Zusammenfassung
Ionenaustauscher können bei der Untersuchung von Gleichgewichten in Lösung oftmals in Fällen angewendet werden, in denen spektrophotometrische oder potentiometrische Methoden versagen.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Literatur
Schubert, J., E. R. Rüssel and L. S. Myers: Dissociation constants of radium-organic acid complexes measured by ion exchange. J. Biol. Chem. 185, 387 (1950).
Schubert, J.: Ion exchange studies of complex ions as a function of temperature, ionic strength and presence of formaldehyde. J. Phys. Chem. 56, 113 (1952).
Schubert, J., and A. Lindenbaum: Stability of alkaline earth-organic acid complexes measured by ion exchange. J. Am. Chem. Soc. 74, 3529 (1952).
Schubert, J., and J. W. Richter: Cation exchange studies on the barium citrate complex and related equilibria. J. Am. Chem. Soc. 70, 4259 (1948).
Schubert, J., and A. Lindenbaum: Complexes of calcium with citric acid and tricarballylic acid measured by ion exchange. Nature (London) 166, 913 (1950).
Schubert, J.: Analytical applications of ion exchange separations. Anal. Chem. 22, 1359 (1950).
Schubert, J.: Complexes of alkaline earth cations including radium with amino acids and related compounds. J. Am. Chem. Soc. 76, 3442 (1954).
Schubert, J.: The use of ion exchangers for the determination of physical-chemical properties of substances, particularly radiotracers, in solution. I. Theoretical. J. Phys. Colloid Chem. 52, 340 (1948).
Vgl. auch Schubert, J.: Ann. Rev. Phys. Chem. 5, 413 (1954). Measurement of complex ion stability by the use of ion exchange resins in D. Glick, Methods of biochemical analysis Vol. III, 247. New York: Interscience Publ. Inc. 1956.
Schubert, J., and J. W. Richter: II. The dissociation constant of strontium citrate and strontium tartrate. J. Phys. Colloid Chem. 52, 350 (1948).
Schubert, J., and J. W. Richter: III. The radiocolloids of zirconium and niobium. J. Colloid Sci. 5, 376 (1950).
Schubert, J., E. L. Lind, W. M. Westfall, P. Pfleger and N. C. Li: Ion exchange and solvent-extraction studies on Co(II) and Zn(II) complexes of some organic acids. J. Am. Chem. Soc. 80, 4799 (1958). (Verwendung von Co60 und Zn65.)
Li, N. C., W. M. Westfall, A. Lindenbaum, J. M. White and J. Schubert: Manganese-54, uranium-233 and cobalt-60 complexes of some organic acids. J. Am. Chem. Soc. 79, 5864 (1957).
Ward, M., and G. A. Welch: The chloride complexes of trivalent plutonium, americum and curium. J. Inorg. Nuclear Chem. 2, 395 (1956). (Modifikation der Methode von Schubert für positiv geladene Komplexionen.)
Feldmann, I., T. Y. Toribara, J. R. Havill and W. F. Neuman: The beryllium-citrate system. II. Ion exchange studies. J. Am. Chem. Soc. 77, 878 (1955).
Mayer, S. W., and S. D. Schwartz: The association of cerous ion with iodide, bromide and fluoride ions. J. Am. Chem. Soc. 73, 222 (1951).
Mayer, S. W., and S. D. Schwartz: The association of cerous ion with sulfite, phosphate and pyrophosphate. J. Am. Chem. Soc. 72, 5106 (1950).
Connick, R. E., and S.W. Mayer: Ion exchange measurements of activity coefficients and association constants of cerous salts in mixed electrolytes. J. Am. Chem. Soc. 73, 1176 (1951).
Fronaeus, S.: The use of cation exchangers for the quantitative investigation of complex systems. Acta Chem. Scand. 5, 859 (1951).
Fronaeus, S.: The use of ion exchangers for the investigation of complex equilibria. Proceedings of the Symposium on Co-ordination Chemistry. S. 61. Copenhagen 1953.
Fronaeus, S.: The equilibrium between nickel and acetate ions. An ion exchange and potentiometric investigation. Acta Chem. Scand. 6, 1200 (1952).
Fronaeus, S.: An ion exchange and extinctometric investigation of the nickel-thiocyanate system. Acta Chem. Scand. 7, 21 (1953).
Fronaeus, S.: On the application of the mass action law to cation exchange equilibrium. Acta Chem. Scand. 7, 469 (1953).
Fronaeus, S.: An ion exchange study of the cerous sulfate system. Svensk. Kern. Tidskr. 64, 317 (1952).
