Analysis of Fungicide Residues in Vegetables and Vegetable Products

  • C. J. Miles
  • K. H. Yanagihara
Part of the Modern Methods of Plant Analysis book series (MOLMETHPLANT, volume 16)

Abstract

The goal of this chapter is to summarize up-to-date methods for analysis of fungicide residues in vegetable and vegetable products without the need to consult the original literature. The number of fungicides in use and the wide range of matrices limit the focus of this chapter on major fungicides and matrices as well as these authors’ experience. The reader must refer to original and supplementary literature to augment their specific needs. Space limitations do not allow detailed discussions and require us to combine materials and methods sections for each method.

Keywords

Thiophanate Phosphonate Chlorpyrifos Dithiocarbamate Butanone 

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References

  1. AOAC (1985) Changes in official methods of analysis, 1st suppl, 14th edn, sect 29A01-29A04. Association of Official Analytical Chemists, Arlington, VAGoogle Scholar
  2. Balasubramanian K, Perez R (1982) Improved method for the determination of total residues of metalaxyl in crop as 2,6-dimethylaniline. Method AG-395, Ciba-Geigy Corp, Greensboro, NCGoogle Scholar
  3. Chou W (1990) Determination of fosetyl-al aluminum tris (O-ethyl phosphonate) by phosphorus specific flame photometric gas chromatography. Method 163, Rhône-Poulenc Ag Co, Research Triangle Park, NCGoogle Scholar
  4. Doerge DR, Miles CJ (1991) Determination of ethylenethiourea in crops using particle beam liquid chromatography/mass spectrometry. Anal Chem 63:1999–2001PubMedCrossRefGoogle Scholar
  5. Fermenta Corp (1988) General procedure for the determination of residues of tetra-chloroisophthalonitrile (chlorothalonil, SDS-2787), HCB and PCBN on selected crops. Document 3136-88-0138-MD-001, Fermenta Corp, Mentor, OHGoogle Scholar
  6. Gilvydis DM, Walters SM (1990) Ion-pairing liquid chromatographic determination of benzimidazole fungicides in foods. J Assoc Off Anal Chem 73:753–761PubMedGoogle Scholar
  7. Gilvydis DM, Walters SM (1991) Gas chromatographic determination of captan, folpet and captafol residues in tomatoes, cucumbers and apples using a wide-bore capillary column: interlaboratory study. J Assoc off Anal Chem 74:830–835PubMedGoogle Scholar
  8. Gordon CF, Schukert RJ, Bornak WE (1967) Improved method for the determination of ethylenebisdithiocarbamate residues in plants, fruits and vegetables. J Assoc Off Anal Chem 50:1102–1108Google Scholar
  9. Hunter G (1988) Dithiocarbamate residues by headspace analysis of carbon disulfide. California Dep Food and Agric, Sacramento, CAGoogle Scholar
  10. Kadenczki L, Arpad Z, Gardi I, Ambrus A, Gyorfi L, Reese G, Ebing W (1992) Column extraction of residues of several pesticides from fruits and vegetables: a simple multiresidue analysis method. J AOAC Int 75:53–61Google Scholar
  11. Kirkland JJ, Holt RF, Pease HL (1973) Determination of benomyl residues in soils and plant tissue by high-speed cation exchange liquid chromatography. J Agric Food Chem 21:368–371PubMedCrossRefGoogle Scholar
  12. Krause RT (1980) Multiresidue method for determining N-methylcarbamate insecticides in crops using high performance liquid chromatography. J Assoc Off Anal Chem 63:1114–1124Google Scholar
  13. Lee SM, Wylie PL (1991) Comparison of the atomic emission detector to other element-selective detectors for the gas chromatographic analysis of pesticide residues. J Agric Food Chem 39:2192–2199CrossRefGoogle Scholar
  14. Lee SM, Papathakis ML, Feng HMC, Hunter GF, Carr JE (1991) Multipesticide residue method for fruits and vegetables: California Department of Food and Agriculture. Fresenius J Anal Chem 339:376–383CrossRefGoogle Scholar
  15. Liao W, Joe T, Cusick WG (1991) Multiresidue screening method for fresh fruits and vegetables with gas chromatographic/mass spectrometric detection. J Assoc Off Anal Chem 74:554–565PubMedGoogle Scholar
  16. Liu CH, Mattern GC, Xiaobing Y, Rosen JD (1990) Determination of benomyl by liquid chromatography/mass spectrometry/selected ion monitoring. J Agric Food Chem 38:167–171CrossRefGoogle Scholar
  17. Liu CH, Mattern GC, Yu X, Rosen RT, Rosen JD (1991) Multiresidue determination of nonvolatile and thermally labile pesticides in fruit and vegetables by thermospray liquid chromatography/mass spectrometry. J Agric Food Chem 39:718–723CrossRefGoogle Scholar
  18. Lowen WK, Pease HL (1964) Dithiocarbamates. In: Zweig G (ed) Analytical methods for pesticides and plant growth regulators, vol 3. Academic Press, New York, pp 69–77Google Scholar
