The Independent-Electron Approximation

  • Peter Fulde
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 100)

Abstract

Calculations within the independent-electron approximation are often a prerequisite for those which include correlation effects. The assumption of independently moving electrons implies that the total wavefunction of the iV-eLectron system Φ(r 1σ1, … ,r N σ N ) can be written in the form of an anti-symmetrized product of single-electron wavefunctions ϕ(r i σ i ).

Keywords

Phosphorus Benzene Hydrocarbon Metal Metal 

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Chapter 2

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Copyright information

© Springer -Verlag Berlin Heidelberg 1993

Authors and Affiliations

  • Peter Fulde
    • 1
  1. 1.MPI für FestkörperforschungStuttgart 80Deutschland

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