Abstract
One might expect the columnar-grain microstructure of chemical-vapordeposited (CVD) diamond films to have a strong effect on the thermal conductivity κ. It was recently demonstrated [1] that the local conductivity κlocal at room temperature of high-quality microwave-plasma-deposited diamond indeed exhibits a strong gradient with respect to position in the films. κlocal was deduced by studying a series of films of different thickness prepared under as identical conditions as possible, the only parameter differentiating the samples being the time of deposition. The local conductivity at height z above the substrate was obtained as the derivative of the measured conductance Zicobs: Zκobs: κlocal(z) = d (Zκobs)/dZ, where the observed conductivity is necessarily averaged over the sample thickness Z by the nature of the measurement. The results, Fig. 1, show that κlocal increases by at least a factor of four going from the substrate surface to the top of a thick (~ 400 µm) sample. Here we present the results of such measurements over a wide temperature range, 6–400K, which allows us to extract the phonon scattering strengths as a function of position z within a sample.
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References
J. E. Graebner, S. Jin, G. W. Kammlott, J. A. Herb, and C. F. Gardinier, Appl. Phys. Lett. 60, 1576 (1992).
J. E. Graebner and J. A. Herb, Diamond Films Technol. 1, 155 (1992).
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© 1993 Springer-Verlag Berlin Heidelberg
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Graebner, J.E. (1993). Extraction of a Local Thermal Conductivity in CVD Diamond Films. In: Meissner, M., Pohl, R.O. (eds) Phonon Scattering in Condensed Matter VII. Springer Series in Solid-State Sciences, vol 112. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84888-9_14
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DOI: https://doi.org/10.1007/978-3-642-84888-9_14
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