Changes in Secondary Ion and Metastable Ion Mass Spectral Patterns with Experimental Conditions

  • Hideki Kambara
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 25)

Abstract

Molecular secondary ion mass spectrometry(SIMS) has been proven to be a powerful analytical method for investigating molecular weights of thermolabile nonvolatile bio-organic compounds[1–10]. Secondary ion mass (SIM) spectra show a lot of fragment peaks which provide important information on molecular structure. One of the favourable characteristics of SIMS is that spectral patterns are quite reproducible in most cases. This enables precise discussion on molecular structure using SIM spectra, such as differenciation of isomers, etc. Although SIM spectral patterns are reproducible under the same experimental conditions, they sometimes change with conditions.

Keywords

Glycerol Saccharide Lithium Adduct Dition 

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References

  1. 1.
    A. Benninghoven, D. Jaspers, W. Sichtermann: Appl. Phys. 11, 35 (1976).CrossRefGoogle Scholar
  2. 2.
    A. Benninghoven, W.K. Sichtermann: Anal. Chem. 50, 1180 (1978).CrossRefGoogle Scholar
  3. 3.
    H. Grade, R.G. Cooks: J.Am.Chem.Soc. 100, 5615 (1978).CrossRefGoogle Scholar
  4. 4.
    R.J. Day, S.E. Unger, R.G. Cooks: Anal. Chem. 52, 557A (1980).CrossRefGoogle Scholar
  5. 5.
    H. Kambara, S. Hishida: Org. Mass Spectrom. 16, 167 (1981).CrossRefGoogle Scholar
  6. 6.
    H. Kambara, S. Hishida: Anal. Chem. 52, 2340 (1981).CrossRefGoogle Scholar
  7. 7.
    H. Kambara, S. Hishida, H. Naganawa: J. Antibiotics 5, 67 (1982).CrossRefGoogle Scholar
  8. 8.
    K. Morimoto, N. shimada, T. Takita, H. Umezawa, H. Kambara: J. Antibiotics 35, 378 (1982).CrossRefGoogle Scholar
  9. 9.
    C.J. McNeal: Anal. Chem. 54, 43A (1982).CrossRefGoogle Scholar
  10. 10.
    M. Barber, R.S. Bordoli, G.J. Elliott, R.D. Sedgwick, A.N. Tyler: Anal. Chem. 54, 645A (1982).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1983

Authors and Affiliations

  • Hideki Kambara
    • 1
  1. 1.Central Research LaboratoryHitachi Ltd.Kokubunji, Tokyo 185Japan

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