, Sore NE, Wilks TJ (1988) Development of a new physicochemical model for brain penetration and its application to the design of centrally acting H2-receptor histamine antagonists. J Med Chem 31: 656–671CrossRefGoogle Scholar
  31. Zabkiewicz JA, Stevens PJG, Forster WA, Steele KD (1993) Foliar uptake of organosilicone surfactant oligomers into bean leaf in the presence and absence of glyphosate. Pestic Sci 38: 135–143CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1994

Authors and Affiliations

  • G. G. Briggs
  • R. H. Bromilow

There are no affiliations available

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