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Real Gases

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Applied Statistical Thermodynamics

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Abstract

In the limit of very low density n all gases follow the law

EquationSource% MathType!MTEF!2!1!+- % feaagCart1ev2aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr % 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9 % vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x % fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaCbeaeaaci % GGSbGaaiyAaiaac2gaaSqaaiaad6gacaaMb8UaaGzaVlabgkziUkaa % ygW7caWGVbaabeaakiaaygW7caaMb8+aaSaaaeaacaWGWbGaamOvaa % qaaiaad6eacaWGlbGaamivaaaacaaMb8Uaeyypa0ZaaCbeaeaaciGG % SbGaaiyAaiaac2gaaSqaaiaad6gacaaMb8UaaGzaVlabgkziUkaayg % W7caWGVbaabeaakiaaygW7caaMb8UaaGzaVpaalaaabaGaamiCaiaa % dAfaaeaacaWGobGaamOuaiaadsfaaaGaaGzaVlabg2da9iaaygW7ca % aIXaaaaa!64D4!]]</EquationSource><EquationSource Format="TEX"><![CDATA[$$\mathop {\lim }\limits_{n \to 0} \frac{{pV}} {{NkT}} = \mathop {\lim }\limits_{n \to 0} \frac{{pV}} {{NRT}} = 1, $$

where p is the pressure, V the volume, N the number of molecules or moles, respectively, k Boltzmanns’s constant, R the gas constant, T the thermodynamic temperature, and n= N/V the number density or molar density, respectively.

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Authors and Affiliations

  1. University of Duisburg, Germany

    Klaus Lucas (Professor of Applied Thermodynamics, Scientific Director of the Institute of Environmental)

  2. Technology and Analysis e.V., Duisburg-Rheinhausen, Germany

    Klaus Lucas (Professor of Applied Thermodynamics, Scientific Director of the Institute of Environmental)

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  1. Klaus Lucas
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© 1991 Springer-Verlag Berlin Heidelberg

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Lucas, K. (1991). Real Gases. In: Applied Statistical Thermodynamics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-01648-0_5

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  • DOI: https://doi.org/10.1007/978-3-662-01648-0_5

  • Publisher Name: Springer, Berlin, Heidelberg

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