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Part of the book series: Lecture Notes in Chemistry ((LNC,volume 40))

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Abstract

It was rationalized (Emanuel 1981) that to describe the kinetic processes involving radicals in polymer matrices one has to use an integro-differential equation which for the case of simple monomolecular reactions reads

$$- d\left[ R \right]/dt = \int_0^\infty {kR\left( k \right)dk}$$
((4.1))

where R(k) denotes the distribution of radicals according to their reactivity expressed in terms of reaction rate constant k.

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© 1986 Springer-Verlag Berlin Heidelberg

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Plonka, A. (1986). Decay of Radicals in Polymer Matrices. In: Time-Dependent Reactivity of Species in Condensed Media. Lecture Notes in Chemistry, vol 40. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-93326-4_4

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  • DOI: https://doi.org/10.1007/978-3-642-93326-4_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-16796-9

  • Online ISBN: 978-3-642-93326-4

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