Skip to main content

Abstract

In general the methods which have been used to elucidate the structures of the gums and mucilages are similar to those which have been employed to determine the detailed architecture of the glucose polymers cellulose and starch (for general reviews see the books by Heuser 1944, and by Radley 1953). The composition of the gums and mucilages is however much more complicated than is that of cellulose and more complex than that of starch in that several neutral sugars may be present in the molecule. These sugars are often joined to one another in the most diverse manner and frequently have attached to them acetyl or methoxyl groups. An added complication is caused by the presence in some cases of d-glucuronic acid or its 4-O-methyl ether or of d-galacturonic acid. Up to the present basic sugars such as d-glucosamine or d-galactosamine have not been encountered in plant gums and mucilages. For the purpose of the present article no special separation will be made between the gums and mucilages in so far as their chemistry is concerned. It suffices to say that in general gums are exuded materials which can be collected as such in a relatively pure state whereas mucilages are components of seeds, bark, roots, etc., and must be isolated by some physical process, such as extraction with water, before they can be obtained in a relatively pure form (for a general review see the book by Mantel 1947). The vexed problem of the homogeneity of the gums and mucilages has yet to be solved.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 54.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature

  • Ahmed, Z. F., and R. L. Whistler: The structure of guaran. J. Amer. Chem. Soc. 72, 2524–2525 (1950).

    Article  CAS  Google Scholar 

  • Anderson, E.: The preparation of l-galactose from flax seed mucilage J. of Biol. Chem. 100, 249–253 (1933).

    CAS  Google Scholar 

  • Anderson, E., and M. Fireman: The mucilage from psyllium seed, Plantago Psyllium L. J. of Biol. Chem. 109, 437–442 (1935).

    CAS  Google Scholar 

  • Anderson, E., Lila Sands and N. Sturgis: Some plant gums of the Southwestern United States. Amer. J. Pharmacy 97, 589–592 (1925).

    CAS  Google Scholar 

  • Andrews, P.: Ph. D. Thesis, University of Bristol, England, 1953.

    Google Scholar 

  • Andrews, P., D. H. Ball and J. K. N. Jones: The isolation of oligosaccharides from gums and mucilages. I. J. Chem. Soc. (Lond.) 1953, 4090–4095.

    Google Scholar 

  • Andrews, P., L. Hough and J.K.N. Jones: Mannose-containing polysaccharides. I. The galactomannans of lucerne and clover seeds. J. Amer. Chem. Soc. 74, 4029–4032 (1952a).

    Article  CAS  Google Scholar 

  • Mannose-containing polysaccharides. II. The galactomannan of fenugreek seed (Trigonella foenum-graecum). J. Chem. Soc. (Lond.) 1952b, 2744–2750.

    Google Scholar 

  • Mannose-containing polysaccharides. III. The polysaccharides in the seed of Iris ochroleuca and I. sibirica. J. Chem. Soc. (Lond.) 1953, 1186–1192.

    Google Scholar 

  • Andrews, P., and J. K. N. Jones: The isolation of oligosaccharides from gums and mucilages. III. Golden apple gum. J. Chem. Soc. (Lond.) 1954, 4134–4138.

    Google Scholar 

  • The isolation of oligosaccharides from gums and mucilages. IV. The isolation of 3-0-β-l-arabopyranosyl-l-arabinose from lemon gum. J. Chem. Soc. (Lond.) 1955, 583–584.

    Google Scholar 

  • Araki, C.: Chemical studies on agar-agar. XIII. 1. Separation of agarobiose from the agar-agar-like substance of Gelidium amansii by partial hydrolysis. J. Chem. Soc. Japan 65, 533–538 (1944).

    CAS  Google Scholar 

  • 2. Chemical constitution of agarobiose. J. Chem. Soc. Japan 65, 627–632 (1944).

    Google Scholar 

  • Araki, C., and S. Hirase: Chemical constitution of agar-agar. XV. Exhaustive mercaptolysis of agar-agar. Bull. Chem. Soc. Japan 26, 463–467 (1953).

