Abstract
The present communication presents preliminary results of laser mass spectrometry on four systems. First, we report on production of quasi-molecular cations and anions in amino acids. Second, we have studied methyl group transfer reactions for amino carboxylates indicating involvement of a thermal process. Third, we have studied the negative ion spectra of aromatic hydrocarbons and nitro compounds. Organic nitro-compounds cause substitution reactions via a chemical ionization solid-state source. Fourth, we have studied fragmentation patterns for amino acids contrasted with SIMS and low-energy electron impact.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
R. Kaufman, F. Hillenkamp, R. Wechsung, Med. Prog. Technol., 6, 121 (1979).
R. J. Day, A. L. Forbes, D. M. Hercules, Spectrosc. Letters, 14, 703 (1981);
C. Schiller, K. G. Kupke, F. Hillenkamp, Z. Anal. Chem., 308, 304 (1981).
R. D. Macfarlane and D. F. Torgenson, Science, 191, 920 (1976).
N. Ohmichi, J. Silbersten, R. D. Levine, J. Phys. Chem., 85, 3369 (1981).
T. Keough, A. J. Destefano, R. A. Sanders, Org. Mass Spectrom., 15, 348 (1980).
C. Schiller, K. G. Krupke, F. Hillenkamp, Z. Anal. Chem., 308, 304 (1981).
A. Benninghoven, D. Jaspers, W. Sichtermann, Appl. Phys., 11, 35 (1976).
K. D. Klöppel, G. Von Bonau, Int. J. of Mass Spect. and Ion Phys., 39, 85 (1981).
D. Voigt, J. Schmidt, Biomed. Mass Spectrom., 5, 44 (1978).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Hercules, D.M., Parker, C.D., Balasanmugam, K., Viswanadham, S.K. (1983). Laser Mass Spectrometry of Organic Compounds. In: Benninghoven, A. (eds) Ion Formation from Organic Solids. Springer Series in Chemical Physics, vol 25. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-87148-1_28
Download citation
DOI: https://doi.org/10.1007/978-3-642-87148-1_28
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-87150-4
Online ISBN: 978-3-642-87148-1
eBook Packages: Springer Book Archive