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Thermodynamic Information from Ion-Molecule Equilibrium Constant Determinations

  • Chapter
Ion Cyclotron Resonance Spectrometry

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 7))

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Abstract

According to the principles of thermodynamics, the equilibrium constant of any chemical equilibrium gives information about the thermochemistry of the chemical reactions in the forward and reverse directions:

$$ - RT\ln {K_{eq}} = \Delta {G^o} = \Delta {H^o} - T\Delta {S^o}$$
(I)

Equation I has been applied extensively to the derivation of thermochemical information, particularly in the liquid phase.

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Authors and Affiliations

  1. Institute for Materials Research, National Bureau of Standards, Washington, DC, 20234, USA

    Sharon G. Lias

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  1. Sharon G. Lias
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Editors and Affiliations

  1. Akademie der Wissenschaften und der Literatur zu Mainz, Geschwister-Scholl-Straße 2, D-6500, Mainz, Germany

    Hermann Hartmann

  2. Institut für Physikalische Chemie, Universität Frankfurt, Robert-Mayer-Straße 11, D-6000, Frankfurt am Main 1, Germany

    Karl-Peter Wanczek

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Lias, S.G. (1978). Thermodynamic Information from Ion-Molecule Equilibrium Constant Determinations. In: Hartmann, H., Wanczek, KP. (eds) Ion Cyclotron Resonance Spectrometry. Lecture Notes in Chemistry, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-93085-0_4

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  • DOI: https://doi.org/10.1007/978-3-642-93085-0_4

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