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Many-electron theory of π-electrons

  • Georges Henry Wagnière
Part of the Lecture Notes in Chemistry book series (LNC, volume 1)

Abstract

We now explicitly consider the interaction between π-electrons [5]. Our Hamiltonian has the form
$$\kappa ^\pi = \sum\limits_\mu ^{\left( \pi \right)} {h_{Core} \left( \mu \right) + \sum\limits_{\mu > \nu }^{\left( \pi \right)} {\frac{{e^2 }}{{r_{\mu \nu } }}} } $$
and we no longer consider each π electron to merely move in the inaccurately defined average field of all the others, but rather to depend more explicitly on their relative positions.

Keywords

Electric Dipole Slater Determinant Excited Configuration Configurational Function Secular Determinant 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin · Heidelberg 1976

Authors and Affiliations

  • Georges Henry Wagnière
    • 1
  1. 1.Physikalisch-Chemisches InstitutUniversität ZürichZürichSwitzerland

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