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Abstract

Other solvomercuration methods for the introduction of nitrogen functionality into organic substrates have been developed. One of these involves the reaction of olefins and sodium azide in the presence of mercury salts which results in azidomercuration (Table 8.1) (Eq. 1).

Keywords

Sodium Azide Sodium Borohydride Amino Sugar Alkaline Sodium Mercury Salt 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Galle, J. E., Hassner, A.: J. Am. Chem. Soc., 94 ,3930 (1972).CrossRefGoogle Scholar
  2. 2.
    Sokolov, V. I., Reutov, O. A.: Izv. Akad. Nauk SSSR, Ser. Khim., 1632 (1967); Bull. Acad. Sci. USSR, Div. Chem. Sci., 1581 (1967).Google Scholar
  3. 3.
    Heathcock, C. H.: Angew. Chem., 81 ,148 (1969)CrossRefGoogle Scholar
  4. 4.
    Traynham, J. G., Hsieh, H. H.: J. Org. Chem., 38 ,868 (1973).CrossRefGoogle Scholar
  5. 5.
    Brimacombe, J. S., Miller, J. A., Zakir, U.: Carbohydr. Res., 41 ,C3 (1975).CrossRefGoogle Scholar
  6. 6.
    Brimacombe, J. S., Miller, J. A., Zakir, U.: Carbohydr. Res., 44 ,C9 (1975).CrossRefGoogle Scholar
  7. 7.
    Brimacombe, J. S., Miller, J. A., Zakir, U.: Carbohydr. Res., 49 ,233 (1976).CrossRefGoogle Scholar
  8. 8.
    Mehta, G., Pandey, P. N.: J. Org. Chem., 40 ,3631 (1975).CrossRefGoogle Scholar
  9. 9.
    Sasaki, T., Kanematsu, K., Kondo, A.: Tetrahedron, 31 ,2215 (1975).CrossRefGoogle Scholar
  10. 10.
    Czernecki, S., Georgoulis, C., Provelenghiou, C.: Tetrahedron Lett., 4841 (1979).Google Scholar
  11. 11.
    Christol, H., Plénat, F., Revel, J.: Bull. Soc. Chim. France, 4537 (1971).Google Scholar
  12. 12.
    Kozikowski, A. P., Scripko, J.: Tetrahedron Lett., 24 ,2051 (1983).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1986

Authors and Affiliations

  • Richard C. Larock
    • 1
  1. 1.Department of ChemistryIowa State UniversityAmesUSA

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