Zusammenfassung
Die polarographische Untersuchungsmethode wird seit ihrer Einführung durch Heyrovský* im Jahre 1925 zunehmend für die Bearbeitung analytischer Probleme verwendet. Schon frühzeitig wurde sie auch zur Untersuchung von Komplexbildung in Lösung herangezogen.
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Literatur
Zusammenfassende Arbeiten über die Grundlagen der polarographischen Methode
Lingane, J. J.: Interpretation of Polarographic waves of complex metal ions. Chem. Rev. 29, 1 (1941).
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Koryta, J.: Polarographie komplexer Verbindungen. Chem. Technik 7, 464 (1955).
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Arbeiten über verschiedene spezielle Methoden
Kolthoff, I. M., and C. S. Miller: Waves involving electrooxidation of mercury at the dropping mercury electrode. J. Am. Chem. Soc. 63, 1405 (1941).
Matyska, B., u. I. Kössler: Polarographische Studie der Komplexbildung von Quecksilber mit Äthylendiamintetraessigsäure. Collection Czechoslov. Chem. Communs. 16, 221 (1951);
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Koryta, J., u. I. Kössler: Polarographische Bestimmung der Komplexbildungskonstanten der Schwermetallkomplexe der Nitrilotriessigsäure. Experientia (Basel) 6, 136 (1950);
Koryta, J., u. I. Kössler: Polarographische Bestimmung der Komplexbildungskonstanten der Schwermetallkomplexe der Nitrilotriessigsäure. Chem. Listy 44, 128 (1950).
Koryta, J., u. I. Kössler: Die polarographische Bestimmung der Stabilitätskonstanten von Komplexen, die von Schwermetallen mit Schwarzenbachs Komplexonen gebildet werden. Collection Czechoslov. Chem. Communs. 15, 241 (1950).
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Ackermann, H., u. G. Schwarzenbach: Komplexone XXII. Die Kinetik des Austausches des Y-4 zwischen Cd2+ und Cu2+. Helv. Chim. Acta 35, 485 (1952).
Methode de Ford und Hume
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Hume, D. N., D. D. de Ford and G. C. B. Cave: A polarographic study of the cadmium thiocyanate complexes. J. Am. Chem. Soc. 73, 5323 (1951).
Frank, R. E., and D. N. Hume: A Polarographie study of Zn-thiocyanate complexes. J. Am. Chem. Soc. 75, 1736 (1953).
Hershenson, H. M., M. E. Smith and D. N. Hume: A Polarographic, Potentiometric and spectrophotometric study of lead nitrate complexes. J. Am. Chem. Soc. 75, 507 (1953).
Kivalo, P., and P. Ekari: A Polarographic study of the bromo complexes of cadmium. Variation of the stability constant with ionic strength. Suomen Kemistilehti B 30, 116 (1957).
Tur’yan, Ya. I, und G. Serova: Die polarographische Bestimmung der Zusammensetzung der Nickelpyridin-Komplexe. Zhur. Fiz. Khim. 31, 2200 (1957).
Kwang-Hsien Hsu, Chio Jen and CHIN-Sui Yen: The evaluation of successive stability constants of complex ions from polarographical data. (Ermittlung der Diffusionskonstanten der einzelnen Komplexionen aus dem gemessenen Diffusionsstrom). Hua Hsüeh Hsüeh Pao 22, 447 (1956).
Cozzi, D., and F. Pantani: The Polarographic behaviour of rhodium(III) chlorocomplexes. International Symposium on the chemistry of coordination compounds. Roma 1957. „La Ricerca Scientifica“ 28, 385 (1958). (J. Inorg. Nucl. Chem.).
Rebertus, R. L., H. A. Laitinen and J. C. Bailar: A Polarographic study of the hydrazine complexes of zink. J. Am. Chem. Soc. 75, 3051 (1953).
Senise, P., and P. Delahay: A Polarographie study of thallium pyrophosphate complexes. J. Am. Chem. Soc. 74, 6128 (1952).
Methode der kleinsten Quadrate
Kivalo, P., and J. Rastas: A method for the calculation of stability constants of complexes. Suomen Kemistilehti B 30, 128 (1957).
Rastas, J., and P. Kivalo: Application of successive differences in the calculation of formation constants. Suomen Kemistilehti B 30, 143 (1957).
Indicatormethode
Ringbom, A., and L. Eriksson: The evaluation of complexity constants from Polarographie data. Acta Chem. Scand. 7, 1105 (1953).
Eriksson, L.: The complexity constants of cadmium chloride and bromide. Acta Chem. Scand. 7, 1146 (1953).
Kivalo, P., and R. Luoto: Polarographic determination of stability constants using the indicator method. Suomen Kemistilehti B 30, 163 (1957).
