Abstract
About 25% of all polymer products involve polymerization within the final mold. Processes including this stage are monomer casting, rubber molding, thermoset injection and compression molding. Most of these processes use thermosetting polymers, because thermosets must be crosslinked in their final shape and because linear polymers with sufficient molecular weight cannot react rapidly enough. Frequently, the cycle times are longer than those required for melt fabricating thermoplastics. Typically the thermosetting reactions are thermally activated, and thus require time for heat transfer to the material in addition to the time needed for the reaction. Recently, technology has been developed for rapid in situ polymerization to form articles directly from monomeric or oligomeric liquids. This process has come to be known as Reaction Injection Molding (RIM), and its modification as the reinforced RIM (RRIM) process.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Bayer-Polyurethanes: Handbook. Bayer AG, FRG, 1979
Becker, W. E. (ed.): Reaction Injection Molding. New York: Van Nostrand Reinhold Company 1979
Sweeney, F. M.: Introduction to Reaction Molding. Westport: Technomic 1979
McBrayer, R. L.: J. Cell. Plast. 16, 331 (1980); SAE Techn. Papers No 800515 (1980)
Börger, H.: Kunststoffe 69, 863 (1979); 72, 359 (1982)
Ferrari, R. J.: Manufacturing Technology Using the RIM Process. In: Injection Molding. Becker, W. E. (ed.). New York: Van Nostrand Reinhold Company, 1979, pp. 56–106, 107–179
McBrayer, R. L., Carver, T. G.: Elastomerics, 113, No 6, 30 (1981)
Lee, L. J.: Rubber Chem. Technol. 153, 542 (1980); Polym. Eng. Sci. 20, 868 (1980)
Webb, S.: Proc. Chem. Eng. 33, No 12, 73 (1980)
Camargro, R. E. et al.: Polym. Eng. Sci. 22, 719 (1982)
Fiorentini, C.: 5th Internat. Conf. Cellular and Non-Cellular Polyurethanes, Strasbourg France, 1980
Schlotterbeck, D.: Kunststoffe 71, 775 (1981)
Botsch, H.: Europ. J. Cell. Plast. 3, No 5, 115 (1980)
Thiele, H., Zettler, H. D.: Ind. Prod. Eng. No 3 94 (1980)
Misitano, G.: Plast. Eng. 35, No 2, 27 (1979)
Knipp, U., Becker, W. E.: Mold ‘Design. In: Reaction Molding. New York: Van Nostrand Reinhold Company, 1979, pp. 215–240, 241–300
Horvath, M.: J. Cell. Plast. 12, 289 (1976)
Gerkin, R. M., Critchfield, F. E.: Meet. Plastics Inst. of Amer., Acron USA, 1976
LaPlaca, J. P.: J. Cell. Plast. 16, 36 (1980)
N.N.: Ind. Week 1979, Sept. 17, 140
Zahn, E., et al.: 5th Internat. Conf. Cellular and Non-Cellular Polyurethanes, Strasbourg France, 1980
N.N.: Plast. World 38, No 1, 11; No 5, 28 (1980); 40, No 12, 12 (1982)
Von Hassel, A.: Plast. Technology, 29, No 1, 21 (1983)
Hölzl, E.: Kunststoffmaschinen No 14, 3 (1983)
Frisch, K. C.: Plast. Rubber Intern. 8, No 1, 17 (1983)
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1986 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Shutov, F.A., Henrici-Olivé, G., Olivé, S. (1986). Reaction Injection Molding Process. In: Henrici-Olivé, G., Olivé, S. (eds) Integral/Structural Polymer Foams. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-02486-7_8
Download citation
DOI: https://doi.org/10.1007/978-3-662-02486-7_8
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-02488-1
Online ISBN: 978-3-662-02486-7
eBook Packages: Springer Book Archive