    Article  CAS  Google Scholar 

  • XVI. Isolation of crystalline agarobiose diethyl mercaptal by mercaptolysis of agar-agar. Bull. Chem. Soc. Japan 27, 105–109 (1954).

    Google Scholar 

  • XVII. Isolation of crystalline agarobiose dimethylacetal by partial methanolysis of agar-agar. Bull. Chem. Soc. Japan 27, 109–112 (1954).

    Google Scholar 

  • Aspinall, G. O., E. L. Hirst and N. K. Matheson: Plant gums of the genus Khaya. The structure of K. grandifolia gum. J. Chem. Soc. (Lond.) 1956.

    Google Scholar 

  • Aspinall, G. O., E. L. Hirst, E. G. V. Percival and I. R. Williamson: The mannans of ivory nut (Phytelephas macrocarpa). I. The methylation of mannan A and mannan B. J. Chem. Soc. (Lond.) 1953, 3184–3188.

    Google Scholar 

  • Aspinall, G. O., E. L. Hirst and A. Wickstrøm: Gum ghatti (Indian gum). The composition of the gum and the structure of two aldobiouronic acids derived from it. J. Chem. Soc. (Lond.) 1955, 1160–1165.

    Google Scholar 

  • Bailey, K.: Cress seed mucilage. Biochemic. J. 29, 2477–2485 (1935).

    CAS  Google Scholar 

  • Bailey, K., and F. W. Norris: Nature and composition of the mucilage of the seed of white mustard (Brassica alba). Biochemic. J. 26, 1609–1623 (1932).

    CAS  Google Scholar 

  • Ball, D. H., J. K. N. Jones and W. H. Nicholson: The acid reversion products of xylose and arabinose. Abstracts, Amer. Chem. Soc. Meeting, Minneapolis, Sept. 1955.

    Google Scholar 

  • Barnett, W. L.: A new method for the production of cellulose acetate. J. Soc. Chem. Ind. 40, 8 T to 10 T (1921).

    Google Scholar 

  • Barry, V. C.: Regulated degradation of 1,3 polysaccharides. Nature (Lond.) 152, 537–538 (1943).

    Article  CAS  Google Scholar 

  • Barry, V. C., and T. Dillon: A galactan sulfuric ester from Dilsea edulis. Proc. Roy. Irish Acad. B 50, 349–358 (1945).

    Google Scholar 

  • Barry, V. C., T. Dillon and W. Mc Gettrick: Periodic acid as a test for the constitution of polysaccharides. J. Chem. Soc. (Lond.) 1942, 183–185.

    Google Scholar 

  • Barry, V. C., Joan E. Mc Cormick and P. W. D. Mitchell: Properties of periodate-oxidised polysaccharides. III. Estimation of α-glycol groupings in a polysaccharide. J. Chem. Soc. (Lond.) 1954, 3692–3696.

    Google Scholar 

  • Bauer, R.W.: Über den aus Agar-agar entstehenden Zucker, über eine neue Säure aus der Arabinose nebst dem Versuch einer Classification der gallertbildenden Kohlenhydrate nach den aus ihnen entstehenden Zuckerarten. J. prakt. Chem. (2) 30, 367–388 (1884).

    Article  Google Scholar 

  • Baum, H.A., and G. A. Gilbert: The anaerobic dispersion of potato starch. Oxygen-sensitive bonds in starch. Chem. a. Ind. 1954, 489–490.

    Google Scholar 

  • The anaerobic fractionation of potato starch. Chem. a. Ind. 1954, 490.

    Google Scholar 

  • Benjamin, H. B., H. K. Ihrig and D. A. Roth: The use of okra as a plasma replacement. Rev. Canad. de Biol. 10, 215–221 (1951).

    CAS  Google Scholar 

  • Brown, F., S. Dunstan, T. G. Halsall, E. L. Hirst and J.K.N. Jones: Application of new methods of end-group determination to structural problems in the polysaccharides. Nature (Lond.) 156, 785–786 (1945).

