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The Borazines

  • Chapter
Boron-Nitrogen Compounds

Part of the book series: Anorganische und Allgemeine Chemie in Einzeldarstellungen ((ANORGANISCHE,volume 6))

Abstract

In 1926 Stock and Pohland 1 reacted diborane and ammonia and isolated a material analyzing as B3N3H6. It was soon established that the molecule consisted of a ring structure of alternating boron arid nitrogen atoms and ever since, borazine, (—BH—NH—)3, and its derivatives have attracted the interest of the chemist primarily because of the resemblance of the six-membered boron-nitrogen heterocycle to benzene and its derivatives. Indeed, a comparison of a variety of physical constants of benzene and the parent borazine shows striking similarities.

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Literatur

  1. Stock, A., and E. Pohland: Ber. dtsch. chem. Ges. 59, 2215 (1926).

    Google Scholar 

  2. Brown, C. A., and A. W. Laubengayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  3. Stock, A., and E. Pohlahd: Ber. dtsch. chem. Ges. 59, 2215 (1926).

    Google Scholar 

  4. Wiberg, E., and A. Bolz: ibid. 78, 209 (1940).

    Google Scholar 

  5. Wibeeg, E., K. Hertwig and A. Bolz: Z. anorg. allg. Chem. 256, 177 (1948).

    Google Scholar 

  6. Stock, A., and E. Pohland: Ber. dtsch. chem. Ges. 59, 2215 (1926).

    Google Scholar 

  7. Wiberg, E., and A. Bolz: ibid. 73, 209 (1940).

    Google Scholar 

  8. Schlesinger, H. I., L. Horvitz and A. B. Bxjrg: J. Amer. chem. Soc. 58, 409 (1936).

    CAS  Google Scholar 

  9. Schlesinger, H.I., D.M. Ritter and A. B. Burg: ibid. 60, 1296 (1938).

    CAS  Google Scholar 

  10. This would be analogous, for instance, to the formation of halogenophos-phazenes, (PNX2)n, through the thermal decomposition of PC15/NH4C1 which reportedly occurs via similar ions15.

    Google Scholar 

  11. Schlesinger, H. L, D.M. Ritter and A. B. Burg: J. Amer. chem. Soc. 60, 2297 (1938).

    CAS  Google Scholar 

  12. Stock, A., E. Wiberg and H. Martini: Ber. dtsch. chem. Ges. 63, 2927 (1930)

    Google Scholar 

  13. Stock, A., and E. Pohland: ibid. 62, 90 (1929).

    Google Scholar 

  14. Schaeffer, G. W., and E. R. Anderson: J. Amer. chem. Soc. 71, 2143 (1949).

    CAS  Google Scholar 

  15. Schaeffer, G. W., R. Schaeffer and H. I. Schlesinger: ibid. 73, 1612 (1951).

    CAS  Google Scholar 

  16. Mikheeva, V. I., and V. Y. Markina: J. inorg. Chem.USSR. 1, 2200 (1956).

    Google Scholar 

  17. Haworth, D. T., and L. P. Hohnstedt: Chem. and Ind. 1960, 559.

    Google Scholar 

  18. Brown, C.A., and A. W. Laubengayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  19. Becke-Goehring, M., and W. Lehr: Z. anorg. allg. Chem. 327, 128 (1964).

    CAS  Google Scholar 

  20. Schaeffer, R., M. Steindler, L. F. Hohnstedt, H.S. Smith Jr., L. B. Eddy and H. I. Schlesinger: J. Amer. chem. Soc. 76, 3303 (1954).

