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Verwendung von Ionenaustauschern für die Untersuchung von Komplexgleichgewichten in Lösung

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Komplexbildung in Lösung

Zusammenfassung

Ionenaustauscher können bei der Untersuchung von Gleichgewichten in Lösung oftmals in Fällen angewendet werden, in denen spektrophotometrische oder potentiometrische Methoden versagen.

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Literatur

  1. Schubert, J., E. R. Rüssel and L. S. Myers: Dissociation constants of radium-organic acid complexes measured by ion exchange. J. Biol. Chem. 185, 387 (1950).

    CAS  Google Scholar 

  2. Schubert, J.: Ion exchange studies of complex ions as a function of temperature, ionic strength and presence of formaldehyde. J. Phys. Chem. 56, 113 (1952).

    Article  CAS  Google Scholar 

  3. Schubert, J., and A. Lindenbaum: Stability of alkaline earth-organic acid complexes measured by ion exchange. J. Am. Chem. Soc. 74, 3529 (1952).

    Article  CAS  Google Scholar 

  4. Schubert, J., and J. W. Richter: Cation exchange studies on the barium citrate complex and related equilibria. J. Am. Chem. Soc. 70, 4259 (1948).

    Article  CAS  Google Scholar 

  5. Schubert, J., and A. Lindenbaum: Complexes of calcium with citric acid and tricarballylic acid measured by ion exchange. Nature (London) 166, 913 (1950).

    Article  CAS  Google Scholar 

  6. Schubert, J.: Analytical applications of ion exchange separations. Anal. Chem. 22, 1359 (1950).

    Article  CAS  Google Scholar 

  7. Schubert, J.: Complexes of alkaline earth cations including radium with amino acids and related compounds. J. Am. Chem. Soc. 76, 3442 (1954).

    Article  CAS  Google Scholar 

  8. Schubert, J.: The use of ion exchangers for the determination of physical-chemical properties of substances, particularly radiotracers, in solution. I. Theoretical. J. Phys. Colloid Chem. 52, 340 (1948).

    Article  CAS  Google Scholar 

  9. Vgl. auch Schubert, J.: Ann. Rev. Phys. Chem. 5, 413 (1954). Measurement of complex ion stability by the use of ion exchange resins in D. Glick, Methods of biochemical analysis Vol. III, 247. New York: Interscience Publ. Inc. 1956.

    Article  CAS  Google Scholar 

  10. Schubert, J., and J. W. Richter: II. The dissociation constant of strontium citrate and strontium tartrate. J. Phys. Colloid Chem. 52, 350 (1948).

    Article  CAS  Google Scholar 

  11. Schubert, J., and J. W. Richter: III. The radiocolloids of zirconium and niobium. J. Colloid Sci. 5, 376 (1950).

    Article  CAS  Google Scholar 

  12. Schubert, J., E. L. Lind, W. M. Westfall, P. Pfleger and N. C. Li: Ion exchange and solvent-extraction studies on Co(II) and Zn(II) complexes of some organic acids. J. Am. Chem. Soc. 80, 4799 (1958). (Verwendung von Co60 und Zn65.)

    Article  CAS  Google Scholar 

  13. Li, N. C., W. M. Westfall, A. Lindenbaum, J. M. White and J. Schubert: Manganese-54, uranium-233 and cobalt-60 complexes of some organic acids. J. Am. Chem. Soc. 79, 5864 (1957).

    Article  CAS  Google Scholar 

  14. Ward, M., and G. A. Welch: The chloride complexes of trivalent plutonium, americum and curium. J. Inorg. Nuclear Chem. 2, 395 (1956). (Modifikation der Methode von Schubert für positiv geladene Komplexionen.)

    Article  CAS  Google Scholar 

  15. Feldmann, I., T. Y. Toribara, J. R. Havill and W. F. Neuman: The beryllium-citrate system. II. Ion exchange studies. J. Am. Chem. Soc. 77, 878 (1955).

    Article  Google Scholar 

  16. Mayer, S. W., and S. D. Schwartz: The association of cerous ion with iodide, bromide and fluoride ions. J. Am. Chem. Soc. 73, 222 (1951).

