Abstract
A series of functionalized alkyl(oligo)thiophenes bearing covalently linked donor and acceptor groups were synthesized. Their electrochemical polymerization led to various new conducting polymers which besides their electrical conductivity incorporate the specific redoxactivity of viologen-, ferrocene-, quinone- and metal-complexed 2,2’-bipyridine groups. Unexpected effects concerning the interplay of the functional group and the polymeric backbone were observed and rationalized.
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All potentials given in this text refer to Ag/AgNO3(0.1M CH3CN) reference electrode internally calibrated to the ferrocene/ferricenium redox couple
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Bäuerle, P., Gaudl, KU., Götz, G. (1992). Polythiophenes Functionalized with Redoxactive Groups. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Polymers. Springer Series in Solid-State Sciences, vol 107. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84705-9_71
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DOI: https://doi.org/10.1007/978-3-642-84705-9_71
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