Abstract
We saw in Chap. 5 that an STE in alkali halides can be described as an excited dimer (excimer), X2− 2, on the halide sublattice, generally accompanied by off-center relaxation of the excimer ion (X− 2) relative to the excited electron wave function. Partly because of the prominent nature of STE phenomena in alkali halides and related ionic crystals, one sometimes sees self-trapped excitons characterized as a phenomenon of ionic insulators. However, the experimental study of excimers in pure organic crystals actually predated their discovery in alkali halides by about 6 yr [8.1]. The organic excimers were not commonly called self-trapped excitons until the late 197O’s, when Matsui and Nishimura showed that excimer formation in a pure organic crystal is quite naturally described within the framework of exciton self-trapping [8.2]. Some of the experimental observations on excimers to be discussed bear an interesting resemblance to phenomena in alkali halides.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. Ferguson: J. Chem. Phys. 28, 765 (1958)
A. Matsui, H. Nishimura: J. Phys. Soc. Jpn. 49, 657 (1980)
L. Friedman: Phys. Rev. 133, A1668 (1964)
T. Holstein: Ann. Phys. (N.Y.) 8, 343 (1959)
J.M. Robertson, J.G. White: J. Chem. Soc. 358 (1947)
A. Matsui, M. Iemura, H. Nishimura: J. Lum. 24/25, 445 (1981)
J.B. Birks, A.A. Kazzaz: Proc. Roy. Soc. A304, 291 (1968)
K. Mizuno, A. Matsui: J. Lumin. 38, 323 (1987)
D.M. Donaldson, J.M. Robertson, J.G. White: Proc. Roy. Soc. London A220, 311(1953)
A. Matsui, K. Mizuno, M. Iemura: J. Phys. Soc. Jpn 51, 1871 (1982)
T. Kobayashi: J. Chem Phys. 69, 3570 (1978)
A. Matsui, K. Mizuno: J. Phys. Soc. Japan 51, 3206 (1982)
M. Schreiber, Y. Toyozawa: J. Phys. Soc. Japan 51, 1544 (1982)
M. Furukawa, K. Mizuno, A. Matsui, N. Tamai, I. Yamazaki: Chem. Phys. 138, 423(1989)
A. Matsui, M. Furukawa, K. Mizuno, N. Tamai, I. Yamazaki: J. Lum. 45, 269(1990)
K. Nasu: J. Lum. 38, 90 (1987)
M. Kobayashi, K. Mizuno, A. Matsui: J. Phys. Soc. Jpn 58, 809 (1989)
R. Horiguchi, N. Iwasaki, Y. Maruyama: J. Phys. Chem. 91, 5135 (1987)
K. Mizuno, A. Matsui: J. Phys. Soc. Jpn 55, 2427 (1985)
M. Kobayashi, Y. Ohno, S. Endo, K. Cho, S. Narita: Physica 117B/118B, 272 (1983)
M. Kobayashi, T. Kawamura, S. Endo, K. Cho, S. Narita: Solid State Commun. 48, 33(1983)
T. Yokoyama, M. Kobayashi: J. Phys. Soc. Jpn 54, 2329 (1985)
U. Rossler, H. Yersin: Phys. Rev. B 26, 3187 (1982)
H. Nishimura, T. Yamaoka, K. Mizuno, M. Iemura, A. Matsui: J. Phys. Soc. Jpn 53, 3999 (1984)
T. Azumi, A.T. Armstrong, S.P. McGlynn: J. Chem. Phys. 41, 3839 (1964)
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1993 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Song, K.S., Williams, R.T. (1993). Simple Organic Molecular Crystals. In: Self-Trapped Excitons. Springer Series in Solid-State Sciences, vol 105. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-97432-8_8
Download citation
DOI: https://doi.org/10.1007/978-3-642-97432-8_8
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-97434-2
Online ISBN: 978-3-642-97432-8
eBook Packages: Springer Book Archive