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Hydrocarbons derived from Peropyrene

Abstract

A zinc-dust melt of perinaphthone (I) yields trimethylenenaphthalene and peropyrene in low yields. Its production can be explained by the formation of an intermediate product (II) which results from a reductive condensation as observed in unsaturated ketones1. Better results are obtained if perinaphthone (I) is first reduced with zinc dust in sodium hydroxide to the diketone (IV). This gives peropyrene very readily in a sodium chloride—zinc chloride melt.2 Peropyrene (III) is formed in small yield during the decarboxylation of trimethylenenaphthalenecarboxylic acid.3

Keywords

Aluminium Chloride Maleic Anhydride Copper Powder Manganese Dioxide Concentrate Sulphuric Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1964

Authors and Affiliations

  • E. Clar
    • 1
  1. 1.University of GlasgowScotland

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