Many-electron theory of π-electrons

  • Georges Henry Wagnière
Part of the Lecture Notes in Chemistry book series (LNC, volume 1)


We now explicitly consider the interaction between π-electrons [5]. Our Hamiltonian has the form
$$\kappa ^\pi = \sum\limits_\mu ^{\left( \pi \right)} {h_{Core} \left( \mu \right) + \sum\limits_{\mu > \nu }^{\left( \pi \right)} {\frac{{e^2 }}{{r_{\mu \nu } }}} } $$
and we no longer consider each π electron to merely move in the inaccurately defined average field of all the others, but rather to depend more explicitly on their relative positions.


Benzene Pyridine 


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Copyright information

© Springer-Verlag Berlin · Heidelberg 1976

Authors and Affiliations

  • Georges Henry Wagnière
    • 1
  1. 1.Physikalisch-Chemisches InstitutUniversität ZürichZürichSwitzerland

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