Ground State Bond Diagrams

  • N. D. Epiotis
  • J. R. Larson
  • H. L. Eaton
Part of the Lecture Notes in Chemistry book series (LNC, volume 29)

Abstract

As the simplest illustrative case of our ideas, let us consider the union of two fragments C· and L· to form the two electron-two orbital system C-L. The ground state of this system, Ψ , is described by an optimal linear combination of the three CW’s as shown below:
$$\Psi aC \bullet \bullet L + {\lambda _l}[C\bar :{L^ + }] + {\lambda _2}[{C^ + }L\bar :]$$
(44)

Keywords

Manifold Ectron 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1982

Authors and Affiliations

  • N. D. Epiotis
    • 1
  • J. R. Larson
    • 2
  • H. L. Eaton
    • 1
  1. 1.Department of ChemistryUniversity of WashingtonSeattleUSA
  2. 2.Department of ChemistryUniversity of ChicagoChicagoUSA

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