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Band-Structure Properties of One-Dimensional Polydecker Sandwich Systems

  • M. C. Böhm
Part of the Lecture Notes in Chemistry book series (LNC, volume 45)

Abstract

The one-dimensional polydecker compounds collected in fig. IV.7 are suitable model systems for a transparent investigation of the dependence of band structure porperties on the type of the central 3d atom and the stoichiometry of the organic π ligand [IV.23]. The synthesis, and the physical and chemical characterization of the first infinite 1D model in this class of low-dimensional solids has been reported recently [IV.24]. The polymer is formed by a 13 valence electron fragment of the general stoichiometry Ni(R5C3B2). The band structure and other electronic properties of this 1D system are reviewed in [IV.25].

Keywords

Dispersion Curve Organic Metal Suitable Model System General Stoichiometry Organometallic Material 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1987

Authors and Affiliations

  • M. C. Böhm
    • 1
  1. 1.Institut für Physikalische Chemie, Physikalische Chemie IIITechnische Hochschule DarmstadtDarmstadtDeutschland

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