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Fast Processes in Polyphenylene Vinylene: PS-Absorption Studies and Computer Simulation

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Electronic Properties of Polymers

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 107))

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Abstract

Photoinduced picosecond absorption spectra of phenylated polyphenylene vinylenes were observed in the intra-gap region. The non-exponential time decay alters with wavelength. The time behaviour of the transient spectra will be explained by two absorbing quasiparticles of different kinetic behaviour, polarons and bipolarons. Generation and recombination of these absorbers will be described by a rate equation system. A numerical simulation of the time dependent absorption has been performed and compared with experiment. The superposition of both polarons and bipolarons in the transient spectra was analyzed quantitatively by comparison with experimental results.

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References

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Author information

Authors and Affiliations

  1. Institute for Optics and Quantum Electronics, University of Jena, O-6900, Jena, Germany

    S. Rentsch

Authors
  1. S. Rentsch
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Editor information

Editors and Affiliations

  1. Institut für Festkörperphysik, Universität Wien, Strudlhofgasse 4, A-1090, Wien, Austria

    Hans Kuzmany

  2. 2. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, W-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring

  3. Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, W-7000, Stuttgart 80, Fed. Rep. of Germany

    Siegmar Roth

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© 1992 Springer-Verlag Berlin Heidelberg

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Rentsch, S. (1992). Fast Processes in Polyphenylene Vinylene: PS-Absorption Studies and Computer Simulation. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Polymers. Springer Series in Solid-State Sciences, vol 107. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84705-9_32

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  • DOI: https://doi.org/10.1007/978-3-642-84705-9_32

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84707-3

  • Online ISBN: 978-3-642-84705-9

  • eBook Packages: Springer Book Archive

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