Calculation of Rate Coefficients in Various Temperature Regions

Abstract

Now, we can apply the general theory developed in the preceding chapter to concrete systems, or, more specifically, to concrete models. In Chapter II we have considered a number of model systems. Among these models were those taking into account interaction with condensed medium. The Hamiltonians (2.47) and (2.61) describe models of electron transfer and energy transfer in condensed media. Since these Hamiltonians are almost isomorphous it is enough to consider the Hamiltonian (2.47) describing the electron transfer in condensed medium.