    Article  CAS  Google Scholar 

  • Brown, F., E. L. Hirst and J. K. N. Jones: Cholla gum. J. Chem. Soc. (Lond.) 1949, 1761–1766.

    Google Scholar 

  • Buchanan, J., E. G. V. Percival and Elizabeth E. Percival: The polysaccharides of Carragheen moss (Chondrus crispus). I. The linkage of the d-galactose residues and the ethereal sulphate. J. Chem. Soc. (Lond.) 1943, 51–54.

    Google Scholar 

  • Challinor, S. W., W. N. Haworth and E. L. Hirst: The compound uronic acids. Structure of the aldobionic acid from gum arabic. J. Chem. Soc. (Lond.) 1931, 258–265.

    Google Scholar 

  • Charlson, A. J., J. R. Nunn and A. M. Stephen: The composition of Acacia cyanophylla gum. J. Chem. Soc. (Lond.) 1955, 269–273.

    Google Scholar 

  • Acacia karroo gum. J. Chem. Soc. (Lond.) 1955, 1428–1431.

    Google Scholar 

  • Conchie, J., and E. G. V. Percival: Fucoidin. II. The hydrolysis of a methylated fucoidin prepared from Fucus vesiculosus. J. Chem. Soc. (Lond.) 1950, 827–832.

    Google Scholar 

  • Connell, J. J., Ruth M. Hainsworth, E. L. Hirst and J. K. N. Jones: Grapefruit and lemon gums. I. The ratio of sugars present in the gums and the structure of the aldobionic acid (4-d-glucuronoside-d-galactose) isolated by graded hydrolysis of the polysaccharides. J. Chem. Soc. (Lond.) 1950, 1696–1700.

    Google Scholar 

  • Deuel, H., R. Leuenberger u. G. Huber: Übder en enzymatischen Abbau von Carubin, dem Galaktomannan aus Ceratonia siliqua L. Helvet. chim. Acta 33, 942–946 (1950).

    Article  CAS  Google Scholar 

  • Dewar, E. T., and E. G. V. Percival: The polysaccharides of Carragheen. II. The Gigartina stellata polysaccharide. J. Chem. Soc. (Lond.) 1947, 1622–1626.

    Google Scholar 

  • Dillon, T.: Constitution of gum arabic. XIIIth Internat. Congress of Pure and Applied Chemistry, Stockholm, Sweden, Abstracts, p. 217, 1953.

    Google Scholar 

  • Dillon, T., and J. Mc Kenna: Mucilage of Dilsea edulis. II. Proc. Roy. Irish Acad. B 53, 45–54 (1950).

    Google Scholar 

  • Dunstan, Sonia, and E. L. Hirst: The structure of Karaya gum (Cochlospermum gossypium). J. Chem. Soc. (Lond.) 1953, 2332–2337.

    Google Scholar 

  • Easterby, D. G.: Ph.D. thesis, University of Bristol, England, 1951.

    Google Scholar 

  • Erskine, A. J.: M. A. thesis, Queen’s University, Kingston, Ontario, Canada 1954.

    Google Scholar 

  • Gill, R. E., E. L. Hirst and J. K. N. Jones: Constitution of the mucilage from the bark of Ulmus fulva (slippery elm mucilage). I. The aldobionic acid obtained by hydrolysis of the mucilage. J. Chem. Soc. (Lond.) 1939, 1469–1471.

    Google Scholar 

  • Constitution of the mucilage from the bark of Ulmus fulva (slippery elm mucilage). II. The sugars formed in the hydrolysis of the methylated mucilage. J. Chem. Soc. (Lond.) 1946, 1025–1029.

    Google Scholar 

  • Goring, D. A. I., and E. G. Young: Studies on Carrageenin: Comparisons of fractions obtained with potassium chloride and by successive extraction at elevated temperatures. Canad. J. Chem. 33, 480 (1955).

    Article  CAS  Google Scholar 

  • Halsall, T. G., E. L. Hirst and J.K.N. Jones: The structure of glycogen. Ratio of non-terminal to terminal glucose residues. J. Chem. Soc. (Lond.) 1947, 1399–1400.