    CAS  Google Scholar 

  21. Eddy, I. B., H.S. Smith Jr. and R.R. Miller: ibid. 77, 2105 (1955).

    CAS  Google Scholar 

  22. Hohnstedt, L. P., and D. T. Haworth: ibid. 82, 89 (1960).

    CAS  Google Scholar 

  23. Dahl, G. H., and R. Schaeffer: J. inorg. miel. Chem. 12, 380 (1960).

    CAS  Google Scholar 

  24. Stock, A., and R. Wierl: Z. anorg. allg. Chem. 203, 228 (1931).

    CAS  Google Scholar 

  25. Bauer, S. H.: J. Amer. chem. Soc. 60, 524 (1938).

    CAS  Google Scholar 

  26. Ramaswamy, K.L.: Proc. Indian Acad. Sci. 2A, 364, 630 (1935).

    CAS  Google Scholar 

  27. Sheldon, J. C., and B.C.Smith: Chem. Revs. 1960, 200.

    Google Scholar 

  28. Watanabe, H., and M. Kubo: J. Amer. chem. Soc. 82, 2428 (1960).

    CAS  Google Scholar 

  29. Crawford, B. L., and J. T. Edsall: J. chem. Physics 7, 223 (1939).

    CAS  Google Scholar 

  30. Price, W. C., R. I. B. Fraser, T. S. Robinson and H. C. Longuet-Higgins: Disc. Faraday Soc. 9, 131 (1950).

    Google Scholar 

  31. Spttrr, R.A., and S. Chang: J. chem. Physics 19, 528 (1951).

    Google Scholar 

  32. Watanabe, H., T. Totani, T. Nakagawa and M. Kubo: Spectrochim. Acta 16, 1076 (1960).

    Google Scholar 

  33. Beyer, H., J. B. Hynes, H. Jenne and K.Niedenzu: Advances in Chemistry 42, 266 (1964).

    CAS  Google Scholar 

  34. Platt, J. R., H. B. Klevens and G. W. Schaefer: J. chem. Physics 15, 598 (1947).

    CAS  Google Scholar 

  35. Jacobs, L. E., J.R. Platt and G. W. Schaeffer: ibid. 16, 116 (1948).

    CAS  Google Scholar 

  36. Roothaak, C. C. J., and R. S. Mulliken: ibid. 16, 118 (1948).

    Google Scholar 

  37. Davies, D.W.: Trans. Faraday Soc. 56, 1713 (1960).

    CAS  Google Scholar 

  38. Watastabe, H., K. Ito and M. Kubo: J. Amer. chem. Soc. 82, 3294 (1960).

    Google Scholar 

  39. Spurr, R. A., and S. Chang: J. chem. Physics 19, 528 (1951).

    Google Scholar 

  40. Chalvet, O., R. Daudel and J. J. Kaufman: Advances in Chemistry 42, 251 (1964).

    CAS  Google Scholar 

  41. Ito, K., H. Watanabe and M. Kubo: J. chem. Physics 32, 947 (1959).

    Google Scholar 

  42. Ito, K., H. Watanabe and M. Kubo: Bull. chem. Soc. Japan 38, 1580 (1960).

    Google Scholar 

  43. Suzuki, M., and R. Kubo: Molecular Physics 7, 201 (1964).

    CAS  Google Scholar 

  44. Crawford, B. L., and J. T. Edsall: J. chem. Physics 7, 223 (1939).

    CAS  Google Scholar 

  45. Kilday, M. V., W. H. Johnson and E. J. Prosen: J. Res. Nat. Bur. Standards 65A, 101 (1961).

    CAS  Google Scholar 

  46. Mamantov, G., and J. L. Margrave: J. inorg. nucl. Chem. 20, 348 (1961).

    CAS  Google Scholar 

  47. Laubengayer, A. W., P. C. Moews Jr. and R. F. Porter: J. Amer. chem. Soc. 83, 1337 (1961).

    CAS  Google Scholar 

  48. Brown, C.A., and A.W. Laubengayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  49. Wiberg,E., and A. Bolz: Ber. dtsch. chem. Ges. 73, 209 (1940).

    Google Scholar 

  50. Haworth, D. T., and L. F. Hohnstedt: J. Amer. chem. Soc. 81, 842 (1959).

    CAS  Google Scholar 

  51. Wiberg, E.: Naturwissenschaften 35, 182, 212 (1948).

    Google Scholar 

  52. Laubengayer, A. W.: Personal communication.

    Google Scholar 

  53. Schaeffer, G. W., R. Schaeffer and H. I. Schlesinger: J. Amer. chem. Soc. 73, 1612 (1951).

    CAS  Google Scholar 

  54. Weirrecht, W. E., and A. W. Laubengayer: Abstr. of Papers, 145th National Meeting of the American Chemical Society, New York 1963, p. 4-N.

    Google Scholar 

  55. Moews, P.C. Jr., and A. W. Laubengayer: Inorg. Chem. 2, 1072 (1963).

    CAS  Google Scholar 

  56. Dahl, G. H., and R. Schaeffer: J. Amer. chem. Soc. 83, 3034 (1961).

    CAS  Google Scholar 

  57. Schlesinger, H. I., D.M. Ritter and A.B. Burg: ibid. 60, 1296 (1938).

    CAS  Google Scholar 

  58. Schaeffer, G. W., and E.R. Anderson: ibid. 71, 2143 (1949).

    CAS  Google Scholar 

  59. Rector, C. W., G. W. Schaeffer and J. R. Platt: J. chem. Physics 17, 460 (1949).

    CAS  Google Scholar 

  60. Haworth, D. T., and L. P. Hohnstedt: Chem. and Ind. 1960, 559.

    Google Scholar 

  61. Emeleus, H. J., and K.Wade: J. chem. Soc. (London) 1960, 2614.

    Google Scholar 

  62. Pearson, R. K., and J. W. Frazer: J. inorg. nucl. Chem. 21, 188 (1961).

    CAS  Google Scholar 

  63. Leeeler, A. J.: Inorg. Chem. 3, 145 (1964).

    Google Scholar 

  64. Schlesinger, H. I., L. Horvitz and A. B. Burg: J. Amer. chem. Soc. 58, 409 (1936).

    CAS  Google Scholar 

  65. Wirerg, E., and K. Hertwig: Z. anorg. allg. Chem. 255, 141 (1947).

    Google Scholar 

  66. Wiberg, E., K. Hertwig and A. Bolz: ibid. 256, 177 (1948).

    CAS  Google Scholar 

  67. Zhigach, A. E., E. B. Kazakova and E. S. Krongauz: Proc. Acad. Sci. USSR., Div. Chem. Sci. 1956, 1029.

    Google Scholar 

  68. Becher, H. J., and S. Prick: Z. anorg. allg. Chem. 295, 83 (1958).

    CAS  Google Scholar 

  69. Hawthorne, M. F.: J. Amer. chem. Soc. 81, 5836 (1959).

    CAS  Google Scholar 

  70. Hawthorne, M. F.: ibid. 83, 833 (1961).

    CAS  Google Scholar 

  71. Martius, C.A.: Liebigs Ann. Chem. 109, 79 (1859).

    Google Scholar 

  72. Joannis, A.: C. R. hebd. Séances Acad. Sci. 185, 1106 (1902).

    Google Scholar 

  73. Rideal, S.: Ber. dtsch. chem. Ges. 22, 992 (1889).

    Google Scholar 

  74. Jones, R. G., and C.R. Kinney: J. Amer. chem. Soc. 61, 1378 (1939).

    CAS  Google Scholar 

  75. Kinney, C. R., and M. T. Kolbezen: ibid. 64, 1584 (1942).

    CAS  Google Scholar 

  76. Kinney,C. R., and C. L. Mahoney: J. org. Chemistry 8, 526 (1943).

    CAS  Google Scholar 

  77. Brown, C. A., and A. W. Lattbengayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  78. Brennan, G. L., G. H. Dahl and R. Schaeffer: ibid. 82, 6248 (1960).