    Article  CAS  Google Scholar 

  17. Mayer, S. W., and S. D. Schwartz: The association of cerous ion with sulfite, phosphate and pyrophosphate. J. Am. Chem. Soc. 72, 5106 (1950).

    Article  CAS  Google Scholar 

  18. Connick, R. E., and S.W. Mayer: Ion exchange measurements of activity coefficients and association constants of cerous salts in mixed electrolytes. J. Am. Chem. Soc. 73, 1176 (1951).

    Article  CAS  Google Scholar 

  19. Fronaeus, S.: The use of cation exchangers for the quantitative investigation of complex systems. Acta Chem. Scand. 5, 859 (1951).

    Article  Google Scholar 

  20. Fronaeus, S.: The use of ion exchangers for the investigation of complex equilibria. Proceedings of the Symposium on Co-ordination Chemistry. S. 61. Copenhagen 1953.

    Google Scholar 

  21. Fronaeus, S.: The equilibrium between nickel and acetate ions. An ion exchange and potentiometric investigation. Acta Chem. Scand. 6, 1200 (1952).

    Article  CAS  Google Scholar 

  22. Fronaeus, S.: An ion exchange and extinctometric investigation of the nickel-thiocyanate system. Acta Chem. Scand. 7, 21 (1953).

    Article  CAS  Google Scholar 

  23. Fronaeus, S.: On the application of the mass action law to cation exchange equilibrium. Acta Chem. Scand. 7, 469 (1953).

    Article  CAS  Google Scholar 

  24. Fronaeus, S.: An ion exchange study of the cerous sulfate system. Svensk. Kern. Tidskr. 64, 317 (1952).

    CAS  Google Scholar 

  25. Fronaeus, S.: The investigation of complex systems of the type M3+-A- by cation exchange. The cerous acetate system. Svensk. Kem. Tidskr. 65, 19 (1953).

    CAS  Google Scholar 

  26. Schufle, J. A., and H. M. Eiland: Indium halide complexes studied by ion-exchange methods. J. Am. Chem. Soc. 76, 960 (1954).

    Article  CAS  Google Scholar 

  27. Salmon, J. E.: Complexes involving tervalent iron and orthophosphoric acid. II. Ion exchange studies of solutions containing phosphate and chloride. J. Chem. Soc. (London) 1953, 2644.

    Google Scholar 

  28. Jameson, R. F., and J. E. Salmon: Chromium phosphates: Phase diagramm and preliminary ion exchange studies of the system chromic oxide-phosphoric oxide-water at 0° and 40°. J. Chem. Soc. (London) 1955, 360.

    Google Scholar 

  29. Lister, B. A., and L. A. McDonnald: Some aspects of the solution chemistry of zirconium. J. Chem. Soc. (London) 1952, 4315.

    Google Scholar 

  30. Cunningham, S. G., and G. T. Seaborg: Chemical properties of berkelium. J. Am. Chem. Soc. 72, 2790 (1950).

    Article  Google Scholar 

  31. Wish, L., E. C. Freiling and L. R. Bunney: Ion exchange as a separation method. VIII. Relative elution positions of lanthanide and actinide elements with lactic acid as eluant at 87°. J. Am. Chem. Soc. 76, 3444 (1954).

    Article  CAS  Google Scholar 

  32. Diamond, R. M., K. Street and G. T. Seaborg: An ion exchange study of possible hybridized 5f bonding in the actinides. J. Am. Chem. Soc. 76, 1461 (1954).

    Article  CAS  Google Scholar 

  33. Genge, J. A. R., A. Holroyd, J. Salmon and J. G. L. Wall: Phosphoric acid as complexing eluant in ion exchange chromatography. Chemistry & Industry 357 (1955).

    Google Scholar 

  34. Holroyd, A., and J. E. Salmon: Ion exchange studies of phosphates. I. Ion exchange sorption and pH-titration methods for determination of complex formation. J. Chem. Soc. (London) 1956, 269.