  19. Luke MA, Froberg JE, Masumoto HT (1975) Extraction and cleanup of organochlorine, organophosphate, organonitrogen and hydrocarbon pesticides in produce for determination by gas-liquid chromatography. J Assoc Off Anal Chem 58:1020–1026PubMedGoogle Scholar
  20. Mattern GC, Liu CH, Louis JB, Rosen JD (1991) GC/MS and LC/MS determination of 20 pesticides for which dietary oncogenic risk has been estimated. J Agric Food Chem 39:700–704CrossRefGoogle Scholar
  21. Miles CJ (1992) Determination of National Pesticide Survey analytes in groundwater by liquid chromatography with postcolumn reaction detection. J Chromatogr 592: 283–290CrossRefGoogle Scholar
  22. Miles CJ, Zhou M (1991) Determination of nabam fungicide in crops by liquid chromatography with postcolumn reaction detection. J Assoc Off Anal Chem 74:384–388PubMedGoogle Scholar
  23. Miles CJ, Doerge DR, Bajic S (1992) Particle beam/liquid chromatography/mass spectrometry of National Pesticide Survey analytes. Arch Environ Contam Toxicol 22: 247–251CrossRefGoogle Scholar
  24. Mills PA (1959) Detection and semi-quantitative estimation of chlorinated organic pesticide residues in food by paper chromatography. J Assoc Off Anal Chem 42:734–740Google Scholar
  25. Mills PA, Onley JJ, Gaither RA (1963) Rapid method for chlorinated pesticide residues in non-fatty foods. J Assoc Off Anal Chem 46:186–191Google Scholar
  26. Newsome WH (1985) An enzyme-linked immunosorbent assay for metalaxyl in foods. J Agric Food Chem 33:528–530CrossRefGoogle Scholar
  27. Newsome WH (1986) Development of an enzyme-linked immunosorbent assay for tri-adimefon in foods. Bull Environ Contam Toxicol 36:9–14PubMedCrossRefGoogle Scholar
  28. Newsome WH, Shields JB (1981) A radioimmunoassay for benomyl and methyl 2-benzimidazole carbamate on food crops. J Agric Food Chem 29:220–222PubMedCrossRefGoogle Scholar
  29. Obrist JJ, Leimkuehler WM, Coffman MW (1982) Residue analysis procedure for Bay-leton and metabolites in barley and wheat. Rep 80488, Mobay Chem Corp, St Louis, MOGoogle Scholar
  30. Office of Technology Assessment (1988) Pesticide residues in food; technologies for detection. (OTA-F-398) US Congress, Washington, DCGoogle Scholar
  31. Official Methods of Analysis (1990) 15th edn. Association of Official Analytical Chemists, Arlington, VAGoogle Scholar
  32. Pease HL, Gardner JA (1969) Fluorometric and colorimetric procedures for determining residues of benomyl. J Agric Food Chem 17:267–270CrossRefGoogle Scholar
  33. Pease HL, Holt RF (1971) Improved method for determining benomyl residues. J Assoc Off Anal Chem 54:1399–1402PubMedGoogle Scholar
  34. Pesticide Analytical Manual (1987) Vols I and II, Food and Drug Administration, Washington, DCGoogle Scholar
  35. Royal Society of Chemistry (1987) The agrochemical handbook. The Royal Society of Chemistry, Nottingham, UKGoogle Scholar
  36. Sherma J (ed) (1989) Analytical methods for pesticides and plant growth regulators, vol 17, Academic Press, San DiegoGoogle Scholar
  37. Slagowski JL, Elliott EJ, Leary JB (1980) Determination of captafol and THPI residues in crops. Method RM-6K-1, Chevron Chem Co, Richmond, CAGoogle Scholar
  38. Spittler TD, Marafioti RA, Lahr LM (1984) Determination of benomyl and its metabolites by cation-exchange high-performance liquid chromatography. J Chromatogr 317:527–531CrossRefGoogle Scholar
  39. Storherr RW, Getz ME, Watts RR (1964) Identification and analyses of five organo-phosphate pesticides: recoveries from crops fortified at different levels. J Assoc Off Anal Chem 47:1087–1093Google Scholar
  40. Storherr RW, Ott P, Watts RR (1971) A general method for organophosphate pesticide residues in non-fatty foods. J Assoc Off Anal Chem 54:513–516PubMedGoogle Scholar
  41. Thier HP, Zeumer H (eds) (1987) Manual of pesticide residue analysis, vol 1. VCH, Weinheim, GermanyGoogle Scholar
  42. van Emon JM, Seiber JN, Hammock BD (1989) Immunoassay techniques for pesticide analysis. In: Sherma J (ed) Analytical methods for pesticides and plant growth regulators, vol 17. Academic Press, San Diego, pp 217–263Google Scholar
  43. Veith GD, Kiwus LM (1977) An exhaustive steam distillation and solvent extraction unit for pesticides and industrial chemicals. Bull Environ Contam Toxicol 17:631–636PubMedCrossRefGoogle Scholar
  44. Voyksner RD, Bursey JT, Pellizzari ED (1984) Analysis for selected pesticides by high-performance liquid chromatography-mass spectrometry. J Chromatogr 312:221–235CrossRefGoogle Scholar
  45. Zweig G (ed) (1964) Analytical methods for pesticides and plant growth regulators, vol 3. Academic Press, New YorkGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1994

Authors and Affiliations

  • C. J. Miles
  • K. H. Yanagihara

There are no affiliations available

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