    CAS  Google Scholar 

  79. Emeleus, H. J., and G. J. Videla: J. chem. Soc. (London) 1959, 1306.

    Google Scholar 

  80. Hohnstedt, L. E., and R. F. Leieield: Abstract of Papers, 133 rd National Meeting of the American Chemical Society, Boston, 1959, p. 35-M.

    Google Scholar 

  81. Ryschkewitsch, G. E., J. J. Haeeis and H. H. Sisler: J. Amer. chem. Soc. 80, 4515 (1958).

    CAS  Google Scholar 

  82. Hohnstedt, L. F., and D. T. Haworth: ibid. 82, 89 (1960).

    CAS  Google Scholar 

  83. Emeleus. H. J., and G. J. Videla: J. Chem. Soc. (London) 1959, 1306.

    Google Scholar 

  84. Niedenzu, K., D. H. Harrelson and J. W. Dawson: Chem. Ber. 94, 671 (1961).

    CAS  Google Scholar 

  85. Wiberg, E., and G. Horeld: Z. Naturforsch. 6b, 338 (1951).

    CAS  Google Scholar 

  86. Turner, H. S., and R. J. Warne: Chem. and Ind. 1958, 526.

    Google Scholar 

  87. Mikhailov, B. M., and P. M. Aronovich: Bull. Acad. Sci. USSR., Div. Chem. Sci. 1957, 1123.

    Google Scholar 

  88. Mikhailov, B. M., and T. K. Kozminskaja: ibid. 1958, 597.

    Google Scholar 

  89. Mikhailov, B. M., A. N. Blokhina and T. V. Kostroma: J. Gen. Chem. USSR. 29, 1483 (1959).

    CAS  Google Scholar 

  90. Burch,J. E., W. Gerrard and E. E. Mooney: J. chem. Soc. (London) 1962, 2200.

    Google Scholar 

  91. Gerrard, W., M. Howarth, E. E. Mooney and D.E.Pratt: ibid. 1963, 1582.

    Google Scholar 

  92. Braun,J.: C. R. hebd. Seances Acad. Sci. 256, 2422 (1963).

    CAS  Google Scholar 

  93. Nöth, H.: Z. Naturforsch. 16b, 618 (1961).

    Google Scholar 

  94. Jenne,H., and K. Niedenzu: Inorg. Chem. 8, 68 (1964).

    Google Scholar 

  95. Mikhailov, B. M., and T. V. Kosteoma: Bull. Acad. Sci. USSR. 1957, 1125.

    Google Scholar 

  96. Aubeey.D.W., and M. F. Lappert: J. chem. Soc. (London) 1959, 2927.

    Google Scholar 

  97. Bttech,J. E., W. Geeeard and E.F. Mooney: ibid. 1962, 2200.

    Google Scholar 

  98. Beyer, H., K. Niedbnzu and J.W. Dawson: J. org. Chemistry 27, 4701 (1962).

    CAS  Google Scholar 

  99. Schupp, L. J., and C. A. Beown: Abstract of Papers, 128th National Meeting of the American Chemical Society, Minneapolis, 1955, p. 48–R.

    Google Scholar 

  100. Rudnee,B., and J. J. Haeeis: Abstract of Papers, 138th National Meeting of the American Chemical Society, New York, 1960. p. 61–P.

    Google Scholar 

  101. Beotheeton, R. J., and H. Steinbeeg: J. org. Chemistry 26, 4632 (1961).

    Google Scholar 

  102. Niedenzu, K., and coworkers: unpublished results.

    Google Scholar 

  103. Schlesinger, H. I., D.M. Ritter and A. B. Burg: J. Amer. chem. Soc. 60, 1296, 2297 (1938).

    CAS  Google Scholar 

  104. Smalley, J. H., and S. F. Staeiej: ibid. 81, 582 (1959).

    CAS  Google Scholar 

  105. Schaeffer, R., M. Steindler, L. F. Hohnstedt, H. S. Smith Jr., L. B. Eddy and H. I. Sohlesinger: ibid. 76, 3303 (1954).

    CAS  Google Scholar 

  106. Hohnstedt, L. F., and D. T. Haworth: ibid. 82, 89 (1960).

    CAS  Google Scholar 

  107. Brown, C.A., and A.W. Laubengayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  108. Niedenzu, K.: Inorg. Chem. 1, 943 (1962).