Fronaeus, S.: The investigation of complex systems of the type M3+-A- by cation exchange. The cerous acetate system. Svensk. Kem. Tidskr. 65, 19 (1953).
Schufle, J. A., and H. M. Eiland: Indium halide complexes studied by ion-exchange methods. J. Am. Chem. Soc. 76, 960 (1954).
Salmon, J. E.: Complexes involving tervalent iron and orthophosphoric acid. II. Ion exchange studies of solutions containing phosphate and chloride. J. Chem. Soc. (London) 1953, 2644.
Jameson, R. F., and J. E. Salmon: Chromium phosphates: Phase diagramm and preliminary ion exchange studies of the system chromic oxide-phosphoric oxide-water at 0° and 40°. J. Chem. Soc. (London) 1955, 360.
Lister, B. A., and L. A. McDonnald: Some aspects of the solution chemistry of zirconium. J. Chem. Soc. (London) 1952, 4315.
Cunningham, S. G., and G. T. Seaborg: Chemical properties of berkelium. J. Am. Chem. Soc. 72, 2790 (1950).
Wish, L., E. C. Freiling and L. R. Bunney: Ion exchange as a separation method. VIII. Relative elution positions of lanthanide and actinide elements with lactic acid as eluant at 87°. J. Am. Chem. Soc. 76, 3444 (1954).
Diamond, R. M., K. Street and G. T. Seaborg: An ion exchange study of possible hybridized 5f bonding in the actinides. J. Am. Chem. Soc. 76, 1461 (1954).
Genge, J. A. R., A. Holroyd, J. Salmon and J. G. L. Wall: Phosphoric acid as complexing eluant in ion exchange chromatography. Chemistry & Industry 357 (1955).
Holroyd, A., and J. E. Salmon: Ion exchange studies of phosphates. I. Ion exchange sorption and pH-titration methods for determination of complex formation. J. Chem. Soc. (London) 1956, 269.
Salmon, J. E.: Complexes involving tervalent iron and orthophosphoric acid. II. Ion exchange studies of solutions containing phosphate and chloride. J. Chem. Soc. (London) 1953, 2644.
Jameson, R. F., and J. E. Salmon: Aluminium phosphates: Phase diagram and ion exchange studies of the system aluminium oxide — phosphoric oxide — water at 25°. J. Chem. Soc. (London) 1954, 4013.
Jameson, R. F., and J. E. Salmon: Chromium phosphates: Phase diagram and preliminary ion exchange studies of the system chromic oxide- phosphoric oxide — water at 0° and 40°. J. Chem. Soc. (London) 1955, 360.
Jameson, R. F., and J. E. Salmon: Complexes involving tervalent iron and orthophosphoric acid. III. The system ferric oxide — phosphoric oxide — water at 25°. J. Chem. Soc. (London) 1954, 28.
Lister, B. A., and L. A. McDonnald: Some aspects of the solution chemistry of zirconium. J. Chem. Soc. (London) 1952, 4315.
Everest, D. A.: Studies in the chemistry of quadrivalent germanium. III. Ion exchange studies of solutions containing germanium and oxalate. J. Chem. Soc. (London) 1955, 4415.
Kraus, K. A., and G. E. Moore: Anion exchange studies. I. Separation of zirconium and niobium in HC1-HF mixtures. J. Am. Chem. Soc. 73, 9 (1951).
Kraus, K. A., and G. E. Moore: II. Tantalum in some HF-HC1 mixtures. J. Am. Chem. Soc. 73, 13 (1951).
Kraus, K. A., and G. E. Moore: III. Protactinium in some HC1-HF mixtures. Separation of niobium, tantalum and protactinium. J. Am. Chem. Soc. 73, 2900 (1951).
Moore, G. E., and K. A. Kraus: IV. Cobalt and nickel in hydrochloric acid solutions. J. Am. Chem. Soc. 74, 843 (1952).
Kraus, K. A., and F. Nelson: VIII. Separation of iron and aluminium in sulfate solutions. J. Am. Chem. Soc. 75, 3273 (1953).
Kraus, K. A., and F. Nelson: X. Ion exchange in concentrated electrolytes. Gold(III) in hydrochloric acid solutions. J. Am. Chem. Soc. 76, 984 (1954).
Nelson, F., and K. A. Kraus: XIII. The alkaline earths in citrate solutions. J. Am. Chem. Soc. 77, 801 (1955).
