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Are There Ordering Effects in Ba(Pb,Bi)O3 and (Ba,K)BiO3?

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Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 113))

Abstract

A simple model is presented for the origin of the wide nonmetallic ranges in the (Ba, K)(Bi, Pb)O 3 alloy phase diagram, proposing that the semiconducting behaviour is caused by the presence of incommensurate oxygen breathing-type charge density waves as well as Bi/Pb ordering waves. The model is studied for large variety of supercell configurations using a simple, yet realistic tight-binding Hamiltonian. Good agreement with experiment is found. Crucial predictions of the model can be tested by diffuse elastic scattering experiments.

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© 1993 Springer-Verlag Berlin, Heidelberg

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Hahn, U., Vielsack, G., Weber, W. (1993). Are There Ordering Effects in Ba(Pb,Bi)O3 and (Ba,K)BiO3?. In: Kuzmany, H., Mehring, M., Fink, J. (eds) Electronic Properties of High-Tc Superconductors. Springer Series in Solid-State Sciences, vol 113. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84865-0_75

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  • DOI: https://doi.org/10.1007/978-3-642-84865-0_75

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84867-4

  • Online ISBN: 978-3-642-84865-0

  • eBook Packages: Springer Book Archive

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