    Google Scholar 

  35. Salmon, J. E.: Complexes involving tervalent iron and orthophosphoric acid. II. Ion exchange studies of solutions containing phosphate and chloride. J. Chem. Soc. (London) 1953, 2644.

    Google Scholar 

  36. Jameson, R. F., and J. E. Salmon: Aluminium phosphates: Phase diagram and ion exchange studies of the system aluminium oxide — phosphoric oxide — water at 25°. J. Chem. Soc. (London) 1954, 4013.

    Google Scholar 

  37. Jameson, R. F., and J. E. Salmon: Chromium phosphates: Phase diagram and preliminary ion exchange studies of the system chromic oxide- phosphoric oxide — water at 0° and 40°. J. Chem. Soc. (London) 1955, 360.

    Google Scholar 

  38. Jameson, R. F., and J. E. Salmon: Complexes involving tervalent iron and orthophosphoric acid. III. The system ferric oxide — phosphoric oxide — water at 25°. J. Chem. Soc. (London) 1954, 28.

    Google Scholar 

  39. Lister, B. A., and L. A. McDonnald: Some aspects of the solution chemistry of zirconium. J. Chem. Soc. (London) 1952, 4315.

    Google Scholar 

  40. Everest, D. A.: Studies in the chemistry of quadrivalent germanium. III. Ion exchange studies of solutions containing germanium and oxalate. J. Chem. Soc. (London) 1955, 4415.

    Google Scholar 

  41. Kraus, K. A., and G. E. Moore: Anion exchange studies. I. Separation of zirconium and niobium in HC1-HF mixtures. J. Am. Chem. Soc. 73, 9 (1951).

    Article  CAS  Google Scholar 

  42. Kraus, K. A., and G. E. Moore: II. Tantalum in some HF-HC1 mixtures. J. Am. Chem. Soc. 73, 13 (1951).

    Article  CAS  Google Scholar 

  43. Kraus, K. A., and G. E. Moore: III. Protactinium in some HC1-HF mixtures. Separation of niobium, tantalum and protactinium. J. Am. Chem. Soc. 73, 2900 (1951).

    Article  CAS  Google Scholar 

  44. Moore, G. E., and K. A. Kraus: IV. Cobalt and nickel in hydrochloric acid solutions. J. Am. Chem. Soc. 74, 843 (1952).

    Article  CAS  Google Scholar 

  45. Kraus, K. A., and F. Nelson: VIII. Separation of iron and aluminium in sulfate solutions. J. Am. Chem. Soc. 75, 3273 (1953).

    Article  CAS  Google Scholar 

  46. Kraus, K. A., and F. Nelson: X. Ion exchange in concentrated electrolytes. Gold(III) in hydrochloric acid solutions. J. Am. Chem. Soc. 76, 984 (1954).

    Article  CAS  Google Scholar 

  47. Nelson, F., and K. A. Kraus: XIII. The alkaline earths in citrate solutions. J. Am. Chem. Soc. 77, 801 (1955).

    Article  CAS  Google Scholar 

  48. Kraus, K. A., F. Nelson and G. E. Moore: XVII. Molybdenum(IV), tungsten(IV) in HCl and HC1-HF solutions. J. Am. Chem. Soc. 77, 3972 (1955).

    Article  CAS  Google Scholar 

  49. Nelson, F., and K. A. Kraus: XVIII. Germanium and arsenic in HCl-solutions. J. Am. Chem. Soc. 77, 4508 (1955).

    Article  CAS  Google Scholar 

  50. Kraus, K. A., F. Nelson and G. W. Smith: IX. Adsorbability of a number of metals in hydrochloric acid solutions. J. Phys. Chem. 58, 11 (1954).

    Article  CAS  Google Scholar 

  51. Kraus, K. A., and G. E. Moore: Separation of columbium and tantalum with anion exchange resins. J. Am. Chem. Soc. 71, 3855 (1949).

    Article  CAS  Google Scholar 

  52. Kraus, K. A., and G. E. Moore: Adsorption of protactinium from hydrochloric acid solutions by anion exchange resins. J. Am. Chem. Soc. 72, 4293 (1950).

