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The Potential Energy Surface of the T1 State of 1,3,5-Hexatrienes and Methylated Derivatives: A Survey of Present Knowledge

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Time-Resolved Vibrational Spectroscopy V

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 68))

Abstract

In previous studies[1,2] we considered the time-resolved resonance Raman (TRRR) spectra of 1,3,5-hexatriene (HT) in its lowest excited triplet state in order to obtain information about the geometry of the T1 intermediate and the mechanism of the cis-trans photoisomerization in T1.

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References

  1. F. Negri, G. Orlandi, A.M. Brouwer, F.W. Langkilde and R. Wilbrandt, J. Chem. Phys. 90, 5944–5963 (1989)

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  5. F.W. Langkilde, R. Wilbrandt, A.M. Brouwer, H.J.C. Jacobs, E. Negri and G. Orlandi, “Steric control of excited state molecular structure. Resonance Raman and absorption spectroscopy of 2-methyl- and 3-methyl-1,3,5-hexatriene in theT1 state” (submitted)

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Authors and Affiliations

  1. Department of Environmental Science and Technology, Risø National Laboratory, DK-4000, Roskilde, Denmark

    R. Wilbrandt & S. Møller

  2. Department of Physical Chemistry A, Royal Danish School of Pharmacy, 2 Universitetsparken, DK-2100, Copenhagen, Denmark

    F. W. Langkilde

  3. Laboratory of Organic Chemistry, University of Amsterdam, NL-1018, WS Amsterdam, The Netherlands

    A. M. Brouwer

  4. Dipartimento di Chimica G. Ciamician, University of Bologna, I-40126, Bologna, Italy

    F. Negri & G. Orlandi

Authors
  1. R. Wilbrandt
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  2. S. Møller
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  3. F. W. Langkilde
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  4. A. M. Brouwer
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  5. F. Negri
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  6. G. Orlandi
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Editor information

Editors and Affiliations

  1. Department of Chemistry, School of Science & Engineering, Waseda University, Tokyo 169, Japan

    Hiroaki Takahashi

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© 1992 Springer-Verlag Berlin Heidelberg

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Wilbrandt, R., Møller, S., Langkilde, F.W., Brouwer, A.M., Negri, F., Orlandi, G. (1992). The Potential Energy Surface of the T1 State of 1,3,5-Hexatrienes and Methylated Derivatives: A Survey of Present Knowledge. In: Takahashi, H. (eds) Time-Resolved Vibrational Spectroscopy V. Springer Proceedings in Physics, vol 68. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84771-4_45

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  • DOI: https://doi.org/10.1007/978-3-642-84771-4_45

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84773-8

  • Online ISBN: 978-3-642-84771-4

  • eBook Packages: Springer Book Archive

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