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Statistical Mechanics: Application to Real Fluids

  • Dimitrios P. Tassios

Abstract

Direct solution of the Schrödinger equation for real fluids is not possible. The potential energy of interaction among the molecules is mutual and, consequently, a separate energy cannot be attributed to each molecule. The lack of this energy separability does not allow the simplification of the partition function of the fluid in terms of that of the individual molecules. (Remember that this was the case with the ideal gas, because there the system energy is not mutual.)

Keywords

Partition Function Radial Distribution Function Molecular Simulation Intermolecular Force Virial Coefficient 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1993

Authors and Affiliations

  • Dimitrios P. Tassios
    • 1
    • 2
  1. 1.National Technical University of AthensZographos, AthensGreece
  2. 2.New Jersey Institute of TechnologyNewarkUSA

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