    CAS  Google Scholar 

  109. Niedenzu, K., H. Beyer and H. Jenne: Chem. Ber. 96, 2649 (1963).

    CAS  Google Scholar 

  110. Muszkat,K. A., L. Hill and B. Kirson: Israel J. Chem. 1, 27 (1963).

    CAS  Google Scholar 

  111. Muszkat, K. A., and B. Kirson: ibid. 1, 150 (1963).

    CAS  Google Scholar 

  112. Laubengayer, A. W., K. Watterson, D. R. Bibinosti and R. F. Porter: Inorg. Chem. 2, 519 (1963).

    CAS  Google Scholar 

  113. Beyer, H., J. B. Hynes, H. Jenne and K. Niedenzu: Advances in Chemistry 42, 266 (1964).

    CAS  Google Scholar 

  114. Ryschkewitsch, G. E., J. J. Harris and H. H. Sisler: J. Amer. chem. Soc. 80, 4515 (1958).

    CAS  Google Scholar 

  115. Becher, H. J., and S. Frick: Z. anorg. allg. Chem. 295, 83 (1958).

    CAS  Google Scholar 

  116. Groszos, A., and S. F. Stafiej: J. Amer. chem. Soc. 80, 1357 (1958).

    CAS  Google Scholar 

  117. Pellón, J., W. G. Deichert and W.M. Thomas: J. Polymer. Sci. 55, 153 (1961).

    Google Scholar 

  118. Smalley, J. H., and S. F. Staeiej: J. Amer. chem. Soc. 81, 582 (1959).

    CAS  Google Scholar 

  119. Ryschkewitsch, G. E., J. J. Harris and H. Sisler: J. Amer. chem. Soc. 80, 4515 (1958).

    CAS  Google Scholar 

  120. Meller, A.: Mh. Chem. 94, 183 (1963).

    CAS  Google Scholar 

  121. Lagowski, J. J., and P. G. Thompson: Proc. chem. Soc. (London) 1959, 301.

    Google Scholar 

  122. Niedenzu, K., and J.W. Dawson: Angew. Chem. 71, 651 (1959).

    CAS  Google Scholar 

  123. Gould, J. R.: U.S. Patent 2, 754,177 (1956).

    Google Scholar 

  124. Niedenzu, K., and J.W. Dawson: J. Amer. chem. Soc. 81, 3561 (1959).

    CAS  Google Scholar 

  125. Gerrard, W., H.R.Hudson and E. P. Mooney: J. chem. Soc. (London) 1962, 113.

    Google Scholar 

  126. Toeniskoetter, R. H., and F.R. Hall: Inorg. Chem. 2, 29 (1963).

    CAS  Google Scholar 

  127. Gutmann, V., A. Meller and R. Schlegel: Mh. Chem. 94, 1071 (1963).

    CAS  Google Scholar 

  128. Niedenzu, K., and J.W. Dawson: Angew. Chem. 73, 433 (1961).

    CAS  Google Scholar 

  129. Niedenzu, K., D. H. Harrelson and J.W. Dawson: Chem. Ber. 94, 671 (1961).

    CAS  Google Scholar 

  130. Niedenzu, K., W. George and J.W. Dawson: Abstract of Papers, 141st national Meeting of the American Chemical Society, Chicago 1961, p. 15–N.

    Google Scholar 

  131. English, W. D., A. L. McCloskey and H. Steinberg: J. Amer. chem. Soc. 88, 2122 (1961).

    Google Scholar 

  132. Niedenzu, K., D. H. Harrelson and J. W. Dawson: Chem. Ber. 94, 671 (1961).

    CAS  Google Scholar 

  133. Gerhard, W., H. R.Hudson and E. F. Mooney: J. chem. Soc. (London) 1962, 113.

    Google Scholar 

  134. Toeniskoetter, R. H., and P.R. Hall: Inorg. Chem. 2, 29 (1963).

    CAS  Google Scholar 

  135. Niedenzu, K., W. George and J. W. Dawson: Abstract of Papers, 141st National Meeting of the American Chemical Society, Chicago 1961, p. 15–N.

    Google Scholar 

  136. Niedenzu, K., J.W.Dawson and W. George: Chem. and Ind. 1963, 255.

    Google Scholar 

  137. Cragg, R. H., and M. F. Lappert: J. chem. Soc. (London) 1964, 2108.

    Google Scholar 

  138. Beyer, H., J. W. Dawson, H. Jenne and K. Niedenzu: ibid. 1964, 2115.

    Google Scholar 

  139. Bradley, M. J., G. E. Ryschkewitsch and H. H. Sisler: J. Amer. chem. Soc. 81, 2635 (1959).

    CAS  Google Scholar 

  140. Brennan, G. L., G.H. Dahl and R. Schaeffer: ibid. 82, 6248 (1960).

    CAS  Google Scholar 

  141. Lappert,M. F., and H. Pyszora: J. chem. Soc. (London) 1963, 1744.

    Google Scholar 

  142. Meller,A.: Personal communication.

    Google Scholar 

  143. Muszkat,K. A., L. Hell and B. Kirson: Israel J. Chem. 1, 27 (1963).

    CAS  Google Scholar 

  144. Niebenzu, K., and J.W. Dawson: Angew. Chem. 72, 920 (1960).

    Google Scholar 

  145. Turner, H.S.: Chem. and Ind. 1958, 1405.

    Google Scholar 

  146. Niedenzu, K., J. W. Dawson and W. George: ibid. 1963, 255.

    Google Scholar 

  147. Seyferth, D., and H. P. Kögler: J. inorg. nucl. Chem. 15, 99 (1960).

    CAS  Google Scholar 

  148. Cowley, A. H., H. H. Sisler and G. E. Ryschkewitsch: J. Amer. chem. Soc. 82, 501 (1960).

    CAS  Google Scholar 

  149. Meller, A.: Mh. Chem. 94, 183 (1963).

    CAS  Google Scholar 

  150. Wiberg,E. and A. Bolz: Ber. dtsch. chem. Ges. 73, 209 (1940).

    Google Scholar 

  151. Muszkat, K. A. and B. Kirson: Israel J. Chem. 1, 150 (1963).

    CAS  Google Scholar 

  152. Niedenzu, K.: Inorg. Chem. 1, 943 (1962).

    CAS  Google Scholar 

  153. Laubengayer, A.W., K. Watterson, D. R. Bidinosti and R.F.Porter: ibid. 2, 519 (1963).

    CAS  Google Scholar 

  154. Stock, A., E. Wiberg and H. Martini: Ber. dtseh. chem. Ges. 63, 2927 (1930).

    Google Scholar 

  155. Brown, C. A., and A. W. Laubengayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  156. Emeleus, H. J., and G. J. Videla: J. chem. Soc. (London) 1959, 1306.