Kraus, K. A., F. Nelson and G. E. Moore: XVII. Molybdenum(IV), tungsten(IV) in HCl and HC1-HF solutions. J. Am. Chem. Soc. 77, 3972 (1955).
Nelson, F., and K. A. Kraus: XVIII. Germanium and arsenic in HCl-solutions. J. Am. Chem. Soc. 77, 4508 (1955).
Kraus, K. A., F. Nelson and G. W. Smith: IX. Adsorbability of a number of metals in hydrochloric acid solutions. J. Phys. Chem. 58, 11 (1954).
Kraus, K. A., and G. E. Moore: Separation of columbium and tantalum with anion exchange resins. J. Am. Chem. Soc. 71, 3855 (1949).
Kraus, K. A., and G. E. Moore: Adsorption of protactinium from hydrochloric acid solutions by anion exchange resins. J. Am. Chem. Soc. 72, 4293 (1950).
Moore, G. E., and K. A. Kraus: Adsorption of iron by anion exchange resins from hydrochloric acid solutions. J. Am. Chem. Soc. 72, 5792 (1950).
Huffmann, E. H., and R. C. Lilly: Anion exchange of complex ions of hafnium and zirconium in HC1-HF mixtures. J. Am. Chem. Soc. 73, 2902 (1951).
Herber, R. H., and J. W. Irvine: Anion exchange studies. I. Bromide complexes of Co(II), Zn(II) and Ga(III). J. Am. Chem. Soc. 76, 987 (1954).
Marcus, Y.: The anion exchange of metal complexes. The silver thiosulphate system. Acta Chem. Scand. 11, 619 (1957).
Fronaeus, S.: On the use of anion exchangers for the investigation of complex systems. Svensk Kem. Tidskr. 65, 1 (1953).
Fronaeus, S.: An ion exchange study of the formation of anionic complexes in the cupric and cadmium sulfate systems. Acta Chem. Scand. 8, 1174 (1954).
Weitere Literatur über die Verwendung von Ionenaustauschern zur Untersuchung von Komplexbildung in Lösung
Salmon, J. E.: Some applications of ion exchange in the study of inorganic complexes. Revs. Pure and Appl. Chem. (Australia) 6, 24 (1956). (Zusammenfassende Übersicht mit vielen Literaturhinweisen.)
Fomin, V. V.: Bestimmung der Zusammensetzung und der Stabilitätskonstanten von Komplexionen mit Hilfe von Kationenaustauschern. Uspekhi Khim. 24, 1010 (1955).
Fomin, V. V., u. V. V. Sinkovskiῐ: Die Untersuchung von komplexen Cobaltoxalaten mit Hilfe von Anionenaustauschern. Zhur. Neorg. Khim. 1, 2316 (1956).
Everest, D. A.: Chemistry of quadrivalent germanium. III. Ion exchange studies of solutions containing germanium and oxalate. J. Chem. Soc. (London) 1955, 4415.
Whiteker, R. A., and N. Davidson: Ion-exchange and spectrophotometric investigation of Fe(III)-sulfate complex ion. J. Am. Chem. Soc. 75, 3081 (1953).
Foreman, J. K., and T. D. Smith: The nature and stability of complex ions formed by tri-, quadri- and sexivalent plutonium ions with ethylenediaminetetraacetic acid. I. pH-titrations and ion exchange studies. J. Chem. Soc. (London) 1957, 1752.
Feldmann, L, and J. R. Havill: Some ion exchange studies of the polymerisation of beryllium. J. Am. Chem. Soc. 74, 2337 (1952).
Holroyd, A., and J. E. Salmon: Complexes involving tervalent iron and orthophosphoric acid. IV. Evidence for the formation of polynuclear complexes from ion exchange experiments. J. Chem. Soc. (London) 1957, 959.
Fuger, J.: Ion exchange behaviour and dissociation constants of americium, curium and californium complexes with ethylenediaminetetra-acetic acid. J. Inorg. Nuclear Chem. 5, 332 (1958).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1961 Springer-Verlag oHG. Berlin · Göttingen · Heidelberg
About this chapter
Cite this chapter
Schläfer, H.L. (1961). Verwendung von Ionenaustauschern für die Untersuchung von Komplexgleichgewichten in Lösung. In: Komplexbildung in Lösung. Molekülverbindungen und Koordinationsverbindungen in Einzeldarstellungen. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87213-6_10
Download citation
DOI: https://doi.org/10.1007/978-3-642-87213-6_10
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-87214-3
Online ISBN: 978-3-642-87213-6
eBook Packages: Springer Book Archive