Abstract
As mentioned in section 1.2.3, Li6[V10O28]·16H2O is decomposing during the standard electrode preparation. This could in part be due to the loss of the crystal water molecules, which stabilize the decavanadate units in the crystal structure via hydrogen bonds. Upon removal of the water molecules the separated decavanadate units form solid-state oxides, which have been shown to be LiVO3 and LiV3O8.[83] Both oxides differ severely from decavanadate regarding the coordination sphere of vanadium and the overall structure.
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Greiner, S. (2020). Results and Discussion. In: Novel Decavanadate Compounds for Lithium-Ion Batteries. BestMasters. Springer Spektrum, Wiesbaden. https://doi.org/10.1007/978-3-658-28985-0_3
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DOI: https://doi.org/10.1007/978-3-658-28985-0_3
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