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Polythiophenes Functionalized with Redoxactive Groups

  • P. Bäuerle
  • K.-U. Gaudl
  • G. Götz
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 107)

Abstract

A series of functionalized alkyl(oligo)thiophenes bearing covalently linked donor and acceptor groups were synthesized. Their electrochemical polymerization led to various new conducting polymers which besides their electrical conductivity incorporate the specific redoxactivity of viologen-, ferrocene-, quinone- and metal-complexed 2,2’-bipyridine groups. Unexpected effects concerning the interplay of the functional group and the polymeric backbone were observed and rationalized.

Keywords

Conducting Polymer Polymeric Backbone Poly Thiophene Acceptor Group Reversible Redox 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    T. Skotheim:”Handbook of Conducting Polymers”, Marcel Dekker, New York, 1986, Vol. 1, 2Google Scholar
  2. 2.
    R.L. Elsenbaumer, K.Y. Jen, R. Obvodi: Synth. Met. 15, 169 (1986)CrossRefGoogle Scholar
  3. 3.
    J.C. Moutet, C.J. Pickett: J. Chem. Soc. Chem. Commun. 188 (1989)Google Scholar
  4. 4.
    J. Roncali, R. Garreau, D. Delabouglise, F. Gamier, M. Lemaire: J. Chem. Soc. Chem. Commun. 679 (1989)Google Scholar
  5. 5.
    A. Deronzier, M. Essakaili: J. Chem. Soc. Chem. Commun. 242, (1990)Google Scholar
  6. 6.
    G. Bidan, D. Limousin: Ann. Phys. (Paris) 11, 5 (1986)Google Scholar
  7. 7.
    A.O. Patil, Y. Ikenoue, F. Wudl, A.J. Heeger: J. Am. Chem. Soc. 109, 1858 (1987)CrossRefGoogle Scholar
  8. 8.
    A. Deronzier, J.-C. Moutet: Acc. Chem. Res. 22, 249 (1989)CrossRefGoogle Scholar
  9. 9.
    F. Gamier: Angew. Chem. Adv. Mater. 101, 529 (1989)Google Scholar
  10. F. Gamier: Angew. Chem. Int. Ed. Engl. 28, 513 (1989)CrossRefGoogle Scholar
  11. F. Gamier: Adv. Mater 1, 117 (1989)CrossRefGoogle Scholar
  12. 10.
    D. Delabouglise, F. Gamier: Adv. Mater. 2, 91 (1990)CrossRefGoogle Scholar
  13. 11.
    P. Cagniant, G. Merle, D. Cagniant: Bull. Soc. Chim. Fr., 308 (1970)Google Scholar
  14. 12.
    P. Audebert, G. Bidan, M. Lapkowski, D. Limousin in:”Electronic Properties of Conjugated Polymers”; M. Kuzmany, M. Mehring, S. Roth (Eds.): (Springer Ser. Solid State Sci. 76, 366 (1987))Google Scholar
  15. 13.
    P. Bäuerle, F. Würthner, S. Heid: Angew. Chem. 102, 414 (1990)CrossRefGoogle Scholar
  16. P. Bäuerle, Angew. Chem. Int. Ed. Engl. 29, 419 (1990)CrossRefGoogle Scholar
  17. 14.
    P. Bäuerle, K.-U. Gaudl: Synth. Met., acceptedGoogle Scholar
  18. 15.
    P. Bäuerle, K.-U. Gaudl: Adv. Mater. 2, 185 (1990)CrossRefGoogle Scholar
  19. 16.
    All potentials given in this text refer to Ag/AgNO3(0.1M CH3CN) reference electrode internally calibrated to the ferrocene/ferricenium redox coupleGoogle Scholar
  20. 17.
    N.S. Sariciftci, H. Neugebauer, K.-U. Gaudl, P. Bäuerle, M. Mehring: these proceedingsGoogle Scholar
  21. 18.
    A.C. Kolbert, N.S. Sariciftci, K.-U. Gaudl, P. Bäuerle, M. Mehring: these proceedingsGoogle Scholar
  22. 19.
    P. Bäuerle, K.-U. Gaudl, F. Würthner, N.S. Sariciftci, H. Neugebauer, M. Mehring, C. Zhong, K. Doblhofer: Adv. Mater 2, 490 (1990)CrossRefGoogle Scholar
  23. 20.
    P. Bäuerle, K.-U. Gaudl, G. Götz, F. Effenberger: VDI-Berichte, in pressGoogle Scholar
  24. 21.
    N.C. Foulds, C.R. Lowe: Anal. Chem. 60, 2473 (1988)CrossRefGoogle Scholar
  25. 22.
    F. Beck, P. Braun, M. Oberst: Ber. Bunsenges. Phys. Chem. 91, 967 (1987)Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1992

Authors and Affiliations

  • P. Bäuerle
    • 1
  • K.-U. Gaudl
    • 1
  • G. Götz
    • 1
  1. 1.Institut für Organische Chemie und Isotopenforschung derUniversität StuttgartStuttgart 80Germany

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