Abstract
Transition metal oxides are classified into two categories: the charge transfer (CT) materials and the Mott-Hubbard (MH) ones. High temperature oxides are known to be in the CT materials. This is because of the subtle balance of the energy levels in copper and oxygen ions and of the unique crystal structure. In this lecture, we examine relations between crystal structure and electronic structure in a variety of the oxides and discuss what the key physical parameters are in the high temperature superconductors. Special attention is paid to the crucial difference in the electronic properties between CT and MH materials. Systematic variation in various electronic properties with materials provides us with valuable information on the mechanism of high temperature superconductivity.
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Maekawa, S., Ohta, Y., Tohyama, T. (1992). Physical Parameters in High-Temperature Superconductors. In: Maekawa, S., Sato, M. (eds) Physics of High-Temperature Superconductors. Springer Series in Solid-State Sciences, vol 106. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84718-9_3
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DOI: https://doi.org/10.1007/978-3-642-84718-9_3
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