Unterscheidung von cis- und trans-Komplexen
Holtzclaw, H. F.: Dissertation. University of Illinois, 1947.
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Holtzclaw, H. F.: Polarographic reduction of cis- and trans-dinitrotetrammincobalt(III)-chloride in chloride, tartrate and citrate media. J. Am. Chem. Soc. 73, 1821 (1951).
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Holtzclaw, H. F.: Polarographic behaviour of isomeric inorganic coordination compounds. J. Phys. Chem. 59, 300 (1955).
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Maksimyuk, E. A., und G. S. Ginzburg: J. Gen. Chem. 26, 1763 (1956).
Hall, J. L., and R. A. Plowman: Polarography of some coordination compounds of platinum. Australian J. Chem. 9, 14 (1956).
Beispiele zur polarographischen Untersuchung über Komplexbildung in Lösung
Lingane, J. J.: Polarographic characteristic of stannous and cupric tartrate complexes and amperometric titration of tin with cupric ion in tartrate medium. J. Am. Chem. Soc. 65, 866 (1943).
Lingane, J. J.: Polarographic behaviour of chloro- and bromo-complexes of stannic tin. J. Am. Chem. Soc. 67, 919 (1945).
Lingane, J. J.: Polarographic investigation of oxalate, citrate and tartrate complexes of Fe3+ and Fe2+ ion. J. Am. Chem. Soc. 68, 2448 (1946).
Lingane, J. J., and F. Kishida: Polarographic characteristics of chlorocomplexes of +5 antimony. J. Am. Chem. Soc. 69, 530 (1947).
Lingane, J. J., and L. Meites: Polarographic characteristics of vanadium in oxalate solutions. J. Am. Chem. Soc. 69, 1021 (1947).
Lingane, J. J., and R. L. Pecsock: Quantitative interpretation of the Polarographic hydrolysis current of chromic ion. J. Am. Chem. Soc. 71, 425 (1949).
Pecsock, R. L., and J. J. Lingane: Polarography of chromium(II). J. Am. Chem. Soc. 72, 189 (1950).
Hume, D. N., and I. M. Kolthoff: The oxidation potential of the chromocyanide — chromi cyanide couple and the polarography of the chromium-cyanide complexes. J. Am. Chem. Soc. 65, 1897 (1943).
Hume, D. N., and I. M. Kolthoff: A Polarographic study of cobalt cyanide complexes. J. Am. Chem. Soc. 71, 867 (1949).
Hume, D. N., and I. M. Kolthoff: The polarography of the nickel cyanide complex and the solubility and constitution of nickel cyanide. J. Am. Chem. Soc. 72, 4423 (1950).
Laitinen, M. A., J. C. Bailar, H. F. Holtzclaw and J. V. Quagliano: Polarographic investigation of hexamminecobalt(III)-chloride in various supporting electrolytes. J. Am. Chem. Soc. 70, 2999 (1948). (Bildung von Überkomplexen).
Laitinen, H. A., E. I. Onstott, J. C. Bailar and S. Swann: Polarographic studies of Cu-complexes. I. Ethylenediamine, diethylenediamine, propylene-diamine, glycine-compounds. J. Am. Chem. Soc. 71, 1550 (1949).
Laitinen, H. A., and E. I. Onstott: III. Pyrophosphate complexes. J. Am. Chem. Soc. 72, 4729 (1950).
Onstott, E. I., and H. A. Laitinen: II. Dipyridyl, orthophenanthroline and thiourea complexes. A double complex system. J. Am. Chem. Soc. 72, 4724 (1950).
Douglas, B. E., H.A. Laitinen and J. C. Bailar: Polarography of some cadmium complexes. J. Am. Chem. Soc. 72, 2484 (1950).
Laitinen, H. A., and E. I. Onstott: Adsorption and reduction of tetrachloroplatinate(II)-ion at the dropping mercury electrode. J. Am. Chem. Soc. 72, 4565 (1950).
Onstott, E. I.: Polarography of ethylenediamine tetraacetate complexes of europium. J. Am. Chem. Soc. 74, 3773 (1952).
Laitinen, H. A., and P. Kivalo: Polarographic reduction of Co(NH3)3+ 6. II. The effect of complexing agents. J. Am. Chem. Soc. 75, 2198 (1953).
Laitinen, H. A., A. J. Frank and P. Kivalo: III. The effect of non-complexing agents. J. Am. Chem. Soc. 75, 2865 (1953).
Schaap, W. B., H. A. Laitinen and J. C. Bailar: Polarography of iron oxalates, malonates and succinates. J. Am. Chem. Soc. 76, 5868 (1954).