    Google Scholar 

  • Oxidation of carbohydrates by the periodate ion. J. Chem. Soc. (Lond.) 1947, 1427–1432.

    Google Scholar 

  • Hands, S., and S. Peat: Isolation of an anhydro-l-galactose derivative from agar. Nature (Lond.) 142, 797 (1938).

    Article  CAS  Google Scholar 

  • Heuser, E.: The chemistry of cellulose. New York: John Wiley & Sons 1944.

    Google Scholar 

  • Hirst, E. L.: The chemistry of plant gums and mucilages. Endeavour 10, 106–111 (1951).

    CAS  Google Scholar 

  • Hirst, E. L., L. Hough and J. K. N. Jones: The structure of Sterculia setigera gum. I. An investigation by the method of paper partition chromatography of the products of hydrolysis of the gum. J. Chem. Soc. (Lond.) 1949, 3145–3151.

    Google Scholar 

  • Hirst, E. L., and J. K. N. Jones: The constitution of Damson gum. I. Composition of Damson gum and structure of an aldobionic acid (glycuronosido-2-mannose) derived from it. J. Chem. Soc. (Lond.) 1938, 1174–1180.

    Google Scholar 

  • The constitution of Damson gum. II. Hydrolysis products from methylated degraded (arabinose-free) Damson gum. J. Chem. Soc. (Lond.) 1939, 1482–1490.

    Google Scholar 

  • The constitution of Damson gum. III. Hydrolysis products from methylated Damson gum. J. Chem. Soc. (Lond.) 1946, 506–512.

    Google Scholar 

  • The constitution of egg-plum gum. I. J. Chem. Soc. (Lond.) 1947, 1064–1068.

    Google Scholar 

  • The galactomannan of carob-seed gum (gum gatto). J. Chem. Soc. (Lond.) 1948, 1278–1282.

    Google Scholar 

  • Moderne Methoden der Pflanzenanalyse, edited by K. Paech and M. V. Tracey, vol. II, p. 275–294. Berlin: Springer 1954.

    Google Scholar 

  • Hirst, E. L., E. G. V. Percival and Clare B. Wylam: Studies on seed mucilages. VI. The seed mucilage of Plantago arenaria. J. Chem. Soc. (Lond.) 1954, 189–198.

    Google Scholar 

  • Hirst, E. L., and A. S. Perlin: The gum of Acacia pycnantha. J. Chem. Soc. (Lond.) 1954, 2622–2627.

    Google Scholar 

  • Hotchkiss, R. D., and W. F. Goebel: Derivatives of glucuronic acid. VII. Synthesis of aldobionic acids. J. of Biol. Chem. 115, 285–292 (1936).

    CAS  Google Scholar 

  • Hough, L., and J. K. N. Jones: The structure of Sterculia setigera gum. II. An investigation by the method of paper partition chromatography of the products of hydrolysis of the methylated gum. J. Chem. Soc. (Lond.) 1950, 1199–1203.

    Google Scholar 

  • Hough, L., J. K. N. Jones and W. H. Wadman: Some observations on the constitution of gum myrrh. J. Chem. Soc. (Lond.) 1952, 796–800.

    Google Scholar 

  • Jackson, J., and F. Smith: The constitution of arabic acid. III. The isolation of methyl heptamethyl aldobionate from methylated degraded arabic acid. J. Chem. Soc. (Lond.) 1940, 74–78.

    Google Scholar 

  • The constitution of arabic acid. IV. The formation of 3-galactosidogalactose by hydrolysis of degraded arabic acid. J. Chem. Soc. (Lond.) 1940, 79–82.

    Google Scholar 

  • James, Sybil p., and F. Smith: The chemistry of gum Tragacanth. I. Tragacanthic acid. J. Chem. Soc. (Lond.) 1945, 739–746.

    Google Scholar 

  • The chemistry of gum tragacanth. II. Derivatives of d- and L-fucose. J. Chem. Soc. (Lond.) 1945, 746–748.