    Google Scholar 

  157. Schaeffer, R., M. Steindler, L. F. Hohnstedt, H. S. Smith Jr., L. B. Eddy and H. I. Schlesinger: J. Amer. chem. Soc. 76, 3303 (1954).

    CAS  Google Scholar 

  158. Nöth, H.: Z. Naturforsch. 16b, 618 (1961).

    Google Scholar 

  159. Nöth, H.: Personal communication.

    Google Scholar 

  160. Wiberg,E., and G. Horeld: Z. Naturforsch. 6b, 338 (1951).

    CAS  Google Scholar 

  161. Niedenzu, K.: Inorg. Chem. 1, 943 (1962).

    CAS  Google Scholar 

  162. Niedenzu, K., H. Beyer and H. Jenne: Chem. Ber. 96, 2649 (1963).

    CAS  Google Scholar 

  163. Muszkat, K. A., L. Hill and B. Kirson: Israel J. Chem. 1, 27 (1963).

    CAS  Google Scholar 

  164. Laubengayer, A. W., K. Watterson, D. R. Bidinosti and R. F. Porter: Inorg. Chem. 2, 519 (1963).

    CAS  Google Scholar 

  165. Harris, J. J., and B. Rudner: Abstract of Papers, 147th National Meeting of the American Chemical Society, Philadelphia 1964, p. 25–L.