Laitinen, H. A., and M. W. Grieb: Polarographic study of the tris-ethylene-diamine-Co(III)-ion. J. Am. Chem. Soc. 77, 5201 (1955).
Meites, L.: Polarographic studies of metal complexes. I. The copper(II)-tartrates. J. Am. Chem. Soc. 71, 3269 (1949).
Meites, L.: II. Copper(II)-citrates. J. Am. Chem. Soc. 72, 180 (1950).
Meites, L.: III. Copper(II)-oxalates and carbonates. J. Am. Chem. Soc. 72, 184 (1950).
Meites, T., and L. Meites: IV. The lead (II)-tartrates and oxalates. J. Am. Chem. Soc. 73, 1161 (1951).
Meites, L.: V. The cadmium(II)-zinc(II)-, and iron(III)-citrates. J. Am. Chem. Soc. 73, 3727 (1951).
Pecsock, R. L., and E. F. Maverick: A polarographic study of the titanium ethylenediamine-tetraacetate complexes. J. Am. Chem. Soc. 76, 358 (1954).
Pecsock, R. L., and R. S. Juret: Polarographic characteristics of vanadium complexes with ethylenediaminetetraacetic acid. J. Am. Chem. Soc. 75, 1202 (1953).
Pecsock, R. L.: A Polarographic study of the oxalato complexes of titanium. J. Am. Chem. Soc. 73, 1304 (1951).
Li, N. C., and E. Doody: Polarographic, potentiometric and conductometric studies of the aspartate and alaninate complexes of copper. J. Am. Chem. Soc. 72, 1891 (1950).
Li, N. C., and E. Doody: Metal amino acid complexes. III. Polarographic and potentiometric studies on complex formation between copper(II) and amino acidion. J. Am. Chem. Soc. 74, 4148 (1952).
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Keefer, R. M.: Polarographic determination of cupric glycinate and cupric alaninate complex ions. J. Am. Chem. Soc. 68, 2329 (1946).
Kern, D. M.: A Polarographic study of the perborate complex. J. Am. Chem. Soc. 77, 5458 (1955).
Hamm, R. E., and C. M. Shuler: Polarographic study of chromium(III)-chlorid solutions. J. Am. Chem. Soc. 73, 1240 (1951).
Hamm, R. E., and R. E. Davis: Complex ions of chromium(III): Reactions between hexaquo-chromium ion and oxalate ion. J. Am. Chem. Soc. 75, 3085 (1953).
Page, J. A., and G. Wilkinson: The Polarographic chemistry of ferrocene and ruthenocene and metal hydrocarbon ions. J. Am. Chem. Soc. 74, 6149 (1952).
Neumann, W. F., J. R. Havill and I. Feldmann: The uranyl-citrate system. II. Polarographic studies on the 1:1 complex. J. Am. Chem. Soc. 73, 3593 (1951).
Banks, Ch. V., and J. H. Patterson: A polarographic investigation of iron-sulfosalicylate complex ions. J. Am. Chem. Soc. 73, 3062 (1951).
Schufle, J. A., M. F. Stabbs and R. E. Witman: A study of indium(III)-complexes by polarographic methods. J. Am. Chem. Soc. 73, 1013 (1951).
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Flannery, R. J., B. Ke, M. W. Grieb and D. Trivick: Polarographic study of Cu(II)-complexes with ethanoleamine and some derivates. J. Am. Chem. Soc. 77, 2996 (1955).
Kivalo, P.: Polarography of Coen3+ 3-ion in the absence of excess of complexing agent. J. Am. Chem. Soc. 77, 2678 (1955).
Rulfs, Ch. L., and G. A. Stoner: The Polarographie reduction of ferric ion in fluoride media. J. Am. Chem. Soc. 77, 2653 (1955).
Nyman, C. J., D. H. Roe and D. B. Masson: Polarographic investigation of the ethylenediamine, 1,2-propanediamine and diethylenetriamine complexes of Hg(I). J. Am. Chem. Soc. 77, 4191 (1955).
Nyman, C. J., E. W. Murbach and G. B. Millard: A potentiometric, pH and Polarographic study of the complex ions of Zn(II) and ethylenediamine. J. Am. Chem. Soc. 77, 4194 (1955).
Wassiljew, A. M., und W. J. Prouchina: Polarographische Untersuchung der Stabilität von Chlorid- und Bromidkomplexen des Cadmiums und Bleis. J. analyt. Chem. U.S.S.R. 6, 218(1951).
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Schläfer, H.L. (1961). Polarographische Methoden. In: Komplexbildung in Lösung. Molekülverbindungen und Koordinationsverbindungen in Einzeldarstellungen. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87213-6_6
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DOI: https://doi.org/10.1007/978-3-642-87213-6_6
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