    Google Scholar 

  • The chemistry of gum tragacanth. III. J. Chem. Soc. (Lond.) 1945, 749–751.

    Google Scholar 

  • Johnston, R., and E. G. V. Percival: The polysaccharides of carragheen. III. Confirmation of the l:3-linkage in carragheenin and the isolation of l-galactose derivatives from a resistant fragment. J. Chem. Soc. (Lond.) 1950, 1994–1998.

    Google Scholar 

  • Jones, J. K. N.: The structure of the mannan present in Porphyra umbilicalis. J. Chem. Soc. (Lond.) 1950, 3292–3295.

    Google Scholar 

  • Larch ε-galactan. II. The isolation of 3-β-l-arabopyranosyl l-arabinose. J. Chem. Soc. (Lond.) 1953, 1672–1675.

    Google Scholar 

  • Jones, J. K. N., and J. R. Nunn: The constitution of gum myrrh. II. J. Chem. Soc. (Lond.) 1955, 3001–3004.

    Google Scholar 

  • Jones, J. K. N., and F. Smith: Plant gums and mucilages. Adv. Carbohydrate Chem. 4, 243–291 (1949).

    Article  CAS  Google Scholar 

  • Jones, W. G. M., and S. Peat: The constitution of agar. J. Chem. Soc. (Lond.) 1942, 225–231.

    Google Scholar 

  • Kylin, H.: Biochemistry of sea algae. Z. physiol. Chem. 83, 171–197 (1913).

    Article  CAS  Google Scholar 

  • Larson, E. B., and F. Smith: The constitution of the galactomannan of the seeds of the Kentucky coffee bean (Gymnocladus dioica). J. Amer. Chem. Soc. 77, 429–432 (1955).

    Article  CAS  Google Scholar 

  • Mantel, C. L.: The water-soluble gums. New York: Reinhold Publishing Corp. 1947.

    Google Scholar 

  • Masson, C. R., and G. W. Caines: Viscosity and molecular weight of degraded carrageenin. Canad. J. Chem. 32, 51–58 (1954).

    Article  CAS  Google Scholar 

  • Mathur, G. P., and S. N. Mukherjee: Aldobiouronic acid, 3-(glycuronopyranosyl)-d-galactopyranose from ketha gum. J. Sci. Industr. Res. (India) B 13, 452–453 (1954).

    Google Scholar 

  • Mori, T.: Seaweed polysaccharides. Adv. Carbohydrate Chem. 8, 317–350 (1953).

    Google Scholar 

  • Mukherjee, S. N.: Gum jeol. VIII. Interaction of jeolic acid with acids and bases. J. Indian Chem. Soc. 30, 201–204 (1953).

    Google Scholar 

  • Mukherjee, S. N., and G. Banarjee: Gum jeol. I. Solution and purification. J. Indian Chem. Soc. 25, 59–63 (1948).

    CAS  Google Scholar 

  • Mukherjee, S. N., and S. C. Chakravarti: Studies on gum jeol (Odina wodier). III. The aldobionic acid. J. Indian Chem. Soc. 1948, 113–118.

    Google Scholar 

  • Mukherjee, S. N., and R. N. R. Choudhury: Gum jeol (Lannea grandis). VIL Properties of jeolic acid in aqueous solution. I. Indian Chem. Soc. 30, 198–200 (1953).

    CAS  Google Scholar 

  • Mukherjee, S. N., and S. K. Sinha: Gum jeol. IX. Interaction of jeolic acid with nonelectrolytes. J. Indian Chem. Soc. 30, 647–651 (1953).

    CAS  Google Scholar 

  • Mukherjee, S. N., and H. C. Srivastava: The structure of neem gum. J. Amer. Chem. Soc. 77, 422–423 (1955).

    Article  CAS  Google Scholar 

  • Neuberg, C., and H. Ohle: The sulfur content of agar. Biochem. Z. 125, 311–313 (1921).

    CAS  Google Scholar 

  • Nishida, K., and H. Hashima: Chemical examination of the glucomannan obtained from “Konjak”. J. Dept. Agricult. Kyushu Imp. Univ. 2, 277–360 (1930).

