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Combustion pp 65-84 | Cite as

Chemical Kinetics

  • Jürgen Warnatz
  • Ulrich Maas
  • Robert W. Dibble

Abstract

The thermodynamic laws discussed in Chapter 4 allow the determination of the equilibrium state of a chemical reaction system. If one assumes that the chemical reactions are fast compared to the other processes like diffusion, heat conduction, and flow, thermodynamics alone allow the description of the system locally (see, e. g., Section 13.1). In most cases, however, chemical reactions occur on time scales comparable with that of the flow and of the molecular transport processes. Therefore, information is needed about the rate of chemical reactions, i. e., the chemical kinetics. Thus, the basic laws of chemical kinetics shall be discussed in the following, which are based on macroscopic observation. The chapter will show that these macroscopic rate laws are a consequence of the underlying microscopic phenomena of collisions between molecules.

Keywords

Rate Coefficient Chemical Kinetic Elementary Reaction Bimolecular Reaction Microwave Discharge 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1999

Authors and Affiliations

  • Jürgen Warnatz
    • 1
  • Ulrich Maas
    • 2
  • Robert W. Dibble
    • 3
  1. 1.Universität Heidelberg Interdisziplinäres Zentrum für Wissenschaftliches RechnenHeidelbergGermany
  2. 2.Institut für Technische VerbrennungUniversität StuttgartStuttgartGermany
  3. 3.Department of Mechanical EngineeringUniversity of CaliforniaBerkeleyUSA

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