Abstract
This paper presents a review of some recent theoretical and experimental work on adsorption from organic liquid mixtures by graphitised carbon blacks. Several relatively simple systems conform reasonably well to approximate theoretical models, but for systems involving higher alkanes and alkanols adsorbed from solution in a lower alkane, complex phenomena are observed which indicate molecular structuring of the higher molecular weight component near the surface. Some preliminary data on very dilute solutions are also reported which again show strong co-operative adsorption at low temperatures.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Ash, S. G., D. H. Everett, C. J. Radke, J. C. S. Faraday II, 69, 1256 (1973);
D. H. Everett, C. J. Radke, A. C. S. Symposium Series no. 8, chapter 1, p. 1, (1975);
D. H. Everett, Israel J. Chem., 14, 267 (1975);
D. G. Hall, J. C. S. Faraday II, 68 (1972).
IUPAC, Manual of Symbols and Terminology for Physico-chemical Quantities and Units, Appendix II, Part I, Definitions, Terminology and Symbols in Colloid and Surface Chemistry; Pure and Applied Chemistry, 31, 579 (1972).
Everett, D. H. in Specialist Periodical Reports: Colloid Science (Chemical Society, London) Vol. 1, chapter 2 (1973).
IUPAC, Manual of Symbols and Terminology for Physico-chemical Quantities and Units, Appendix II, Part II, Heterogeneous Catalysis; Pure and Applied Chemistry, 46, 73 (1976).
Ref. 3, p. 65; A. L. Myers and S. Sircar, J. Phys. Chem., 76, 3412 (1972).
Sircar, S. and A. L. Myers, A. I. Ch. E. Journal, 19, 159 (1973).
Ldrionov, O. G., K. V. Chmutov and M. D. Yudelevich, Zhur. fiz. Khim., 41, 2616 (1967), (Russ. J. Phys. Chem., 41, 1417 (1967).
Everett, D. H. and R. T. Podoll in Specialist Periodical Reports: Colloid Science (Chemical Society, London) to appear 1978.
Brown, C. J. and D. H. Everett in Specialist Periodical Reports: Colloid Science (Chemical Society, London) Vol. 2, chapter 2 (1975).
Everett, D. H., Trans. Faraday Soc., 60, 1803 (1964).
Rusanov, A. I., Phase Equilibrium and Surface Phenomena (in Russian), chapter VI (Chimia, Leningrad 1967).
Everett, D. H., Trans. Faraday Soc., 61, 2478 (1965).
Defay, R. and I. Prigogine, Trans. Faraday Soc., 46, 199 (1950).
see S. Ono and S. Kondo, Encyclopaedia of Physics, ed. Flügge, Vol. X, p. 159 (Springer, Berlin, 1960);
J. E. Lane, Austral. J. Chem., 21, 827 (1968).
Parfitt, G. D. and E. Willis, J. Phys. Chem., 63, 1780 (1964);
G. D. Parfitt and P. C. Thompson, Trans. Faraday Soc., 67, 3372 (1971).
Kiselev, A. V., V. V. Khopina and Yu, A. Eltekov, Zhur. fiz. Khim., 48, 760 (1974) (Russ. J. Phys. Chem., 48, 440 (1974).
Ash, S. G., Ph. D. thesis, Bristol (1970);
S. G. Ash, R. Bown, and D. H. Everett, J. Chemical Thermodynamics, 5, 239 (1973) (a somewhat similar design of apparatus was described by E. Kurbanbekov, O. G. Larionov, K. V. Chmutov, and M. D, Yudelevich, Zhur. fiz. Khim., 43, 1630 (1969) (Russ. J. Phys. Chem., 43, 916) (1969).
Sharma, S. C. and T. Fort, J. Colloid and Interface Sci., 43, 36 (1973).
Ash, S. G., R. Bown, and D. H. Everett, J. C. S. Faraday I, 71, 123 (1975);
Brown, C. E., D. H. Everett, and C. J. Morgan, ibid., 71, 883 (1975).
e.g., G. L Berezin, A. V. Kiselev, and V. A. Sinitsyn, Zhur. fiz. Khim., 44, 734 (1970) (Russ. J. Phys. Chem., 44, 408) (1970);
A. V. Kiselev, J. Colloid and Interface Sci., 28, 430 (1968).
Kurbanbekov, E., O. G. Larionov, K. V. Chmutov, and M. D. Yudelevich, Zhur. fiz. Khim., 47, 1617, 1618 (1973) (Russ. J. Phys. Chem., 47, 919, 920 (1973));
S. A. Kazaryan, O. G. Larionov, K. V. Chmutov, and M. D. Yudelevich, ibid, 47, 1619, 2171 (ibid, 920, 921, 1231) (1973).
see ref. 8.
Patterson, I., unpublished.
Bown, R., Ph. D. thesis, Bristol (1973); to be published.
Everett, D. H. and R. J. Munn, Trans. Faraday Soc., 60, 1951 (1964).
Thome, P. E., Ph. D. thesis, Bristol (1974); to be published.
Brown, C. E., D. H. Everett, A. V. Powell, and P. E. Thorne, Faraday Dicussions, Chemical Society, 59, 97 (1975).
Brown, C. E. and D. H. Everett, in preparation.
Smith, R, W., Ph. D. thesis, Bristol, in preparation.
Martin, J., unpublished data obtained at NPL Teddington.
Findenegg, G. H., this Discussion.
Podoll, R. T., unpublished.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1978 Dr. Dietrich Steinkopff Verlag, Darmstadt
About this paper
Cite this paper
Everett, D.H. (1978). Thermodynamics of adsorption from non-aqueous solutions. In: Lagaly, G., Müller, F.H., Weiss, A. (eds) Lösungen und Adsorption. Verhandlungsberichte der kolloid-Gesellschaft, vol 65. Steinkopff, Heidelberg. https://doi.org/10.1007/978-3-642-93664-7_11
Download citation
DOI: https://doi.org/10.1007/978-3-642-93664-7_11
Publisher Name: Steinkopff, Heidelberg
Print ISBN: 978-3-7985-0538-4
Online ISBN: 978-3-642-93664-7
eBook Packages: Springer Book Archive