Abstract
Chemical ionization mass spectrometry(CIMS) has become an important tool in the field of analytical chemistry. CI studies are usually performed using commercial mass spectrometers which are capable of working at relatively high pressures (about 1 torr).
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Refences and Notes
A. M. Falick and T. Gäumann, Helv. Chim. Acta 59, 987 (1976)
D. Stahl and T. Gaumann, “The Mass Spectrum of 1-Heptyl Iodide”, Org. Mass Spectrom.
A. Lavanchy, R. Houriet and T. Gäumann,”The Mass Spectrometric Fragmention of n-Heptane”, submitted for publication in the J. Am. Chem. Soc.
P. Tecon, D. Stahl and T. Gäumann, “Fragmentation of 1-Heptene after Field Ionisation”, Int. J. Mass Spectrom. Ion Phys.
R. Houriet and T. Gäumann, Helv. Chim. Acta 59, 107 (1976)
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R. Houriet and T. Gaumann, “An ICR Study of the Reactions of CH5 + and C2H5 + with n-Hexane Labelled with 13C″, to be submitted for publication in the Int. J. Mass Spectrom. Ion Phys.
A. Fiaux, B. Wirz and T. Gaumann, Helv. Chim. Acta 57, 708 (1974)
S. G. Lias, R. J. Eyler and P. Ausloos, Int. J. Mass Spectrom. Ion Phys. 19, 219 (1976)
Hf’s taken from a) F. P. Lossing and G. P. Semeluk, Can J. Chem. 48, 955 (1970);
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The hydride affinity is defined as H-A(MH+)≡ΔHf(MH+)+ΔHf (H-)-ΔHf (MH2). H-A(C3H7 +) = 1104 kJ/mole and H-A((CH3)2CH+) = 1045 kJ/mole
D. Stahl and T. Gäumann, in Advances in Mass Spectrometry, ed. by N. R. Daly, Heyden, London, 1977
A. Fiaux, D. L. Smith and J. H. Futrell, J. Am. Chem. Soc. 98, 5773 (1976)
R. P. Clow and J. H. Futrell, J. Am. Chem. Soc. 94, 3748 (1972)
F. H. Field, M. S. B. Munson and D. A. Becker, Adv. Chem. Ser. No. 58, 167 (1966)
R. D. Smith and J. H. Futrell, Int. J. Mass Spectrom. Ion Phys. 20, 347 (1976)
G. Parisod and T. Gäumann, see ref. 12
A. Fiaux, B. Wirz and T. Gäumann, Helv. Chim. Acta 57, 525 (1974)
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Houriet, R., Gäumann, T. (1978). Studies in the Chemical Ionization of Hydrocarbons. In: Hartmann, H., Wanczek, KP. (eds) Ion Cyclotron Resonance Spectrometry. Lecture Notes in Chemistry, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-93085-0_8
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