    Google Scholar 

  166. Muszkat, K. A., and B. Kirson: Israel J. Chem. 1, 150 (1963).

    CAS  Google Scholar 

  167. Woods, W. G., and A. L. McCloskey: Inorg. Chem. 2, 861 (1963).

    CAS  Google Scholar 

  168. Gutmann, V., A. Meller and R. Schlegel: Mh. Chem. 94, 733 (1963).

    CAS  Google Scholar 

  169. Sujishi, S., and S.Witz: J. Amer. chem. Soc. 79, 2447 (1957).

    CAS  Google Scholar 

  170. Gerbard, W., E. F. Mooney and D. E. Pratt: J. appl. Chem. 13, 127 (1963).

    Google Scholar 

  171. Gerrard, W., and E. F. Mooney: J. chem. Soc. (London) 1960, 4028.

    Google Scholar 

  172. Hohnstedt, L. F., and D. T. Haworth: J. Amer. chem. Soc. 82, 89 (1960).

    CAS  Google Scholar 

  173. Jones, R. G., and C.R. Kinney: ibid. 61, 1378 (1939).

    CAS  Google Scholar 

  174. Kinney, C. R., and M. T. Kolbezen: ibid. 64, 1584 (1942).

    CAS  Google Scholar 

  175. Lappert, M. F., and H. Pyszora: J. chem. Soc. (London) 1963, 1744.

    Google Scholar 

  176. Niedenzu, K., and J.W. Dawson: J. Amer. chem. Soc. 81, 3561 (1959).

    CAS  Google Scholar 

  177. Ryschkewitsch, G. E., J. J. Harris and H. H. Sisler: ibid. 80, 4515 (1958).

    CAS  Google Scholar 

  178. Turner, H. S., and R. J. Warne: Chem. and Ind. 1958, 526.

    Google Scholar 

  179. Mykhailov, B. M., A. N. Blokhina and T. V. Kostroma: J. Gen. Chem. USSR. 29, 1483 (1959).

    Google Scholar 

  180. Mikhailov, B. M., and T. V. Kostroma: ibid. 29, 1477 (1959).

    CAS  Google Scholar 

  181. Muszkat, K. A., L. Hill and B. Kirson: Israel J. Chem. 1, 27 (1963).

    CAS  Google Scholar 

  182. Muszkat, K. A., and B. Kirson: ibid. 1, 150 (1963).

    CAS  Google Scholar 

  183. Brennan, G. L., G. H. Dahl and R. Schaefeer: J. Amer. chem. Soc. 82, 2648 (1960).

    Google Scholar 

  184. Newsom, H. C., W.D. English, A. L. McCloskey and W.G. Woods: J. Amer. chem. Soc. 83, 4134 (1961).

    CAS  Google Scholar 

  185. Toeniskoetter, R. H., and F.R. Hall: Inorg. Chem. 2, 29 (1963).

    CAS  Google Scholar 

  186. Niedenztt, K., and J. W. Dawson: J. Amer. chem. Soc. 81, 3561 (1959).

    Google Scholar 

  187. Newsom, H. C., W. G. Woods and A. L. McCloskey: Inorg. Chem. 2, 36 (1963).

    CAS  Google Scholar 

  188. Wagner, R. I., and J.L. Bradford: ibid. 1, 99 (1962).

    CAS  Google Scholar 

  189. Pellón, J., W. G. Deichest and W. M. Thomas: J. Polymer. Sci. 55, 153 (1961).

    Google Scholar 

  190. Seyferth, D., and M. Takamizawa: J. org. Chemistry 28, 1142 (1963).

    CAS  Google Scholar 

  191. Fritz, P., K. Niedenzu and J.W. Dawson: Inorg. Chem. 3, 626 (1964).

    CAS  Google Scholar 

  192. Kiedenzu, K., and coworkers: unpublished results.

    Google Scholar 

  193. Davies, D.W.: Trans. Faraday Soc. 56, 1713 (1960).

    CAS  Google Scholar 

  194. Meller, A.: Mh. Chem. 94, 183 (1963).

    CAS  Google Scholar 

  195. Brotherton, R.J., and A.L. McCloskey: Advances in Chemistry 42, 131 (1964).

    CAS  Google Scholar 

  196. Laubengayer, A. W., K. Watterson, D. R. Bidinosti and R. F. Porter: Inorg. Chem. 2, 519 (1963).

    CAS  Google Scholar 

  197. Toeniskoetter, R. H., and F.R. Hall: Inorg. Chem. 2, 29 (1963).

    CAS  Google Scholar 

  198. Kobshak, V. V., N. I. Bekasova, V. A. Zamyatina and G. I. Aristorkhova: Vysokomolekulyarnye Soedineniya 3, 525 (1961).

    Google Scholar 

  199. Boone, J. L., and G. W. Willcockson: Abstr. of Papers, 142nd National Meeting of the American Chemical Society, Atlantic City 1962, p. 6–N.

    Google Scholar 

  200. Niedenzu, K., D. H. Harrelson and J. W. Dawson: Chem. Ber. 94, 671 (1961).

    CAS  Google Scholar 

  201. Paetzold, P. I.: Z. anorg. allg. Chem. 826, 47 (1963).

    Google Scholar 

  202. Wagner, R. I., and J. L. Bradford: Inorg. Chem. 1, 93 (1962).

    CAS  Google Scholar 

  203. Laubengayer, A. W.: Personal communication.

    Google Scholar 

  204. Haworth, D. T., and L. F. Hohnstedt: J. Amer. Chem. Soc. 81, 842 (1959).

    CAS  Google Scholar 

  205. Weibrecht, W. E., and A. W. Laubengayer: Abstr. of Papers, 145th National Meeting of the American Chemical Society, New York 1963, p. 4–N.

    Google Scholar 

  206. Weibrecht, W. E.: Ph. D. Thesis, Cornell University, 1964.

    Google Scholar 

  207. Muszkat, K.A., and B. Kirson: Israel J. Chem. 1, 150 (1963).

    CAS  Google Scholar 

  208. Wiberg, E., and A. Bolz: Ber. dtsch. chem. Ges. 73, 209 (1940).

    Google Scholar 

  209. Jones, R. G., and C.R. Kinney: J. Amer. chem. Soc. 61, 1378 (1939).

    CAS  Google Scholar 

  210. Kinney, C.R., and M. T. Kolbezen: ibid. 64, 1584 (1942).

    CAS  Google Scholar 

  211. Kinney, C.R., and C. L. Mahoney: J. org. Chemistry 8, 526 (1943).

    CAS  Google Scholar 

  212. Niedenzu, K., D. H. Harrelson and J.W. Dawson: Chem. Ber. 94, 671 (1961).

    CAS  Google Scholar 

  213. Gerhard, W., E. F. Mooney and D.E. Pratt: J. appl. Chem. 13, 127 (1963).

    Google Scholar 

  214. Weibrecht, W. E., and A. W. Laubengayer: Abstr. of Papers, 145th National Meeting of the American Chemical Society, New York 1963, p. 4–N.

    Google Scholar 

  215. Weibrecht, W. E.: Ph. D. Thesis, Cornell University, 1964.

    Google Scholar 

  216. Muszkat, K.A., and B. Kirson: Israel J. Chem. 1, 150 (1963).

    CAS  Google Scholar 

  217. Lipscomb, W.N.: J. physic. Chem. 61, 23 (1957).

    CAS  Google Scholar 

  218. Even if not specifically designated for each preparation, all equipment has to be carefully dried and working in inert gas atmosphere (nitrogen, argon) is recommended. All solvents have to be absolutely anhydrous and proper protection of the reaction vessel contents against exposure to moisture is essential for obtaining reasonable yields of products.