    CAS  Google Scholar 

  • O’Neill, A. N.: Degradative studies on fucoidin. J. Amer. Chem. Soc. 76, 5074–5076 (1954).

    Article  Google Scholar 

  • 3,6-Anhydro-d-galactose as a constituent of ϰ-carrageenin. Amer. Chem. Soc. Meeting, New York, Sept. 1954. J. Amer. Chem. Soc. 77, 2837–2839 (1955).

    Google Scholar 

  • O’Sullivan, C.: Researches on the gums of the arabin group. II. Geddic acids, gedda gums; the dextrorotatory varieties. J. Chem. Soc. 59, 1029–1075 (1891).

    Article  Google Scholar 

  • Palmer, K. J., and M. Ballantyne: The structure of (I) some pectin esters and (II) guar galactomannan. J. Amer. Chem. Soc. 72, 736–741 (1950).

    Article  CAS  Google Scholar 

  • Percival, Elizabeth E.: The mercaptolysis of the polysaccharide from Chondrus crispus. Chem. a. Ind. 1954, 1487.

    Google Scholar 

  • Percival, E. G. V.: Carbohydrate sulphate s. Quart. Rev. Chem. Soc. 3, 369–384 (1949).

    Article  CAS  Google Scholar 

  • Percival, E. G. V., and A. G. Ross: Fucoidin. I. The isolation and purification of fucoidin from brown seaweeds. J. Chem. Soc. (Lond.) 1950, 717–720.

    Google Scholar 

  • Percival, E. G. V., J. C. Somerville and I. A. Forbes: Isolation of an anhydro-l-galactose derivative from agar. Nature (Lond.) 142, 797–798 (1938).

    Article  CAS  Google Scholar 

  • Percival, E. G. V., and T. G. H. Thomson: Studies on agar-agar. IV. J. Chem. Soc. (Lond.) 1942, 750–755.

    Google Scholar 

  • Perlin, A. S.: Isolation and composition of the soluble pentosans of wheat flours. Cereal Chem. 28, 370–381 (1951).

    CAS  Google Scholar 

  • Radley, J. A.: Starch and its derivatives, vols. I and II. London: Chapman & Hall 1953.

    Google Scholar 

  • Rafiqtte, C. M., and F. Smith: The constitution of guar gums. J. Amer. Chem. Soc. 72, 4634–4637 (1950).

    Article  Google Scholar 

  • Rebers, P. A., and F. Smith: The constitution of iles mannan. J. Amer. Chem. Soc. 76, 6097–6102 (1954).

    Article  CAS  Google Scholar 

  • Renfrew, Alice G., and L. H. Cretcher: Quince-seed mucilage. J. of Biol. Chem. 97, 503–510 (1932).

    CAS  Google Scholar 

  • Selby, K.: The methoxyl content of gum tragacanth. J. Chem. Soc. (Lond.) 1953, 2504.

    Google Scholar 

  • Smith, D. B., A. N. O’Neill and A. S. Perlin: Studies on the heterogenity of carrageenin. Canad. J. Chem. 33, 1352–1360 (1955).

    Article  CAS  Google Scholar 

  • Smith, F.: The constitution of arabic acid. I. The isolation of 3-d-galactosido-l-arabinose. J. Chem. Soc. (Lond.) 1939, 744–753.

    Google Scholar 

  • The constitution of arabic acid. V. Methylated arabic acid. J. Chem. Soc. (Lond.) 1940, 1035–1051.

    Google Scholar 

  • The constitution of carob gum. J. Amer. Chem. Soc. 70, 3249–3253 (1948).

    Google Scholar 

  • The constitution of mesquite gum. III. The structure of the monomethyl glucuronic acid component. J. Chem. Soc. (Lond.) 1951, 2646–2652.

    Google Scholar 

  • Smith, F., and D. Spriestersbach: Reduction of the products of periodate oxidation of carbohydrates. IV. The constitution of gum arabic. Amer. Chem. Soc. Meeting, Minneapolis, Sept., 1955. Abstracts of Papers, 15 D.