    Article  CAS  Google Scholar 

  53. Moore, G. E., and K. A. Kraus: Adsorption of iron by anion exchange resins from hydrochloric acid solutions. J. Am. Chem. Soc. 72, 5792 (1950).

    Article  CAS  Google Scholar 

  54. Huffmann, E. H., and R. C. Lilly: Anion exchange of complex ions of hafnium and zirconium in HC1-HF mixtures. J. Am. Chem. Soc. 73, 2902 (1951).

    Article  Google Scholar 

  55. Herber, R. H., and J. W. Irvine: Anion exchange studies. I. Bromide complexes of Co(II), Zn(II) and Ga(III). J. Am. Chem. Soc. 76, 987 (1954).

    Article  CAS  Google Scholar 

  56. Marcus, Y.: The anion exchange of metal complexes. The silver thiosulphate system. Acta Chem. Scand. 11, 619 (1957).

    Article  CAS  Google Scholar 

  57. Fronaeus, S.: On the use of anion exchangers for the investigation of complex systems. Svensk Kem. Tidskr. 65, 1 (1953).

    Google Scholar 

  58. Fronaeus, S.: An ion exchange study of the formation of anionic complexes in the cupric and cadmium sulfate systems. Acta Chem. Scand. 8, 1174 (1954).

    Article  CAS  Google Scholar 

Weitere Literatur über die Verwendung von Ionenaustauschern zur Untersuchung von Komplexbildung in Lösung

  • Salmon, J. E.: Some applications of ion exchange in the study of inorganic complexes. Revs. Pure and Appl. Chem. (Australia) 6, 24 (1956). (Zusammenfassende Übersicht mit vielen Literaturhinweisen.)

    CAS  Google Scholar 

  • Fomin, V. V.: Bestimmung der Zusammensetzung und der Stabilitätskonstanten von Komplexionen mit Hilfe von Kationenaustauschern. Uspekhi Khim. 24, 1010 (1955).

    CAS  Google Scholar 

  • Fomin, V. V., u. V. V. Sinkovskiῐ: Die Untersuchung von komplexen Cobaltoxalaten mit Hilfe von Anionenaustauschern. Zhur. Neorg. Khim. 1, 2316 (1956).

    CAS  Google Scholar 

  • Everest, D. A.: Chemistry of quadrivalent germanium. III. Ion exchange studies of solutions containing germanium and oxalate. J. Chem. Soc. (London) 1955, 4415.

    Google Scholar 

  • Whiteker, R. A., and N. Davidson: Ion-exchange and spectrophotometric investigation of Fe(III)-sulfate complex ion. J. Am. Chem. Soc. 75, 3081 (1953).

    Article  CAS  Google Scholar 

  • Foreman, J. K., and T. D. Smith: The nature and stability of complex ions formed by tri-, quadri- and sexivalent plutonium ions with ethylenediaminetetraacetic acid. I. pH-titrations and ion exchange studies. J. Chem. Soc. (London) 1957, 1752.

    Google Scholar 

  • Feldmann, L, and J. R. Havill: Some ion exchange studies of the polymerisation of beryllium. J. Am. Chem. Soc. 74, 2337 (1952).

    Article  Google Scholar 

  • Holroyd, A., and J. E. Salmon: Complexes involving tervalent iron and orthophosphoric acid. IV. Evidence for the formation of polynuclear complexes from ion exchange experiments. J. Chem. Soc. (London) 1957, 959.

    Google Scholar 

  • Fuger, J.: Ion exchange behaviour and dissociation constants of americium, curium and californium complexes with ethylenediaminetetra-acetic acid. J. Inorg. Nuclear Chem. 5, 332 (1958).

    Article  CAS  Google Scholar 

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Schläfer, H.L. (1961). Verwendung von Ionenaustauschern für die Untersuchung von Komplexgleichgewichten in Lösung. In: Komplexbildung in Lösung. Molekülverbindungen und Koordinationsverbindungen in Einzeldarstellungen. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87213-6_10

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  • DOI: https://doi.org/10.1007/978-3-642-87213-6_10

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