    Google Scholar 

  219. Ryschkewitsch, G. E., J. J. Habris and H. H. Sisler: J. Amer. chem. Soc. 80, 4515 (1958).

    CAS  Google Scholar 

  220. Schaeffer, G. W., and E.R. Anderson: ibid. 71, 2143 (1949).

    CAS  Google Scholar 

  221. Haworth, D. T., and L. P. Hohnstedt: Chem. and Ind. 1960, 559.

    Google Scholar 

  222. Mikhailov, B. M., A. N. Blokhina and T.V. Kostroma: J. Gen. Chem. USSR. 29, 1483 (1959).

    CAS  Google Scholar 

  223. Ryschkewitsch, G. E., J. J. Harris and H. H. Sisler: J. Amer. chem. Soc. 80, 4515 (1958).

    CAS  Google Scholar 

  224. Niedenzu, K., and J.W. Dawson: ibid. 81, 3561 (1959).

    CAS  Google Scholar 

  225. Gerrard, W., H. R. Hudson and E. F. Mooney: J. chem. Soc. (London) 1962, 113.

    Google Scholar 

  226. Niedenzu, K., D. H. Harrelson and J.W. Dawson: Chem. Ber. 94, 671 (1961).

    CAS  Google Scholar 

  227. Lappert, M. F., and H. Pyszora: J. chem. Soc. (London) 1963, 1744.

    Google Scholar 

  228. Lonsdale, K., and E. W. Toor: Acta crystallogr. (Copenhagen) 12, 1048 (1959).

    CAS  Google Scholar 

  229. Okamato, Y., and A. J. Gordon: Chem. and Ind. 1963, 528.

    Google Scholar 

  230. Champion, N. G. S., R. Foster and R. K. Mackie: J. chem. Soc. (London) 1961, 5060.

    Google Scholar 

  231. Foster, R.: Nature 195, 490 (1962).

    Google Scholar 

  232. Mellon Jr., E.K., and J. J. Lagowski: ibid. 199, 997 (1963).

    CAS  Google Scholar 

  233. Nakamuea, D., H. Watanabe and M. Kubo: Bull. chem. Soc. Japan 34, 142 (1961).

    Google Scholar 

  234. Coubsen, D. L., and J. L. Hoard: J. Amer. chem. Soc. 74, 1742 (1952).

    Google Scholar 

  235. Cbalvet, O., R. DaudeIí and J.J. Kaufman: Advances in Chemistry 42, 251 (1964).

    Google Scholar 

  236. Silver, A. H., and P. J. Bray: J. chem. Physics 32, 288 (1960).

    CAS  Google Scholar 

  237. Becher, H. J., and S. Frick: Z. physik. Chem. (NF) 12, 241 (1957).

    CAS  Google Scholar 

  238. Ring, M. A., and W. S. Koski: J. chem. Physics 35, 381 (1961).

    CAS  Google Scholar 

  239. Rector, C. W., G. W. Schaeffer and J. R. Platt: ibid. 17, 460 (1949).

    CAS  Google Scholar 

  240. Watahabe, H., K. Ito and M. Kubo: J. Amer. chem. Soc. 82, 3294 (1960).

    Google Scholar 

  241. Becher, H.J., and S. Frick: Z. anorg. allg. Chem. 295, 83 (1958).

    CAS  Google Scholar 

  242. Watanare, H., M. Narisada, T. Nakagawa and M. Kubo: Spectrochim, Acta 16, 78 (1960).

    Google Scholar 

  243. Butcher, J. M., W. Gerbard, E. F. Mooney, R. A. Rothenbury and H. A. Willis: ibid. 18, 1487 (1962).

    CAS  Google Scholar 

  244. Gutmaiosr, V., A. Meller and R. Schlegel: Mh. Chem. 94, 1071 (1963).

    Google Scholar 

  245. Watanabe, H., Y. Kuroda and M. Kubo: Spectrochim. Acta (London) 17, 454 (1961).

    CAS  Google Scholar 

  246. Becher, H. J., and S. Frick: Z. anorg. allg. Chem. 295, 83 (1959).

    Google Scholar 

  247. Meller, A., and R. Schlegel: Mh. Chem. 95, 382 (1964).

    CAS  Google Scholar 

  248. Lappert, M. F.: Proc. chem. Soc. (London) 1959, 59.

    Google Scholar 

  249. Beyer, H., J. B. Hynes, H. Jenne and K. Niedenzu: Advances in Chemistry 42, 266 (1964).

    CAS  Google Scholar 

  250. Ito, K., H. Watanabe and M. Kuro: Bull. chem. Soc. Japan 33, 1580 (1960).

    Google Scholar 

  251. Mooney, E. F.: Spectrochim. Acta 18, 1355 (1962).

    CAS  Google Scholar 

  252. Butcher, I. M., W. Gerrard, E. F. Mooney, R. A. Rothestbfry and. H.A. Willis: ibid. 18, 1487 (1962).

    CAS  Google Scholar 

  253. Mooney, E.F.: Spectrochim. Acta 18, 1355 (1962).

    CAS  Google Scholar 

  254. Ito, K., H. Watanabe and M. Kubo: J. chem. Physics 32, 947 (1959).

    Google Scholar 

  255. Becher, H. J., and S. Prick: Z. physik. Chem. (NF) 12, 241 (1957).

    CAS  Google Scholar 

  256. Waugh, J. S., and R. W. Fessenden: J. Amer. chem. Soc. 79, 846 (1957).

    CAS  Google Scholar 

  257. Chapman, D., S. H. Glarum and A. G. Massey: J. chem Soc. (London) 1963, 3140.

    Google Scholar 

  258. Wiberg, E., and A. Bolz: Ber. dtsch. chem. Ges. 73, 209 (1940).

    Google Scholar 

  259. Schlesinger, H. I., L. Horvitz and A.B. Burg: J. Amer. chem. Soc. 58, 409 (1936).

    CAS  Google Scholar 

  260. Schlesinger, H. I., D.M. Ritter and A. B. Burg: ibid. 60, 1296 (1938).

    CAS  Google Scholar 

  261. Ryschkewitsch, G. E., J. J. Harris and H. H. Sisler: ibid. 80, 4515 (1958).