    Google Scholar 

  • Stephen, A. M.: Acacia mollissima Willd. I. The component sugars and aldobiouronic acid of black wattle gum. J. Chem. Soc. (Lond.) 1951, 646–649.

    Google Scholar 

  • Tipson, R. S., C. C. Ciiristman and P. A. Levene: Structure of the aldobionic acid from flaxseed mucilage. J. of Biol. Chem. 128, 609–620 (1939).

    CAS  Google Scholar 

  • Wadman, W. H.: Some reactions of sugars catalysed by a cation-exchange resin. J. Chem. Soc. (Lond.) 1952, 3051–3055.

    Google Scholar 

  • Whistler, R. L., and H. E. Conrad: A crystalline galactobiose from acid hydrolysis of okra mucilage. J. Amer. Chem. Soc. 76, 1673–1674 (1954).

    Article  CAS  Google Scholar 

  • 2-O-(d-galactopyranosyluronic acid)-l-rhamnose from okra mucilage. J. Amer. Chem. Soc. 76, 3544–3546 (1954).

    Google Scholar 

  • Whistler, R. L., and D. F. Durso: The isolation and characterization of two crystalline disaccharides from partial acid hydrolysis of guaran. J. Amer. Chem. Soc. 73, 4189–4190 (1951).

    Article  CAS  Google Scholar 

  • A new crystalline trisaccharide from partial acid hydrolysis of guaran and the structure of guaran. J. Amer. Chem. Soc. 74, 5140–5141 (1952).

    Google Scholar 

  • Whistler, R. L., and C. L. Smart: Polysaccharide chemistry. New York: Academic Press 1953.

    Google Scholar 

  • Whistler, R. L., and C. G. Smith: A crystalline mannotriose from the enzymatic hydrolysis of guaran. J. Amer. Chem. Soc. 74, 3795–3796 (1952).

    Article  CAS  Google Scholar 

  • Whistler, R. L., and Joan Z. Stein: A crystalline mannobiose from the enzymatic hydrolysis of guaran. J. Amer. Chem. Soc. 73, 4187–4188 (1951).

    Article  CAS  Google Scholar 

  • White, E. V.: The constitution of mesquite gum. IV. 4-Methoxy-d-glucuronic acid. J. Amer. Chem. Soc. 70, 367–369 (1948).

    Article  CAS  Google Scholar 

  • Occurrence of the l-arabinose unit in sapote gum. J. Amer. Chem. Soc. 74, 3966 (1952).

    Google Scholar 

  • The constitution of sapote gum. I. Methanolysis of sapote gum methyl ether. J. Amer. Chem. Soc. 75, 257–259 (1953).

    Google Scholar 

  • The constitution of sapote gum. III. A structural evaluation. J. Amer. Chem. Soc. 76, 4906–4909 (1954).

    Google Scholar 

  • White, E. V., and P. S. Rao: Constitution of the polysaccharide from tamarind seed. J. Amer. Chem. Soc. 75, 2617–2619 (1953).

    Article  CAS  Google Scholar 

  • Wise, L. E.: The polysaccharides from iles mannan. Arch. of Biochem. 23, 127–130 (1949).

    CAS  Google Scholar 

  • Wolfrom, M. L., and W. B. Neely: The uronic acid component of chondroitinsulfuric acid. J. Amer. Chem. Soc. 75, 2778–2781 (1953).

    Article  CAS  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1958 Springer-Verlag oHG. Berlin · Göttingen · Heidelberg

About this chapter

Cite this chapter

Hirst, E.L., Jones, J.K.N. (1958). The gums and mucilages of plants. In: Åberg, B., et al. Aufbau · Speicherung · Mobilisierung und Umbildung der Kohlenhydrate / Formation · Storage · Mobilization and Transformation of Carbohydrates. Handbuch der Pflanzenphysiologie / Encyclopedia of Plant Physiology, vol 6. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-94731-5_20

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-94731-5_20

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-94732-2

  • Online ISBN: 978-3-642-94731-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics