Abstract
We discuss the interference of π-electronic and structural defects for the crystal structure in polyacetylene. We consider the local crystallografic modifications caused by solitons and the special type of backbone solitons — the twistons. The role of twistons in formation of hexagonal or tetragonal phases with unhindered rotations at finite dopant concentration is discussed.
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© 1992 Springer-Verlag Berlin Heidelberg
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Brazovskii, S., Kirova, N. (1992). Solitons, Twistons and Crystallinity on Conducting Polymers. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Polymers. Springer Series in Solid-State Sciences, vol 107. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84705-9_8
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DOI: https://doi.org/10.1007/978-3-642-84705-9_8
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-84707-3
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