    CAS  Google Scholar 

  262. Smalley, J. H., and S.F. Stamej: ibid. 81, 582 (1959).

    CAS  Google Scholar 

  263. Meller, A.: Mh. Chem. 94, 183 (1963).

    CAS  Google Scholar 

  264. Toeniskoetter, R. H., and F.R. Hall: Inorg. Chem. 2, 29 (1963).

    CAS  Google Scholar 

  265. Gutmann, V., A. Meller and R. Schlegel: Mh. Chem. 94, 1071 (1963).

    CAS  Google Scholar 

  266. Wagneb, R. I., and J. L. Bbadeobd: Inorg. Chem. 1, 93 (1962).

    Google Scholar 

  267. Beyer, H., J. B. Hynes, H. Jenne and K. Niedenzu: Advances in Chemistry 42, 266 (1964).

    CAS  Google Scholar 

  268. Aubeey, D. W., and M. F. Lappebt: Proc. chem. Soc. (London) 1960, 148.

    Google Scholar 

  269. Lappebt, M. P., and M. K.Majumdab: ibid. 1961, 425.

    Google Scholar 

  270. Lappebt, M. F., and H. Pyszoba: J. chem. Soc. (London) 1963, 1744.

    Google Scholar 

  271. Schlesinger, H. I., D. M. Ritter and A. B. Burg: J. Amer. chem. Soc. 60 1296 (1938).

    CAS  Google Scholar 

  272. Schaeffer, G. W., R. Schaeffer and H. I. Schlesinger: ibid. 73, 1612 (1951).

    CAS  Google Scholar 

  273. Schlesinger, H. I., L. Horvitz and A. B. Burg: ibid. 58, 409 (1936).

    CAS  Google Scholar 

  274. Ryschkewitsch, G. E., J. J. Harris and H. H. Sisler: ibid. 80, 4515 (1958).

    CAS  Google Scholar 

  275. Newsom, H. C., W.G. Woods and A. L. McCloskey: Inorg. Chem. 2, 36 (1963).

    CAS  Google Scholar 

  276. Bartlett, R. K., H. S. Turner, R. J. Warne, M. A. Young and W. S. McDonald: Proc. chem. Soc. (London) 1962, 153.

    Google Scholar 

  277. Wagner, R. I., and J.L. Bradford: Inorg. Chem. 1, 93 (1962).

    CAS  Google Scholar 

  278. Smalley, J. H., and S. F. Stafiej: J. Amer. chem. Soc. 81, 582 (1959).

    CAS  Google Scholar 

  279. Meller, A.: Mh. Chem. 94, 183 (1963).

    CAS  Google Scholar 

  280. Wagner, R. I., and J.L. Bradford: Inorg. Chem. 1, 93 (1962).

    CAS  Google Scholar 

  281. Toeniskoetter, P.H., and F.R. Hall: ibid. 2, 29 (1963).

    CAS  Google Scholar 

  282. Stock, A.: Hydrides of Boron and Silicon, Cornell University Press, Ithaca, N.Y., 1933.

    Google Scholar 

  283. Schaeffer, R., M. Steindler, L. F. Hohnstedt, H.S. Smith Jr., L. B. Eddy and H. I. Schlesinger: J. Amer. chem. Soc. 76, 3303 (1954).

    CAS  Google Scholar 

  284. Brown, C. A., and A. W. Laubehgayer: J. Amer. chem. Soc. 77, 3699 (1955).

    CAS  Google Scholar 

  285. Laubengayer, A. W., P. W. Moews Jr. and R. F. Porter: ibid. 83, 1337 (1961).

    CAS  Google Scholar 

  286. Niedenzu, K., and coworkers: unpublished results.

    Google Scholar 

  287. Laubengayer, A. W., and O. T. Beachley Jr.: Advances in Chemistry 42, 281 (1964).

    Google Scholar 

  288. Laubengayer, A. W.: Personal communication.

    Google Scholar 

  289. Wagner, R.I., and J. L. Bradford: Inorg. Chem. 1, 93 (1962).

    CAS  Google Scholar 

  290. Wagner, R. I., and J. L. Bradford: ibid. 1, 99 (1962).

    CAS  Google Scholar 

  291. Harris, J. J.: J. org. Chemistry 26, 2155 (1961).

    CAS  Google Scholar 

  292. Gerrard, W., H. R. Hudson and E. F. Mooney: J. chem. Soc. (London) 1962, 113.

    Google Scholar 

  293. Gutmann, V., A. Meller and R. Schlegel: Mh. Chem. 95, 314 (1964).

    CAS  Google Scholar 

  294. Lappert, M. F.: Proc. Chem. Soc. (London) 1959, 59.

    Google Scholar 

  295. Aubrey, D.W., and M. F. Lappert: J. chem. Soc. (London) 1959, 2927.

    Google Scholar 

  296. Toeniskoetter, R. H., and F.R. Hall: Inorg. Chem. 2, 29 (1963).

    CAS  Google Scholar 

  297. Lappert, M. F., and M. K. Majumdar: Proc. chem. Soc. (London) 1961, 425.

    Google Scholar 

  298. Gutmann, V., A. Meller and R. Schlegel: Mh. Chem. 94, 1071 (1963).

    CAS  Google Scholar 

  299. Seyperth, D., and H. P. Kögler: J. inorg. nucl. Chem. 15, 99 (1960).

    Google Scholar 

  300. Wagner, R. I., and J.L. Bradford: Inorg. Chem. 1, 99 (1962).

    CAS  Google Scholar 

  301. Larcombe, B. E., and H.S.Turner: Chem. and Ind. 1963, 410.

    Google Scholar 

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    Dr. Kurt Niedenzu & Dr. John W. Dawson

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Niedenzu, K., Dawson, J.W. (1965). The Borazines. In: Boron-Nitrogen Compounds. Anorganische und Allgemeine Chemie in Einzeldarstellungen, vol 6. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-85826-0_5

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