Abstract
The most useful reaction in the synthesis of symmetric tertiary stibines is the conversion of antimony trihalides with organometallic compounds, such as trialkylaluminums, trialkylaluminum etherates, Grignard reagents, organolithium, and organosodium derivatives, respectively, in ether, tetrahydrofuran, or benzene. The latter three types of reagents are useful in the synthesis of aliphatic as well as aromatic stibines. Triarylstibines are also formed by treating antimony trihalides with aryl halides and sodium or magnesium in benzene or ether and by diazotization of aromatic amines in the presence of antimony trichloride in an acid medium followed by a decomposition of the diazonium intermediates with zinc dust.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1968 Springer Science+Business Media New York
About this chapter
Cite this chapter
Dub, M. (1968). Antimony. In: Dub, M. (eds) Compounds of Arsenic, Antimony, and Bismuth. Organometallic Compounds, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-01611-4_2
Download citation
DOI: https://doi.org/10.1007/978-3-662-01611-4_2
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-01613-8
Online ISBN: 978-3-662-01611-4
eBook Packages: Springer Book Archive